File name: Pandora169s1_Egbert_20241220_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20241221T052540.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20241220_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20241220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241220T172847.2Z 9120.728324 411 1 49.26 2 67.72 182.90 99.42 295.66 0.00 1 0.00 1 0 17 4.246e-02 7.798e-03 1.842e-02 2.313e-03 3.992123e-01 1.187916e-03 4.821405e-03 -6.000000e+00 2.494728e-02 222.31 -2.00 3.58 -2.00 318.53 0.00e+00 7.295433e-04 2.432918e-04 3.146533e-04 -6.000000e+00 1.084481e-03 272.58 -2.00 20.00 -2.00 317.99 0.00e+00 2.616 0.000 302.00 328.00 3 5.0431e+00 3.1776e-03 3.2463e-02 -6.0000e+00 6.1350e-02 2.9356e-02 3.6252e-03 2.0382e-02 -6.0000e+00 6.6940e-02 -6.0949e-03 2.5340e-03 1.0306e-02 -6.0000e+00 3.9826e-02 -9.1161e-03 1.3290e-03 3.0501e-03 -6.0000e+00 1.6616e-02 1.6393e-04 -6.0784e-04 7.2676e-05 3.8503e-05 -6.0000e+00 1.3195e-03 -1.0300e-02 -8.2467e-05 11 8 0 10 0 0 99.30 23.12 0.24 -0.01030 -0.01487 17 4 1 5 0 2897.210 26.73 20.00 23.12 2.37 36.4 920.96 20713 -2191 21467 -2721 902 14324 19617 -938 436 -12321 -5432 -16288 -5285 7331 4176 -6131 -1697 -3414 1780 -459 6453 -737 -390 -3708 -1986 -1824 51 -7656 195 4477 1295 4639 -3903 -4725 -1576 -5264 -699 -1335 -406 -2521 -442 417 -1159 -1961 1003 350 999 -53 -1055 56 1557 1541 -4650 3715 1084 1751 827 921 -871 261 712 1747 2603 3077 112 381 -952 -202 160 2152 947 1177 624 129 -330 41 -1610 -965 191 -469 -1156 -1331 -2425 -1708 -1203 -183 -168 213 421 69 255 1201 -131 -430 920 234 369 627 -289 -158 -618 -1325 -613 41 -323 -1288 -771 -608 -147 402 475 185 529 292 4 314 202 107 308 160 -245 -77 549 225 465 76 161 926 656 283 154 -661 -634 74 63 -186 -220 672 86 204 -128 -528 -588 631 -90 739 -113 34 472 657 -42 21 -713 -308 -1102 -372 540 367 -662 -190 -413 216 -59 798 -99 -54 -560 -313 -297 8 -1276 30 670 217 833 -819 -1028 -328 -1141 -158 -350 -123 -886 -166 164 -476 -821 412 145 413 -22 -449 25 708 748 -2510 1971 606 1001 482 535 -508 151 422 1091 1729 2144 80 265 -650 -138 116 1662 782 999 530 106 -258 30 -1122 -662 137 -371 -1004 -1246 -2411 -1763 -1291 -204 -193 248 488 78 275 1223 -130 -427 953 262 446 806 -387 -211 -794 -1623 -725 49 -401 -1672 -1032 -842 -212 606 743 293 827 442 6 443 285 156 463 247 -383 -119 827 331 664 107 221 1283 952 434 245 -1087 -1064 128 112 -341 -409 1256 160 376 -230 -930 -1027 SS 20241220T173439.4Z 9120.732400 414 1 48.20 2 67.79 184.36 100.35 296.71 0.00 1 0.00 1 0 17 6.052e-02 8.230e-03 2.617e-02 2.895e-03 3.943368e-01 1.486611e-03 4.729561e-03 -6.000000e+00 3.556716e-02 222.31 -2.00 3.58 -2.00 318.70 0.00e+00 1.295356e-03 3.205125e-04 1.914238e-04 -6.000000e+00 1.545986e-03 272.58 -2.00 20.00 -2.00 318.16 0.00e+00 2.623 0.000 302.00 328.00 3 5.3756e+00 3.9979e-03 3.2345e-02 -6.0000e+00 8.7466e-02 1.5731e-02 4.5771e-03 2.0147e-02 -6.0000e+00 9.5428e-02 8.7216e-03 3.2776e-03 1.0205e-02 -6.0000e+00 5.6775e-02 -1.3631e-02 1.7234e-03 3.2255e-03 -6.0000e+00 2.3693e-02 1.1762e-04 -2.8644e-04 9.1577e-05 3.9379e-05 -6.0000e+00 1.8808e-03 -1.1224e-02 -5.1201e-05 11 9 0 11 32 0 99.96 23.12 0.38 -0.01122 -0.01338 16 3 1 5 0 3011.930 26.73 20.00 23.12 2.64 36.6 922.81 26319 -717 17880 -4801 -7125 19953 44748 -6489 3385 -7353 -6406 -21451 -5254 11547 8277 -6208 -3188 -6901 -9 2497 7305 3890 -3583 -4350 -3841 665 -942 -6066 -2735 9071 3194 10300 -5348 -3526 910 -5662 1733 -1550 -1771 -3788 -1334 306 -770 -2165 483 867 1190 -770 -987 -979 1210 872 -1354 3281 305 1526 533 592 -1049 1500 80 1151 1686 2363 -651 1036 -500 -926 131 2225 833 757 1107 1053 -853 607 -1016 -1402 450 -525 -588 -1288 -3012 -1995 -1073 1 224 -202 549 852 628 1874 -381 -130 1297 411 604 546 -628 -110 -655 -1670 -981 340 -333 -1370 -1053 -583 -133 105 439 -10 401 137 -252 456 281 599 218 363 -344 -94 461 124 260 33 125 1815 347 -315 244 -225 -450 281 -157 -297 -4 543 170 133 -215 -572 -509 691 -26 577 -184 -263 569 1086 -276 145 -367 -330 -1373 -335 742 637 -610 -330 -786 -1 286 819 456 -465 -603 -561 97 -139 -910 -390 1192 483 1616 -1049 -701 171 -1138 354 -377 -506 -1257 -473 113 -296 -855 188 338 463 -305 -396 -406 523 404 -679 1664 164 834 298 330 -586 821 46 695 1090 1602 -456 694 -329 -616 92 1669 672 630 915 842 -652 426 -682 -933 313 -404 -498 -1184 -2963 -2037 -1140 1 256 -234 632 953 670 1876 -373 -127 1324 456 726 702 -844 -147 -841 -2044 -1156 404 -413 -1780 -1414 -811 -192 159 692 -16 633 209 -369 645 398 870 330 564 -541 -146 700 185 373 46 171 2504 507 -487 391 -373 -762 489 -284 -551 -8 1031 324 249 -392 -1020 -900 SS 20241220T174108.9Z 9120.736909 417 1 50.65 2 67.89 185.96 101.37 297.88 0.00 1 0.00 1 0 17 4.473e-02 8.253e-03 1.742e-02 2.247e-03 3.947886e-01 1.154350e-03 4.762969e-03 -6.000000e+00 2.629087e-02 222.31 -2.00 3.58 -2.00 318.56 0.00e+00 1.671807e-03 2.386412e-04 3.262479e-04 -6.000000e+00 1.142745e-03 272.58 -2.00 20.00 -2.00 318.02 0.00e+00 2.635 0.000 302.00 328.00 3 4.9922e+00 3.0898e-03 3.2445e-02 -6.0000e+00 6.4654e-02 2.1670e-02 3.5274e-03 2.0150e-02 -6.0000e+00 7.0538e-02 -4.5864e-03 2.4736e-03 1.0274e-02 -6.0000e+00 4.1966e-02 -8.6346e-03 1.2965e-03 3.3518e-03 -6.0000e+00 1.7515e-02 1.7081e-04 -3.7361e-04 7.0868e-05 4.0451e-05 -6.0000e+00 1.3902e-03 -1.1693e-02 -5.3623e-05 11 8 0 10 0 0 99.93 23.12 0.16 -0.01169 -0.01450 20 4 1 5 0 2532.110 26.73 20.00 23.12 2.82 36.4 923.12 26231 -7010 12660 3624 -6769 13356 -4065 -1489 -7523 -10199 -11195 -21861 -12936 10946 572 3368 -57 2688 -2013 6718 3716 5176 -3496 -1704 -5680 1019 -1841 -7056 -5703 8637 -40 6267 -4939 -2316 -3539 -3244 -1378 -1393 -1921 -305 -1930 176 -667 -453 408 596 -415 677 -1037 283 1863 1287 -3667 985 581 1612 1566 263 -557 787 635 1942 2314 2784 343 26 -198 -810 917 1739 1025 1108 1034 660 -385 -204 -1051 -1876 214 -1039 -478 -1921 -2360 -1887 -754 -146 403 -17 883 499 371 903 -425 -1035 1149 313 270 512 -327 -500 -636 -1927 -704 667 -871 -1505 -879 -686 130 407 745 180 454 327 12 534 264 477 214 32 -396 -87 110 591 494 418 -157 1395 782 -75 -173 -404 -543 95 198 -316 -60 556 -129 370 -120 -276 -899 766 -304 475 143 -275 447 -168 -66 -388 -570 -657 -1529 -963 771 51 331 -6 305 -251 805 468 650 -491 -249 -907 158 -294 -1148 -899 1227 -7 1096 -1035 -488 -742 -683 -310 -360 -583 -104 -724 68 -269 -185 167 245 -172 279 -437 122 838 620 -1947 529 323 912 898 152 -320 448 374 1202 1531 1932 245 18 -133 -553 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