File name: Pandora169s1_Egbert_20241219_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20241220T052345.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20241219_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20241219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241219T133829.4Z 9119.568396 304 1 49.97 2 84.00 131.31 63.87 269.00 0.00 1 0.00 1 0 17 9.123e-01 4.426e-02 3.664e-01 1.523e-02 1.048659e+00 9.349950e-03 1.139627e-02 -6.000000e+00 5.535318e-01 222.26 -2.00 3.58 -2.00 322.30 0.00e+00 1.686834e-02 4.805011e-03 1.206210e-02 -6.000000e+00 2.638145e-02 272.65 -2.00 20.00 -2.00 321.87 0.00e+00 8.563 0.012 302.00 328.00 3 1.1628e+00 3.2714e-02 1.2884e-01 -6.0000e+00 1.3606e+00 1.7913e+00 4.2591e-02 1.2972e-01 -6.0000e+00 1.4918e+00 -2.1073e+00 3.9251e-02 4.8378e-02 -6.0000e+00 8.7956e-01 8.0470e-01 1.9601e-02 1.3161e-02 -6.0000e+00 3.7113e-01 1.1878e-05 -2.4088e-03 4.3146e-04 1.6851e-04 -6.0000e+00 2.9926e-02 -9.5514e-03 -1.2960e-04 12 8 8 10 0 0 90.89 23.23 0.38 -0.00955 -0.02765 30 6 1 5 0 1665.310 26.83 19.99 23.23 1.13 36.4 913.28 900000 66489 900000 900000 469387 900000 900000 -13399 102179 85340 153346 -101223 -19628 900000 900000 89803 38260 80726 162018 900000 900000 273848 -12798 900000 -62506 148376 -25339 -64145 900000 900000 112817 900000 -57570 71348 900000 44726 149355 143937 101641 5499 394402 310062 117180 59617 167068 78942 900000 82758 121956 25361 78950 104564 -84604 324452 30403 50844 102519 29015 21006 17535 10926 1316 41755 76401 48951 95862 14074 10152 11761 44224 45000 23812 54295 27153 -5725 52302 28788 -13302 20021 5091 18951 12073 7008 10033 -4685 13449 5497 3255 9491 5427 134 27992 5596 -16553 15925 2049 -2139 -3141 -6904 3570 -1358 -5866 -10485 -4396 -4311 224 -6208 3616 -2104 -3681 -3805 -2020 -3303 341 -3392 994 -3477 2177 -413 4080 781 17 1705 3847 229 2129 2380 5538 121 -1039 1547 1628 -489 -21 543 79 81 350 1159 -277 1076 -1453 -4099 900000 2053 900000 900000 6952 900000 900000 -416 1513 1264 2271 -6820 -803 900000 900000 2452 1818 2706 2525 900000 900000 4056 -726 900000 -4925 2198 -1265 -4316 900000 900000 2116 900000 -6594 2616 900000 1837 2337 2564 2980 417 5842 4592 3552 3036 3137 3368 900000 3649 3986 2117 4453 5085 -23201 4806 3226 4495 5583 2883 2110 1749 1177 168 4214 6360 5534 7332 2255 1774 2207 6853 7314 4696 7848 4558 -1148 5707 3738 -2663 3466 1199 4618 3547 2351 3465 -1927 4887 2205 1344 3650 2081 51 8019 1983 -7794 6498 1125 -1439 -2445 -6067 2896 -1087 -4411 -7473 -2886 -2923 153 -4810 2808 -1952 -3988 -4687 -2665 -4586 459 -4656 1297 -4809 2980 -601 5758 1101 23 2174 4677 281 2519 2841 6973 185 -1850 3021 3470 -1138 -53 1416 213 223 967 3120 -721 2574 -3314 -9259 SS 20241219T134931.7Z 9119.576061 307 1 49.53 2 82.54 133.39 65.83 270.84 0.00 1 0.00 1 0 17 6.448e-01 1.879e-02 1.402e-01 3.973e-03 9.492145e-01 2.241312e-03 1.045867e-02 -6.000000e+00 3.787004e-01 222.26 -2.00 3.58 -2.00 321.97 0.00e+00 1.158372e-02 1.200112e-03 1.457638e-03 -6.000000e+00 1.647059e-02 272.65 -2.00 20.00 -2.00 321.55 0.00e+00 7.148 0.007 302.00 328.00 3 7.5244e-01 7.9023e-03 8.6985e-02 -6.0000e+00 9.3117e-01 6.5299e-01 1.1342e-02 5.7179e-02 -6.0000e+00 1.0161e+00 -8.7515e-01 1.1923e-02 2.9841e-02 -6.0000e+00 6.0456e-01 3.5349e-01 5.5524e-03 1.5424e-02 -6.0000e+00 2.5225e-01 9.6748e-05 -1.4326e-03 1.0805e-04 2.3760e-04 -6.0000e+00 2.0036e-02 -1.0140e-02 -1.0450e-04 12 9 8 11 8 0 91.04 23.22 0.19 -0.01014 -0.02091 105 22 1 5 0 471.600 26.83 20.00 23.22 1.28 36.2 913.44 -116101 -196141 -195927 -173415 -196191 -110839 -209942 -229143 -187424 -248798 -188042 -172970 -142709 -21660 -94556 -65135 -113808 -61357 -66721 -70888 -36879 -20828 -112653 -76143 -101073 -63764 -69020 -84407 -69279 43538 -22044 29656 -27693 -26828 11179 -11012 -3879 7121 7658 31018 16487 20480 15871 26089 29993 11061 50796 39027 24782 25939 36538 35068 -8029 39344 19949 28468 24566 15100 10255 12687 11145 12210 19808 24290 17496 20575 14167 13925 9674 13741 12611 6738 11246 6636 2955 5013 213 -2710 2984 -88 2900 2239 -480 -365 -750 626 1386 -248 660 -419 -461 439 -1872 -5233 -466 -1877 -1928 -900 -1621 -1433 -1403 -3257 -1559 -1223 -2921 -2650 -2664 -1383 -679 -263 -592 -667 -699 -732 -612 -395 -61 642 738 911 740 1642 2379 1651 1213 1263 121 2072 1068 244 467 -77 -276 56 57 -181 110 734 237 147 -157 -1193 -1848 -765 -3040 -3175 -2138 -2764 -687 -3180 -4359 -2443 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-2.00 321.18 0.00e+00 6.153 0.004 302.00 328.00 3 1.1633e+00 4.9566e-03 7.5442e-02 -6.0000e+00 1.0337e+00 1.4319e-01 7.5594e-03 4.9405e-02 -6.0000e+00 1.1280e+00 -1.7147e-01 8.6899e-03 2.8121e-02 -6.0000e+00 6.7113e-01 6.2811e-02 4.0415e-03 1.4608e-02 -6.0000e+00 2.8004e-01 1.8755e-04 -7.8638e-04 7.3238e-05 1.8746e-04 -6.0000e+00 2.2241e-02 -1.0212e-02 -9.8435e-05 12 8 8 10 0 0 93.82 23.20 0.16 -0.01021 -0.01612 151 32 1 5 0 327.490 26.83 20.00 23.20 1.35 36.3 914.53 -176977 -259458 -276606 -121368 -244358 -73667 -251448 -264153 -240395 -233381 -233932 -70853 -169097 103647 -121840 -52064 -135607 -7235 -48973 5501 -65849 29482 -98762 -40793 -85183 -49796 -97005 -65977 -51442 82943 -58961 25364 -39186 7263 -9690 14309 -28886 7915 -22692 -1178 -2535 13405 1853 10350 7641 3983 14054 11198 1508 10389 12240 11124 -9463 14444 4069 9073 4378 295 2050 1633 2099 6373 8167 5890 5589 6705 3267 1428 3874 5217 3407 1013 3782 1128 46 -753 215 -2491 1463 -548 543 -220 -1677 -1835 -372 -849 994 -555 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