File name: Pandora169s1_Egbert_20240710_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20241108T134558.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20240710_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20240710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240710T175249.8Z 8957.745021 311 1 3.08 2 22.89 196.99 56.06 115.44 0.00 1 0.00 1 0 17 9.773e-03 7.850e-03 1.936e-03 1.468e-03 1.576484e-01 8.031071e-04 1.910487e-03 -6.000000e+00 5.968576e-03 233.03 -2.00 3.58 -2.00 314.42 0.00e+00 4.506969e-04 6.209823e-05 1.714406e-05 -6.000000e+00 2.634342e-04 285.86 -2.00 20.00 -2.00 313.82 0.00e+00 1.085 0.000 302.00 328.00 3 3.2861e+00 2.0705e-03 1.3551e-02 -6.0000e+00 1.4985e-02 2.3693e-02 2.2856e-03 8.3383e-03 -6.0000e+00 1.6194e-02 -2.6566e-03 1.3047e-03 4.0145e-03 -6.0000e+00 9.6290e-03 -3.8915e-03 5.4683e-04 1.1110e-03 -6.0000e+00 3.9739e-03 5.9662e-03 2.1993e-04 4.6481e-05 1.7192e-05 -6.0000e+00 3.0474e-04 2.3180e-03 3.8774e-05 12 9 1 12 1 1 98.28 22.95 0.24 0.00232 0.00397 11 41 1 5 0 256.140 26.51 20.00 22.95 22.32 37.7 981.68 1509 -431 -89 -3572 -2147 -1332 252 1748 165 -1433 -2461 -936 -167 166 690 -210 -417 1148 554 1449 385 259 1402 1749 927 1348 -581 -861 -3 1094 1293 1765 1290 -1769 -3044 -1272 -1893 -573 -285 -195 -860 -630 -907 -571 -477 -235 -1175 -354 -712 417 1017 812 936 750 304 1490 786 111 69 619 1215 1706 1435 1224 -75 -838 -324 -198 1080 777 62 533 243 514 106 -296 -592 -820 -25 -694 -1247 -1812 -2606 -1778 -1066 -663 103 9 504 131 746 -292 17 366 809 35 580 720 15 -414 -456 -1126 -140 174 -969 -1610 -594 -776 40 382 426 338 414 95 14 339 470 -1 743 236 -56 175 619 570 844 455 166 1536 566 256 90 -373 -331 38 -177 -328 -4 269 -124 3 -151 -674 -946 595 -182 -37 -1424 -807 -479 93 700 69 -622 -1070 -409 -74 82 354 -115 -225 624 310 821 222 149 812 1046 555 816 -350 -509 -2 605 731 1042 762 -1070 -1785 -734 -1198 -382 -213 -158 -729 -535 -786 -495 -410 -199 -1008 -290 -589 341 823 693 805 669 278 1367 707 100 63 570 1115 1656 1434 1221 -76 -815 -301 -180 991 763 63 567 259 525 104 -283 -535 -708 -22 -658 -1227 -1883 -2808 -2003 -1236 -792 125 11 620 159 858 -317 18 376 863 39 672 875 18 -501 -534 -1283 -159 199 -1163 -1999 -742 -1010 52 509 583 459 548 120 17 405 561 -1 935 307 -75 233 798 723 1042 551 194 1831 691 320 113 -481 -435 50 -240 -454 -6 388 -181 4 -209 -937 -1310 SS 20240710T175716.2Z 8957.748104 314 1 1.11 2 23.14 199.54 55.37 116.44 0.00 1 0.00 1 0 17 1.019e-02 7.990e-03 1.383e-03 1.047e-03 1.567087e-01 5.726348e-04 1.905110e-03 -6.000000e+00 6.220496e-03 233.03 -2.00 3.58 -2.00 314.43 0.00e+00 4.063945e-04 4.446572e-05 1.484242e-05 -6.000000e+00 2.745908e-04 285.86 -2.00 20.00 -2.00 313.84 0.00e+00 1.087 0.000 302.00 328.00 3 1.6447e+00 1.4756e-03 1.3544e-02 -6.0000e+00 1.5618e-02 1.3659e-02 1.6295e-03 8.3045e-03 -6.0000e+00 1.6879e-02 -1.5502e-03 9.3027e-04 4.0028e-03 -6.0000e+00 1.0036e-02 -4.4267e-03 3.9037e-04 1.1095e-03 -6.0000e+00 4.1409e-03 3.0920e-02 2.6642e-04 3.3057e-05 1.6843e-05 -6.0000e+00 3.1765e-04 3.4332e-03 3.4139e-05 12 9 1 12 1 1 99.25 22.95 0.24 0.00343 0.00544 23 229 1 5 0 46.150 26.51 20.00 22.95 22.54 37.8 983.50 1562 159 -748 -3217 -3147 -1114 148 1222 372 -1704 -2843 -1104 -594 204 647 -221 -461 724 883 1332 847 580 1698 1200 1352 839 9 -705 179 1159 1830 2032 1682 -1616 -3410 -2124 -1602 -451 190 -688 -1073 -653 -599 -878 -278 -319 -821 -430 -641 158 992 656 1044 999 446 1109 794 235 284 435 1040 1698 1437 1186 -242 -719 -443 -494 1337 913 -87 375 316 566 155 -219 -635 -729 -236 -715 -1455 -1696 -2653 -1769 -975 -629 147 180 336 286 286 154 -181 579 717 209 542 572 -129 -397 -620 -1117 -308 591 -892 -1296 -798 -962 -175 530 560 380 291 211 71 398 373 177 458 76 -217 214 506 530 1051 722 235 1334 912 304 97 -394 -255 230 -30 -311 -41 239 -155 -187 -255 -873 -848 607 66 -308 -1257 -1192 -399 55 492 153 -731 -1224 -478 -276 98 340 -117 -251 398 497 763 491 337 990 729 805 510 6 -420 99 655 1053 1157 999 -986 -2028 -1250 -1024 -297 139 -546 -880 -554 -517 -762 -238 -270 -707 -356 -515 126 811 566 897 889 408 1021 708 218 261 402 949 1638 1415 1203 -242 -693 -411 -451 1270 883 -91 391 329 587 156 -209 -555 -638 -213 -681 -1476 -1795 -2890 -1940 -1133 -749 176 221 410 345 332 169 -190 587 757 231 631 694 -157 -492 -725 -1277 -355 677 -1069 -1591 -1019 -1237 -233 710 770 518 391 271 88 479 449 215 575 98 -288 280 667 669 1296 879 276 1560 1120 380 121 -506 -334 301 -41 -435 -59 338 -221 -269 -357 -1198 -1155 SS 20240710T180143.0Z 8957.751193 317 1 1.08 2 23.42 202.05 54.69 117.46 0.00 1 0.00 1 0 17 1.111e-02 8.770e-03 4.276e-03 3.269e-03 1.567625e-01 1.786884e-03 1.887269e-03 -6.000000e+00 6.782153e-03 233.03 -2.00 3.58 -2.00 314.38 0.00e+00 5.783472e-04 1.369254e-04 1.933766e-05 -6.000000e+00 2.995403e-04 285.86 -2.00 20.00 -2.00 313.79 0.00e+00 1.089 0.000 302.00 328.00 3 3.5136e+00 4.6037e-03 1.3534e-02 -6.0000e+00 1.7027e-02 2.3541e-02 5.0817e-03 8.2757e-03 -6.0000e+00 1.8406e-02 -1.8357e-04 2.9016e-03 3.9736e-03 -6.0000e+00 1.0944e-02 -2.4785e-03 1.2160e-03 1.1284e-03 -6.0000e+00 4.5129e-03 4.7309e-03 -5.1557e-04 1.0316e-04 1.6889e-05 -6.0000e+00 3.4661e-04 3.9701e-03 -9.6601e-05 12 9 1 12 1 1 999.00 22.94 0.17 0.00397 0.00010 2 29 1 5 0 356.980 26.51 19.99 22.94 22.80 37.8 984.79 1698 346 -1369 -3508 -3196 -1805 -36 390 615 -1708 -3334 -875 -200 -537 1327 272 -1164 1379 683 2242 286 1110 2087 1595 916 1364 -515 -450 -151 1007 2405 836 1395 -635 -3883 -1515 -1230 185 187 -187 -1021 -1026 -538 -411 -914 -591 -742 -244 -1522 724 765 662 1235 1315 177 902 343 179 608 568 1536 876 1960 1734 -466 -1328 -348 -485 1376 951 762 433 122 137 155 -460 94 -490 -399 -791 -1763 -2179 -3424 -1650 -960 -757 -143 -287 155 633 728 -42 108 552 410 344 524 387 -206 -30 -506 -817 39 615 -1303 -1176 -473 -863 74 497 449 561 145 -8 229 735 325 -220 756 442 -166 308 619 583 583 890 162 1328 373 164 23 -791 -366 534 150 -183 -215 177 -174 -13 -91 -1051 -800 683 145 -578 -1429 -1221 -667 -14 157 260 -746 -1466 -384 -93 -266 690 148 -650 769 389 1283 167 644 1217 954 563 844 -317 -267 -86 563 1355 491 836 -384 -2337 -901 -770 126 140 -150 -859 -882 -467 -357 -793 -509 -629 -203 -1249 587 633 564 1077 1170 160 821 314 164 552 518 1425 845 1942 1748 -468 -1283 -321 -443 1285 940 785 456 129 142 154 -435 84 -428 -356 -746 -1763 -2284 -3733 -1836 -1102 -900 -174 -354 190 758 836 -46 113 568 432 379 606 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