File name: Pandora169s1_Egbert_20241011_L2Fit_fwvt1c18d20240515p1-8.txt File generation date: 20241108T150816.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20241011_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20241011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1799 Nominal wavelengths inside fitting window [nm]: 492.0857 492.2066 492.3274 492.4482 492.5690 492.6897 492.8105 492.9312 493.0519 493.1726 493.2933 493.4140 493.5346 493.6552 493.7759 493.8965 494.0170 494.1376 494.2582 494.3787 494.4992 494.6197 494.7402 494.8607 494.9811 495.1016 495.2220 495.3424 495.4628 495.5832 495.7035 495.8239 495.9442 496.0645 496.1848 496.3051 496.4253 496.5456 496.6658 496.7860 496.9062 497.0264 497.1466 497.2667 497.3868 497.5069 497.6270 497.7471 497.8672 497.9872 498.1073 498.2273 498.3473 498.4673 498.5872 498.7072 498.8271 498.9470 499.0669 499.1868 499.3067 499.4266 499.5464 499.6662 499.7860 499.9058 500.0256 500.1453 500.2651 500.3848 500.5045 500.6242 500.7439 500.8635 500.9832 501.1028 501.2224 501.3420 501.4616 501.5811 501.7007 501.8202 501.9397 502.0592 502.1787 502.2981 502.4176 502.5370 502.6564 502.7758 502.8952 503.0146 503.1339 503.2532 503.3726 503.4918 503.6111 503.7304 503.8496 503.9689 504.0881 504.2073 504.3265 504.4456 504.5648 504.6839 504.8030 504.9221 505.0412 505.1603 505.2794 505.3984 505.5174 505.6364 505.7554 505.8744 505.9933 506.1123 506.2312 506.3501 506.4690 506.5878 506.7067 506.8255 506.9444 507.0632 507.1820 507.3007 507.4195 507.5382 507.6569 507.7757 507.8943 508.0130 508.1317 508.2503 508.3689 508.4876 508.6061 508.7247 508.8433 508.9618 509.0804 509.1989 509.3174 509.4358 509.5543 509.6727 509.7912 509.9096 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241011T113652.2Z 9050.483938 27 1 49.46 2 89.57 100.65 161.14 345.13 0.00 1 0.00 1 0 50 2.150e-02 2.128e-02 1.111e-03 1.104e-03 8.492945e+03 7.230189e+01 5.134532e+02 -6.000000e+00 1.214849e+03 280.80 -2.00 20.00 -2.00 505.43 0.00e+00 3.520387e-03 3.094766e-05 1.809623e-04 -6.000000e+00 6.063707e-04 280.80 -2.00 20.00 -2.00 501.25 0.00e+00 3.256261e-01 2.125329e-02 8.573422e-02 -6.000000e+00 4.312813e-01 225.71 -2.00 3.58 -2.00 502.72 0.00e+00 19.890 0.154 489.00 513.00 1 5.4398e+00 1.6264e-03 3.5999e-02 -6.0000e+00 3.3087e-02 -3.4901e-02 4.0796e-04 2.6095e-03 -6.0000e+00 8.5411e-03 5.0110e-04 2.9503e-03 1.1667e-04 8.9218e-05 -6.0000e+00 2.3820e-03 1.0840e-02 2.6027e-05 12 8 8 10 0 0 92.39 23.07 14.93 0.01084 0.03130 17 4 1 4 0 2909.140 26.62 20.01 23.07 11.96 37.4 917.72 -5973 -4361 -1864 -73 1281 2360 3146 3020 2377 1479 -73 -984 -1845 -2403 -2600 -1910 -698 454 1430 1431 1899 1778 1807 2320 2288 2074 1430 -58 -1915 -3652 -3702 -2648 -1062 862 2140 1393 628 144 -182 -289 -67 824 1583 2398 2693 2679 2436 1378 46 -1457 -3238 -4252 -3806 -2751 -674 1022 1875 2412 2323 2562 2658 2889 3051 2710 2088 1024 -40 -410 -1561 -2019 -2158 -1880 -1274 -841 -682 -1703 -2690 -3437 -3547 -3410 -3040 -2614 -1814 -1940 -1072 -1183 -1153 -970 -1060 -242 904 1737 2492 2680 2198 1440 174 -1552 -2651 -4105 -3715 -2750 -816 394 879 -33 -994 -1344 -1683 -722 245 1355 2036 3041 3471 4025 4008 3797 2349 1823 549 447 434 1108 1868 1406 1280 1260 895 133 -532 -1610 -2208 -2427 -2349 -1300 -390 341 909 1107 1012 1177 1250 1701 1046 267 -1259 -2510 -3536 -3410 -5342 -3936 -1633 -65 1156 2153 2890 2793 2204 1368 -68 -910 -1703 -2216 -2406 -1775 -654 415 1320 1335 1773 1669 1706 2195 2179 1981 1367 -55 -1823 -3467 -3498 -2510 -1019 837 2019 1331 602 138 -174 -276 -64 796 1541 2349 2657 2651 2404 1358 45 -1420 -3143 -4113 -3671 -2675 -661 1015 1882 2349 2274 2511 2617 2857 3025 2693 2072 1016 -40 -403 -1537 -1983 -2121 -1856 -1266 -841 -684 -1712 -2696 -3430 -3524 -3384 -3023 -2610 -1817 -1967 -1090 -1212 -1144 -993 -1051 -239 895 1730 2484 2656 2228 1437 172 -1521 -2580 -4019 -3651 -2746 -802 397 902 -35 -1041 -1407 -1772 -738 252 1401 2118 3163 3627 4224 4247 4049 2530 1950 587 473 460 1171 1974 1501 1372 1354 966 140 -558 -1688 -2381 -2538 -2475 -1381 -418 370 997 1228 1101 1288 1376 1869 1154 294 -1386 -2753 -3885 -3758 SQ 20241011T114013.5Z 9050.486267 31 1 48.91 2 88.99 101.24 161.27 347.31 0.00 1 0.00 1 0 15 2.002e-02 1.970e-02 9.799e-04 9.735e-04 8.311114e+03 6.401706e+01 5.066481e+02 -6.000000e+00 1.131262e+03 280.80 -2.00 20.00 -2.00 505.45 0.00e+00 3.304950e-03 2.720720e-05 1.745963e-04 -6.000000e+00 5.645317e-04 280.80 -2.00 20.00 -2.00 501.29 0.00e+00 3.222628e-01 1.874997e-02 8.330282e-02 -6.000000e+00 4.012229e-01 225.71 -2.00 3.58 -2.00 502.75 0.00e+00 18.656 0.127 489.00 513.00 1 5.3633e+00 1.4343e-03 3.2441e-02 -6.0000e+00 3.0786e-02 -4.4065e-02 3.5913e-04 2.4423e-03 -6.0000e+00 7.9379e-03 6.4393e-04 1.2769e-05 1.0357e-04 8.7537e-05 -6.0000e+00 2.2169e-03 4.0237e-02 -8.6042e-05 12 8 8 10 0 0 69.22 23.08 13.92 0.04024 0.04033 24 5 1 4 0 2037.530 26.62 20.01 23.08 11.96 37.5 918.11 -5597 -3961 -1908 -221 1388 2244 2902 3014 2190 1279 310 -603 -1829 -2640 -2677 -1755 -674 521 1490 1366 1683 1620 1795 2010 2149 1870 1236 -219 -1867 -3542 -3602 -2586 -1192 723 1762 1342 869 282 -158 -34 -155 795 1441 2317 2548 2660 2119 1280 202 -1275 -2862 -3882 -3838 -2535 -885 704 1589 2034 2017 1620 2475 2716 2777 2332 1815 1206 219 -639 -1528 -1760 -2107 -1923 -1183 -713 -663 -1411 -2426 -3070 -3233 -3442 -2707 -2416 -1967 -1579 -1175 -1014 -992 -705 -770 -61 756 1572 2392 2478 2217 1114 209 -1090 -2465 -3808 -3810 -2620 -890 51 577 -216 -944 -1385 -1372 -1028 -5 1095 2001 2804 3252 3707 3630 3698 2309 1836 545 317 534 1122 1599 1108 1215 1007 910 368 -202 -1386 -1957 -2250 -2036 -1200 -363 300 685 1000 1039 1085 1181 1478 832 340 -1036 -2152 -3309 -3031 -4902 -3496 -1707 -201 1277 2016 2631 2745 2004 1169 283 -548 -1664 -2405 -2442 -1604 -621 487 1406 1305 1611 1503 1672 1882 2022 1767 1169 -208 -1756 -3317 -3354 -2414 -1128 692 1706 1313 850 275 -154 -34 -153 785 1386 2240 2483 2597 2071 1247 196 -1225 -2733 -3691 -3648 -2421 -856 689 1576 2029 2022 1635 2491 2745 2817 2296 1783 1219 221 -643 -1537 -1760 -2112 -1937 -1157 -702 -656 -1397 -2395 -3015 -3161 -3373 -2647 -2376 -1946 -1574 -1180 -1023 -1004 -711 -779 -61 766 1602 2440 2518 2224 1105 204 -1053 -2371 -3677 -3703 -2578 -893 51 587 -224 -979 -1437 -1425 -1075 -5 1159 2127 2893 3370 3861 3820 3907 2464 1945 577 333 559 1173 1677 1174 1291 1073 971 394 -216 -1482 -2085 -2399 -2183 -1299 -386 322 746 1100 1154 1214 1329 1663 913 371 -1131 -2407 -3708 -3398 SQ 20241011T114330.6Z 9050.488549 35 1 48.21 2 88.41 101.81 161.38 349.48 0.00 1 0.00 1 0 36 1.931e-02 1.902e-02 9.923e-04 9.864e-04 7.221319e+03 6.357580e+01 4.339334e+02 -6.000000e+00 1.091355e+03 280.80 -2.00 20.00 -2.00 505.44 0.00e+00 3.045679e-03 2.759105e-05 1.589839e-04 -6.000000e+00 5.447132e-04 280.80 -2.00 20.00 -2.00 501.25 0.00e+00 2.476183e-01 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