File name: Pandora169s1_Egbert_20240618_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20241106T172534.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20240618_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20240618 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240618T105057.0Z 8935.452049 131 1 49.22 2 78.88 68.05 131.27 284.22 0.00 1 0.00 1 0 17 3.527e-01 1.965e-02 1.328e-01 5.565e-03 6.445554e-01 3.064880e-03 8.156869e-03 -6.000000e+00 2.147836e-01 232.88 -2.00 3.58 -2.00 320.96 0.00e+00 7.650549e-03 1.298196e-03 4.867418e-03 -6.000000e+00 9.429540e-03 283.82 -2.00 20.00 -2.00 320.32 0.00e+00 5.001 0.002 302.00 328.00 3 3.6912e+00 9.8521e-03 6.2675e-02 -6.0000e+00 5.3937e-01 3.3153e-01 1.2375e-02 4.1925e-02 -6.0000e+00 5.8363e-01 -4.5359e-01 1.0146e-02 2.3348e-02 -6.0000e+00 3.4659e-01 1.7731e-01 4.9063e-03 8.0544e-03 -6.0000e+00 1.4242e-01 4.9767e-05 -1.2344e-03 1.6930e-04 1.5917e-04 -6.0000e+00 1.1001e-02 1.2412e-02 -2.0612e-04 12 9 8 11 8 0 35.94 23.26 0.13 0.01241 0.00314 25 5 1 5 0 1967.640 26.83 19.99 23.26 30.67 37.5 1050.68 207181 -100580 482 -34792 3554 -51477 -27951 -137532 -102129 -110365 -107512 -134774 -65306 -74479 -26187 -59746 -50725 -40129 -638 -20612 23864 -10897 -13738 -40520 -37823 -24517 -15312 -58249 -3126 39610 13917 43041 -38876 -40752 29724 -3800 16120 8945 15774 -724 17956 25745 8507 9453 22345 11801 25646 6328 18918 11760 12498 14629 11619 25406 5222 11238 7438 6328 -678 4184 3514 3508 6911 11114 5334 10281 101 1164 2070 7553 4747 4996 3657 3285 -1663 89 -5928 -4164 -630 -3486 -1611 -2486 -1840 -3197 -2482 1306 218 -1328 701 164 212 2141 -857 -3999 -365 -776 -399 -1917 -2236 -1514 -1404 -3557 -3532 -1392 -1753 -873 -1041 -302 45 53 325 300 82 283 -410 119 295 586 747 1367 929 572 1616 2091 882 757 33 1944 526 -46 462 -299 -450 396 516 18 40 360 -37 -97 -193 -1198 -1658 1124 -2790 6 -543 37 -846 -389 -5116 -2976 -3568 -3582 -6419 -2107 -3169 -883 -3041 -2628 -2037 -24 -957 765 -466 -613 -2351 -2211 -1298 -745 -4039 -139 1340 673 1857 -3718 -4061 1580 -273 1062 720 1389 -83 1902 2687 1073 1208 2590 1533 3010 910 2539 1796 2067 2589 2274 4662 1193 2498 1723 1464 -164 974 866 948 2010 3374 1754 3197 34 410 794 3057 2107 2268 1647 1401 -683 33 -2245 -1610 -264 -1730 -895 -1543 -1222 -2277 -1856 996 174 -1095 563 128 156 1475 -596 -2996 -293 -708 -409 -2187 -2689 -1797 -1574 -3774 -3583 -1411 -1871 -972 -1222 -374 60 77 504 482 131 439 -618 175 441 908 1203 2239 1517 914 2493 3127 1291 1080 48 2877 857 -81 873 -595 -932 854 1160 41 96 858 -88 -223 -428 -2576 -3552 SS 20240618T105650.8Z 8935.456143 134 1 48.92 2 77.90 69.00 132.26 285.42 0.00 1 0.00 1 0 17 3.078e-01 1.125e-02 1.258e-01 3.812e-03 6.044589e-01 2.103088e-03 7.176074e-03 -6.000000e+00 1.874773e-01 232.88 -2.00 3.58 -2.00 320.79 0.00e+00 4.551884e-03 8.940838e-04 2.941152e-03 -6.000000e+00 8.294095e-03 283.82 -2.00 20.00 -2.00 320.15 0.00e+00 4.626 0.002 302.00 328.00 3 3.5668e+00 6.7237e-03 5.6839e-02 -6.0000e+00 4.7075e-01 3.4185e-02 8.6484e-03 3.5940e-02 -6.0000e+00 5.0956e-01 -1.0090e-01 7.8832e-03 1.9355e-02 -6.0000e+00 3.0254e-01 3.4600e-02 3.8233e-03 6.3614e-03 -6.0000e+00 1.2500e-01 8.9322e-05 -1.0745e-03 1.1853e-04 1.0535e-04 -6.0000e+00 9.6415e-03 1.3447e-02 -2.3923e-04 12 9 8 11 8 0 39.09 23.21 0.27 0.01345 0.00537 35 7 1 5 0 1397.580 26.83 19.99 23.21 30.85 37.4 1051.26 900000 -79253 12770 -110887 -37059 -50498 -121015 -91571 -75789 -141248 -97121 -119738 -84388 -33752 8496 -38215 -38014 -22677 18480 -1336 27695 10423 -35305 -13995 -42624 -12474 1971 -36184 -7932 101508 22366 25401 -39078 -26609 21431 9157 8014 6994 1229 2081 2488 7980 566 2837 7327 -1 11019 -945 1427 1997 6624 4388 1285 10264 -2930 4369 1943 1762 -2956 -82 825 1597 5420 6438 1878 5084 -23 -2044 139 3146 2562 -528 1965 573 33 336 -1854 -1848 -1033 -2114 -862 -1869 -2199 -2040 -974 133 1055 210 853 235 967 1588 -901 -1408 868 -90 278 720 -988 -145 -1589 -2049 -1818 -474 -502 -1544 -866 28 -239 661 423 -46 -199 183 84 909 -1 324 543 866 479 477 1076 892 524 -2497 375 1099 207 59 -215 -390 -593 -54 6 -208 175 590 15 65 -21 -251 -638 900000 -817 58 -1556 -254 -396 -1950 -1258 -989 -3529 -1775 -3090 -1963 -621 130 -1019 -1129 -642 389 -35 578 259 -1372 -481 -1994 -464 65 -1661 -292 1561 802 1021 -3070 -1939 1017 499 490 506 111 213 280 911 72 364 925 0 1414 -140 217 324 1132 841 274 2164 -729 1056 488 442 -765 -21 220 464 1688 2151 671 1746 -8 -783 58 1407 1235 -269 965 271 15 137 -740 -763 -471 -1117 -510 -1233 -1563 -1535 -768 110 896 183 732 196 761 1183 -674 -1103 734 -86 296 831 -1209 -175 -1838 -2225 -1896 -499 -554 -1801 -1054 36 -330 975 664 -74 -320 284 126 1331 -2 501 871 1418 782 763 1671 1351 772 -3670 537 1636 335 103 -398 -755 -1193 -112 13 -468 400 1352 34 146 -46 -524 -1329 SS 20240618T110217.7Z 8935.459927 137 1 49.80 2 76.98 69.87 133.18 286.56 0.00 1 0.00 1 0 17 2.287e-01 1.006e-02 1.004e-01 2.925e-03 5.716160e-01 1.600560e-03 6.838794e-03 -6.000000e+00 1.393255e-01 232.88 -2.00 3.58 -2.00 320.53 0.00e+00 4.248851e-03 6.229493e-04 2.701060e-03 -6.000000e+00 6.159397e-03 283.82 -2.00 20.00 -2.00 319.86 0.00e+00 4.324 0.002 302.00 328.00 3 3.4384e+00 4.9551e-03 5.3211e-02 -6.0000e+00 3.4984e-01 2.9504e-02 6.1920e-03 3.3501e-02 -6.0000e+00 3.7864e-01 -8.5519e-02 5.4171e-03 1.7738e-02 -6.0000e+00 2.2482e-01 2.6176e-02 2.6754e-03 5.7299e-03 -6.0000e+00 9.2915e-02 1.3838e-04 -7.8634e-04 9.1283e-05 9.3462e-05 -6.0000e+00 7.1627e-03 1.2852e-02 -1.5512e-04 12 8 8 10 0 0 76.45 23.18 0.31 0.01285 0.00694 49 10 1 5 0 1016.100 26.73 19.99 23.18 30.91 37.3 1051.37 900000 -94831 32719 -93409 51678 -46554 -12183 -120324 -37697 -89902 -21702 -107586 -20150 -36005 16303 -36783 -18971 -15384 1170 -34209 34695 -17753 -20151 -22059 -22666 -8188 -10372 -31027 -3037 17881 1571 5737 -18680 -21554 -938 -4411 -4292 -3283 -3049 571 -2993 2046 452 2789 2665 4111 4059 4522 1341 2959 3321 7507 2499 6738 -1964 4866 783 1513 -2142 2585 -443 3692 3882 4982 1475 4441 -941 -53 458 2668 1092 1238 1699 1315 -956 187 -2265 -1929 -466 -1283 -1125 -1764 -2862 -1772 -491 228 545 -259 910 -33 730 1149 -444 -1499 493 -481 180 74 -530 -379 -1287 -2441 -1083 -428 -974 -1242 -409 -688 717 207 706 108 416 251 175 375 267 260 567 391 357 407 1109 553 591 -2107 265 1238 541 -217 18 -562 -399 -93 -97 -42 246 258 -12 107 280 -643 -527 900000 -1543 171 -1527 211 -481 -99 -2885 -472 -1916 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