File name: Pandora169s1_Egbert_20240810_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20241108T142255.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20240810_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T105246.6Z 8988.453317 54 1 49.64 2 84.88 73.54 142.51 34.75 0.00 1 0.00 1 0 25 6.598e-01 4.138e-02 3.259e-01 1.882e-02 1.042977e+00 1.124428e-02 1.153013e-02 -6.000000e+00 4.080059e-01 232.04 -2.00 3.58 -2.00 322.33 0.00e+00 -7.920841e-03 5.321443e-03 7.749868e-04 -6.000000e+00 1.834577e-02 286.74 -2.00 20.00 -2.00 321.76 0.00e+00 9.630 0.017 302.00 328.00 3 3.7869e-01 4.1647e-02 1.0997e-01 -6.0000e+00 1.0204e+00 1.9120e+00 5.3039e-02 5.7390e-02 -6.0000e+00 1.1044e+00 -2.3339e+00 3.4690e-02 2.8539e-02 -6.0000e+00 6.5575e-01 8.9088e-01 1.6866e-02 1.0094e-02 -6.0000e+00 2.7338e-01 1.0488e-05 -1.4996e-03 5.0978e-04 1.5279e-04 -6.0000e+00 2.0760e-02 3.0952e-03 -1.4037e-04 12 8 8 10 0 0 17.58 23.40 0.67 0.00310 -0.00817 31 7 1 5 0 1600.740 27.05 20.00 23.40 19.48 37.4 946.28 900000 33484 168110 258644 55459 900000 12002 -6838 3807 -75926 5113 -76743 39195 178808 189156 65306 27597 11360 171480 23158 174788 179143 72621 -1663 -9776 50465 13778 -37108 5796 900000 -14012 900000 -76098 32518 382740 28621 143520 37945 200 35874 62848 49436 71463 65583 137623 39083 900000 43695 3413 85034 32298 43264 33445 900000 12686 71193 55263 29525 -12262 33248 4026 -6819 19494 33230 26817 138716 -1683 8861 22605 80306 41994 10739 60707 6446 3294 25865 -9168 -14290 18777 786 23958 13794 4270 3089 -808 18875 826 -6043 3032 -85 4652 45881 6146 -4393 27426 -3348 -2321 -8476 -16503 1078 -3993 -10606 -4306 -6329 -12359 -3115 -482 6647 2689 -3424 -4349 -1122 -1462 4078 1482 1101 -2211 -717 -1392 3811 3253 -1197 2132 4303 -1531 588 2526 5421 1147 -1120 426 1203 -1078 668 225 -252 447 1554 -360 -588 513 -641 -3227 900000 2456 3082 4742 1955 900000 575 -405 204 -8887 267 -9741 1916 3278 3468 3293 1907 913 3144 1470 3204 3284 2552 -127 -758 2236 800 -3175 301 900000 -1049 900000 -11698 1788 7017 1443 2631 2087 19 2631 3745 3399 3821 3507 3670 2448 900000 2603 318 3767 2665 3503 3219 900000 1667 5330 4813 3158 -1836 2946 474 -959 2353 3858 3483 6473 -301 1530 3799 8466 6929 2257 7976 1320 614 3438 -1667 -2925 3213 178 5102 3735 1403 1098 -316 6335 342 -2702 1210 -33 1640 11215 2115 -1859 9902 -1824 -1480 -6604 -15106 830 -3028 -7736 -2712 -4045 -8821 -2154 -349 4962 2395 -3775 -5530 -1509 -2052 5426 1989 1472 -3127 -1046 -1991 5600 4657 -1703 2815 5398 -1985 733 3136 7205 1861 -2025 860 2653 -2644 1745 633 -701 1256 4328 -999 -1645 1309 -1538 -7747 SS 20240810T110431.4Z 8988.461474 57 1 49.56 2 82.85 75.53 141.34 38.82 0.00 1 0.00 1 0 17 7.512e-01 1.727e-02 2.241e-01 4.172e-03 9.067297e-01 2.418407e-03 1.027715e-02 -6.000000e+00 4.568632e-01 232.04 -2.00 3.58 -2.00 322.04 0.00e+00 6.333059e-03 1.524355e-03 4.578791e-03 -6.000000e+00 2.032270e-02 286.74 -2.00 20.00 -2.00 321.52 0.00e+00 7.390 0.008 302.00 328.00 3 5.5478e-01 9.9637e-03 9.0005e-02 -6.0000e+00 1.1438e+00 4.7888e-01 1.4648e-02 5.6575e-02 -6.0000e+00 1.2371e+00 -6.8395e-01 1.3910e-02 3.1530e-02 -6.0000e+00 7.3658e-01 2.7859e-01 6.1222e-03 1.0837e-02 -6.0000e+00 3.0468e-01 1.0073e-04 -1.3774e-03 1.1541e-04 2.0703e-04 -6.0000e+00 2.3424e-02 2.2970e-03 -1.3768e-04 12 8 8 10 0 0 19.47 23.41 0.24 0.00230 -0.00805 122 26 1 5 0 406.200 27.05 20.00 23.41 19.77 37.4 948.03 -161070 -270478 -208635 -125790 -165352 121663 -186859 -282258 -140359 -275361 -166274 -235002 -164028 -47308 -88641 -114744 -119686 -85797 35206 -95193 -42010 -52398 -78646 -70416 -86948 -43482 -62126 -102456 -66525 354514 -20306 21058 -43107 -9753 41515 10883 2156 19172 27030 14032 25269 17475 24747 11043 36639 14315 62271 35857 6952 20877 31855 22600 20655 37821 7237 21840 18111 14223 7459 12570 14042 10991 20947 22986 11765 21466 7147 7637 9603 11338 11814 3817 8026 6304 1326 5763 -189 -1100 143 161 2294 1769 -599 -1326 -922 1794 745 -294 592 862 755 2140 -1608 -2615 -748 -394 -1711 -665 -2123 -697 -2670 -3394 -2448 -1270 -3042 -2673 -2068 -1005 -613 -27 -418 -506 -340 -217 -538 -62 451 315 693 706 929 1125 1553 1801 1060 310 409 1584 827 243 227 -342 -214 -134 184 -142 177 593 189 45 71 -1117 -1307 -953 -5043 -2392 -605 -1101 495 -1590 -6220 -882 -6535 -1599 -5019 -2487 -297 -1082 -2023 -2556 -1587 208 -1969 -559 -775 -1571 -1380 -1946 -708 -1218 -2744 -1427 1442 -398 335 -1374 -256 645 233 56 496 780 495 891 717 990 520 1366 689 1942 1556 405 1176 1824 1605 1661 2793 717 2098 1836 1478 748 1278 1476 1239 2465 2999 1839 3119 1240 1423 1847 2432 2743 989 1940 1440 288 1171 -37 -234 35 48 795 665 -255 -611 -451 904 396 -161 318 444 368 990 -781 -1398 -456 -268 -1393 -615 -2156 -700 -2563 -2967 -1962 -1005 -2580 -2400 -1979 -1045 -679 -34 -596 -734 -505 -318 -812 -92 678 497 1077 1115 1427 1739 2295 2567 1475 423 562 2339 1341 455 453 -747 -501 -322 471 -380 482 1623 511 117 169 -2666 -3063 SS 20240810T111535.0Z 8988.469155 60 1 49.40 2 80.93 77.39 140.14 42.48 0.00 1 0.00 1 0 17 6.214e-01 8.211e-03 9.660e-02 1.727e-03 7.919735e-01 9.777052e-04 9.146939e-03 -6.000000e+00 3.780532e-01 232.04 -2.00 3.58 -2.00 321.45 0.00e+00 3.768940e-03 5.351897e-04 3.980097e-03 -6.000000e+00 1.681222e-02 286.74 -2.00 20.00 -2.00 320.87 0.00e+00 6.010 0.004 302.00 328.00 3 5.2852e-01 3.5714e-03 7.4914e-02 -6.0000e+00 9.4653e-01 7.1038e-02 5.1408e-03 4.9354e-02 -6.0000e+00 1.0236e+00 -8.8669e-02 5.1760e-03 2.6210e-02 -6.0000e+00 6.0947e-01 2.6365e-02 2.3724e-03 7.9584e-03 -6.0000e+00 2.5218e-01 4.2354e-04 -7.8495e-04 4.8749e-05 1.4684e-04 -6.0000e+00 1.9376e-02 9.9575e-04 -1.1119e-04 11 8 0 10 0 0 -0.21 23.43 0.17 0.00100 -0.00490 269 57 1 5 0 183.620 27.05 20.00 23.43 20.27 37.3 950.62 -226289 -251790 -200230 -157253 -177626 -154617 -199916 -204389 -178198 -208574 -178169 -174367 -148746 -57384 -61332 -78669 -98831 -64857 -37129 -39973 -29006 -45234 -38962 -47911 -41832 -40723 -46001 -55672 -24260 -4354 -19063 -13673 -15097 -28776 -6962 -22838 -13867 -6939 -1005 -2184 2429 -1510 3961 185 6213 -1497 6429 767 2997 1582 6313 5110 7623 5506 3634 3623 4863 1182 261 2419 2968 3775 5358 5687 3035 2292 2361 856 2489 4060 1933 697 809 860 -705 -27 -1820 -1111 -974 308 -515 -569 -2074 -1208 -828 121 208 417 654 718 94 598 -1249 -364 25 -83 -6 647 -412 -293 -935 -1931 -918 480 -1662 -1453 -1210 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