File name: Pandora169s1_Egbert_20240519_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20241106T170308.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20240519_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20240519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240519T103421.8Z 8905.440530 154 1 49.66 2 83.29 68.64 118.63 293.01 0.00 1 0.00 1 0 17 5.731e-01 2.974e-02 2.935e-01 8.397e-03 9.960441e-01 5.088268e-03 1.084210e-02 -6.000000e+00 3.546230e-01 231.15 -2.00 3.58 -2.00 322.27 0.00e+00 3.244265e-03 2.979927e-03 3.408430e-03 -6.000000e+00 1.584456e-02 280.71 -2.00 20.00 -2.00 321.80 0.00e+00 7.796 0.009 302.00 328.00 3 1.1750e+00 1.9963e-02 9.5789e-02 -6.0000e+00 8.9010e-01 1.1622e+00 2.7137e-02 6.0355e-02 -6.0000e+00 9.6893e-01 -1.6197e+00 2.3157e-02 3.2227e-02 -6.0000e+00 5.6996e-01 6.6132e-01 1.0536e-02 1.0000e-02 -6.0000e+00 2.3352e-01 3.0619e-05 -2.2689e-03 2.3616e-04 1.7853e-04 -6.0000e+00 1.8471e-02 3.6160e-03 -1.0619e-04 12 8 8 10 0 0 99.80 23.88 0.29 0.00362 -0.01343 51 11 1 5 0 973.530 27.45 20.00 23.88 17.43 36.3 1007.65 900000 -101845 35921 55215 900000 38219 900000 -141173 61730 -170544 -24611 -130738 146692 900000 900000 -63501 124057 5288 900000 -36730 900000 -17762 61047 -42657 -21848 -69594 174980 -67330 62826 900000 81447 87208 11365 -44475 900000 5635 236432 -11162 86898 24812 121176 56188 95711 15243 142912 85720 159615 63443 24649 32434 80269 63454 89429 150746 25908 45366 57098 68137 30315 54634 16989 23947 22937 43416 26941 81078 16166 13607 11668 39414 21302 14371 19462 21020 781 15263 -11414 -1878 177 5772 2688 3305 -5227 4102 -2826 8783 -2024 2292 -843 7046 -2359 12221 -6650 -5577 1412 -255 -6274 -2646 -4117 -2707 -3953 -4747 -4063 -5289 -4461 -1185 -1576 70 -1193 -3237 -1977 -1063 -1406 -677 999 -285 93 87 459 2338 3098 2135 5255 2951 2058 -6854 2960 3624 2007 -419 1301 -585 -184 -122 767 34 20 460 287 -575 196 -1452 -1865 900000 -3865 370 451 900000 312 900000 -5425 505 -8721 -348 -5504 1199 900000 900000 -2919 1099 149 900000 -1492 900000 -556 922 -1701 -734 -3527 1430 -3051 869 900000 1246 1482 425 -2767 900000 211 1933 -580 2167 1215 2698 2336 2827 911 2679 2707 2608 2594 1504 2002 3583 3608 4376 4560 2452 3721 4230 4454 2627 3711 1633 2352 2549 4478 3396 6505 2345 2152 2073 6101 4126 3016 3783 3737 150 2365 -2175 -351 37 1374 768 1067 -1996 1537 -1189 3493 -918 1013 -378 2841 -985 4334 -2842 -2571 706 -152 -4619 -2142 -3651 -2393 -3341 -3683 -2903 -3795 -3317 -904 -1288 62 -1197 -3767 -2554 -1467 -2009 -961 1373 -392 130 127 693 3514 4514 3005 6947 3875 2654 -9373 3753 4939 3156 -765 2592 -1280 -427 -302 1989 93 54 1265 778 -1500 476 -3372 -4246 SS 20240519T104527.4Z 8905.448234 157 1 49.43 2 81.42 70.48 120.41 295.30 0.00 1 0.00 1 0 17 7.480e-01 1.398e-02 1.591e-01 2.899e-03 8.745579e-01 1.659095e-03 1.018868e-02 -6.000000e+00 4.534895e-01 231.15 -2.00 3.58 -2.00 321.74 0.00e+00 7.438241e-03 9.266427e-04 5.512673e-03 -6.000000e+00 1.973634e-02 280.72 -2.00 20.00 -2.00 321.24 0.00e+00 6.321 0.005 302.00 328.00 3 1.0484e+00 6.0863e-03 8.1460e-02 -6.0000e+00 1.1352e+00 2.8103e-01 8.9788e-03 5.6358e-02 -6.0000e+00 1.2299e+00 -3.8855e-01 9.3333e-03 3.3215e-02 -6.0000e+00 7.3014e-01 1.5372e-01 4.2274e-03 1.2297e-02 -6.0000e+00 3.0080e-01 1.6798e-04 -9.0257e-04 7.9936e-05 2.3737e-04 -6.0000e+00 2.3310e-02 2.9798e-03 -5.2308e-05 12 8 8 10 0 0 98.60 23.88 0.19 0.00298 -0.00380 133 28 1 5 0 371.550 27.45 20.00 23.88 18.22 36.2 1012.26 -237316 -280138 -269600 -139523 -223231 -113623 -210708 -282173 -235094 -275545 -211117 -244952 -159680 -95822 -45127 -115649 -98193 -94736 16949 -49251 -20396 -41744 -39023 -71088 -68758 -79141 -34922 -85212 -47558 36464 476 -16109 -22784 -41162 31274 -16684 -1591 -10947 7676 8358 9189 3819 9107 7309 20908 75 23189 21332 12669 11275 13204 9533 14497 23782 4863 10615 12381 7025 4698 3421 6814 7830 9021 13005 9364 11751 3794 3345 6951 7818 5747 3561 4333 3744 425 211 -2276 -256 -1637 368 553 632 -2284 -386 -815 527 -205 310 -147 182 -51 1337 -2039 -1686 -583 -826 -648 -254 -702 -885 -2010 -2157 -1476 -682 -2062 -2012 -1436 -838 -340 47 -147 -224 -241 -112 -192 458 793 388 715 763 508 851 1570 1165 986 -1418 427 1653 594 61 227 -542 -109 -128 -94 -240 -31 526 88 -61 39 -678 -668 -1952 -3828 -3557 -538 -1894 -321 -1679 -4654 -2659 -5064 -2496 -4617 -1888 -813 -302 -1771 -1481 -1562 109 -646 -204 -526 -502 -1239 -1247 -1660 -521 -1948 -868 337 8 -361 -633 -1352 587 -476 -43 -392 277 325 400 190 456 386 996 5 1185 1192 783 788 1029 874 1408 2301 566 1216 1421 842 563 415 843 1077 1416 2221 1776 2226 754 719 1624 2056 1679 1096 1290 1044 111 51 -544 -64 -488 129 217 284 -1166 -208 -469 317 -122 188 -88 111 -29 729 -1157 -1034 -386 -649 -599 -253 -758 -957 -2056 -1996 -1325 -607 -1958 -1918 -1456 -924 -420 63 -220 -341 -374 -170 -297 692 1216 594 1141 1235 802 1345 2363 1699 1394 -1996 593 2454 972 115 454 -1183 -243 -306 -229 -614 -82 1368 226 -148 92 -1525 -1476 SS 20240519T110021.0Z 8905.458577 162 1 49.50 2 78.89 72.93 122.75 298.48 0.00 1 0.00 1 0 17 4.455e-01 7.322e-03 4.347e-02 1.088e-03 7.266806e-01 6.018457e-04 8.304602e-03 -6.000000e+00 2.701410e-01 231.15 -2.00 3.58 -2.00 320.96 0.00e+00 4.190346e-03 2.733506e-04 2.306303e-03 -6.000000e+00 1.175561e-02 280.72 -2.00 20.00 -2.00 320.40 0.00e+00 5.006 0.002 302.00 328.00 3 7.3433e-01 1.9423e-03 6.3261e-02 -6.0000e+00 6.7624e-01 6.2881e-02 2.6148e-03 4.0911e-02 -6.0000e+00 7.3258e-01 -5.9539e-02 2.6304e-03 2.2751e-02 -6.0000e+00 4.3493e-01 1.1077e-02 1.2611e-03 8.3750e-03 -6.0000e+00 1.7921e-01 9.0022e-04 -6.6315e-04 3.1184e-05 1.2080e-04 -6.0000e+00 1.3883e-02 2.3198e-03 -3.8250e-05 11 9 0 11 8 0 75.42 23.87 0.19 0.00232 -0.00266 362 77 1 5 0 136.580 27.45 20.00 23.87 19.81 36.2 1021.32 -169800 -150526 -141470 -151230 -138036 -171054 -140730 -141080 -113212 -149895 -93965 -127870 -69679 -70572 -45178 -59539 -44689 -37697 -15096 -35063 -8893 -27883 -15152 -36042 -23322 -29600 -18255 -35290 -17238 -18987 -7584 -8870 -5984 -12351 -4679 -9137 -4121 -7626 1483 -2389 1255 -771 1601 -1297 2594 185 3659 1251 3730 2335 3965 3892 4476 3535 2244 2623 1501 674 89 956 1656 3235 3481 3919 1741 1246 725 902 2173 2652 1281 916 705 867 -519 -734 -2040 -1215 -570 -364 -1239 -922 -2404 -1106 -1099 -390 282 300 433 493 111 275 -984 -6 -34 -26 421 652 -3 -255 -777 -1136 -351 445 -1228 -1571 -953 -799 135 497 380 122 101 -104 -44 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