File name: Pandora169s1_Egbert_20240625_L2Fit_fout2c12d20201119p1-8.txt File generation date: 20240626T052937.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v12d20201119.txt Level 1 file used: Pandora169s1_Egbert_20240625_L1_smca1c12d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20240625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB data based on session 9 First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0720 305.2131 305.3541 305.4952 305.6362 305.7772 305.9182 306.0591 306.2001 306.3411 306.4820 306.6229 306.7639 306.9048 307.0457 307.1865 307.3274 307.4683 307.6091 307.7500 307.8908 308.0316 308.1724 308.3132 308.4540 308.5948 308.7355 308.8763 309.0170 309.1577 309.2984 309.4391 309.5798 309.7205 309.8612 310.0018 310.1425 310.2831 310.4237 310.5643 310.7049 310.8455 310.9861 311.1266 311.2672 311.4077 311.5482 311.6887 311.8292 311.9697 312.1102 312.2507 312.3911 312.5316 312.6720 312.8124 312.9528 313.0932 313.2336 313.3740 313.5143 313.6547 313.7950 313.9354 314.0757 314.2160 314.3563 314.4965 314.6368 314.7771 314.9173 315.0575 315.1978 315.3380 315.4782 315.6183 315.7585 315.8987 316.0388 316.1790 316.3191 316.4592 316.5993 316.7394 316.8795 317.0195 317.1596 317.2996 317.4396 317.5797 317.7197 317.8597 317.9996 318.1396 318.2796 318.4195 318.5595 318.6994 318.8393 318.9792 319.1191 319.2590 319.3988 319.5387 319.6785 319.8183 319.9582 320.0980 320.2377 320.3775 320.5173 320.6570 320.7968 320.9365 321.0762 321.2160 321.3556 321.4953 321.6350 321.7747 321.9143 322.0540 322.1936 322.3332 322.4728 322.6124 322.7520 322.8915 323.0311 323.1706 323.3101 323.4497 323.5892 323.7286 323.8681 324.0076 324.1471 324.2865 324.4259 324.5653 324.7048 324.8442 324.9835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240625T124853.4Z 8942.533951 254 1 49.18 2 58.66 86.85 86.16 238.03 0.00 1 0.00 1 0 17 1.107e-02 7.205e-03 2.431e-03 9.012e-04 2.824375e-01 4.886184e-04 3.457336e-03 -6.000000e+00 6.836249e-03 232.93 -2.00 3.58 -2.00 316.86 0.00e+00 3.202590e-04 6.263095e-05 1.679297e-04 -6.000000e+00 2.977060e-04 284.47 -2.00 20.00 -2.00 316.12 0.00e+00 1.915 0.000 302.00 328.00 3 4.0620e+00 1.2896e-03 2.4188e-02 -6.0000e+00 1.7177e-02 1.6577e-03 1.4319e-03 1.5148e-02 -6.0000e+00 1.8475e-02 -5.0671e-03 8.4303e-04 7.3397e-03 -6.0000e+00 1.0972e-02 -3.8416e-03 4.0301e-04 2.0075e-03 -6.0000e+00 4.6399e-03 9.9101e-04 -1.0248e-03 2.8268e-05 2.6351e-05 -6.0000e+00 3.4228e-04 -1.2751e-01 0.0000e+00 11 9 0 11 8 0 99.87 22.67 0.03 -0.12751 -0.13521 62 13 1 5 0 792.990 26.21 20.00 22.67 24.71 37.2 1007.76 900000 788 -1519 420 -2732 -2538 -1346 -806 -432 -669 -2521 -4120 -2889 -1591 -542 257 -643 -1132 511 716 1333 1437 518 1491 1243 1079 1244 -206 -691 238 1074 1578 1902 659 -1940 -2872 -2584 -3237 -1693 -892 -1004 -909 -354 -329 -309 328 77 -139 -203 -913 8 610 645 990 864 527 1146 904 328 -121 180 785 1601 2017 1882 140 -127 -348 -539 1107 927 222 478 522 853 272 -310 -739 -1364 -609 -1060 -1389 -1688 -2297 -1751 -753 -387 253 204 552 441 516 117 -429 345 529 133 562 666 9 -268 -706 -1352 -586 190 -844 -1112 -797 -993 40 590 657 326 169 -61 -159 276 284 457 667 314 -122 273 415 344 754 -232 -179 1323 689 326 -55 -498 -392 105 82 -85 82 504 -147 -146 -425 -1026 900000 98 -208 57 -366 -317 -163 -103 -60 -102 -406 -685 -498 -300 -114 60 -162 -301 139 202 384 421 154 451 393 356 419 -70 -226 75 335 515 660 243 -736 -1073 -970 -1314 -765 -454 -564 -543 -218 -207 -195 207 48 -87 -125 -564 5 393 435 693 626 391 862 686 250 -92 137 609 1296 1709 1645 122 -107 -284 -440 940 843 212 467 509 808 247 -265 -602 -1098 -508 -952 -1340 -1726 -2453 -1931 -859 -458 308 251 674 526 589 127 -449 358 571 152 686 852 11 -350 -889 -1640 -696 230 -1068 -1455 -1071 -1373 56 864 985 491 249 -86 -217 366 378 626 948 460 -181 400 597 484 1029 -310 -235 1744 944 466 -81 -745 -595 163 131 -140 136 847 -248 -243 -693 -1649 SS 20240625T125915.4Z 8942.541150 257 1 7.00 2 56.80 88.61 87.66 239.86 0.00 1 0.00 1 0 17 1.221e-02 7.461e-03 4.721e-03 1.986e-03 2.708460e-01 1.078608e-03 3.320488e-03 -6.000000e+00 7.540894e-03 232.93 -2.00 3.58 -2.00 316.58 0.00e+00 3.864657e-04 1.289487e-04 1.348522e-04 -6.000000e+00 3.283377e-04 284.47 -2.00 20.00 -2.00 315.85 0.00e+00 1.820 0.000 302.00 328.00 3 3.7404e+00 2.8355e-03 2.3069e-02 -6.0000e+00 1.8948e-02 4.7957e-03 3.1432e-03 1.4502e-02 -6.0000e+00 2.0378e-02 -1.1049e-02 1.8311e-03 7.0304e-03 -6.0000e+00 1.2102e-02 -8.9033e-04 8.6112e-04 1.9262e-03 -6.0000e+00 5.1194e-03 1.5240e-03 -7.9994e-04 6.2256e-05 2.5687e-05 -6.0000e+00 3.7744e-04 -1.2938e-01 0.0000e+00 12 9 1 12 1 1 62.86 22.67 0.11 -0.12938 -0.13540 11 18 1 5 0 582.530 26.21 20.00 22.67 25.29 37.1 1010.33 900000 1613 64 504 -4675 -1489 -2093 815 -3216 294 -3753 -2153 -4712 -1771 -311 549 -1774 -302 -563 852 1427 877 1494 968 1465 935 1582 894 -1243 677 1017 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-1021 40 1050 1086 310 456 -245 15 -121 410 489 888 565 -52 203 710 488 900 289 88 1346 1297 -91 268 -759 -245 323 238 -335 -70 743 -246 -121 -1105 -1653 SS 20240625T132226.3Z 8942.557249 267 1 49.66 2 52.65 92.69 91.13 243.87 0.00 1 0.00 1 0 25 1.054e-02 7.435e-03 1.298e-03 6.200e-04 2.451913e-01 3.379775e-04 3.016110e-03 -6.000000e+00 6.511009e-03 232.93 -2.00 3.58 -2.00 316.24 0.00e+00 3.811484e-04 3.718413e-05 1.034820e-04 -6.000000e+00 2.835389e-04 284.47 -2.00 20.00 -2.00 315.52 0.00e+00 1.644 0.000 302.00 328.00 3 3.6594e+00 8.8472e-04 2.0854e-02 -6.0000e+00 1.6360e-02 1.4531e-03 9.7845e-04 1.3117e-02 -6.0000e+00 1.7596e-02 -3.8719e-03 5.6635e-04 6.3651e-03 -6.0000e+00 1.0450e-02 -3.6196e-03 2.6168e-04 1.7469e-03 -6.0000e+00 4.4193e-03 2.0389e-03 -9.0860e-04 1.9516e-05 2.3965e-05 -6.0000e+00 3.2598e-04 -1.2775e-01 0.0000e+00 11 8 0 10 0 0 99.18 22.63 0.16 -0.12775 -0.13458 126 27 1 5 0 393.930 26.21 20.00 22.63 26.53 37.3 1017.27 900000 28 -686 -1209 -2137 -2555 -832 -1099 76 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