File name: Pandora169s1_Egbert_20241228_L2Fit_fwvt1c18d20240515p1-8.txt File generation date: 20241229T053017.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20241228_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20241228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1799 Nominal wavelengths inside fitting window [nm]: 492.0857 492.2066 492.3274 492.4482 492.5690 492.6897 492.8105 492.9312 493.0519 493.1726 493.2933 493.4140 493.5346 493.6552 493.7759 493.8965 494.0170 494.1376 494.2582 494.3787 494.4992 494.6197 494.7402 494.8607 494.9811 495.1016 495.2220 495.3424 495.4628 495.5832 495.7035 495.8239 495.9442 496.0645 496.1848 496.3051 496.4253 496.5456 496.6658 496.7860 496.9062 497.0264 497.1466 497.2667 497.3868 497.5069 497.6270 497.7471 497.8672 497.9872 498.1073 498.2273 498.3473 498.4673 498.5872 498.7072 498.8271 498.9470 499.0669 499.1868 499.3067 499.4266 499.5464 499.6662 499.7860 499.9058 500.0256 500.1453 500.2651 500.3848 500.5045 500.6242 500.7439 500.8635 500.9832 501.1028 501.2224 501.3420 501.4616 501.5811 501.7007 501.8202 501.9397 502.0592 502.1787 502.2981 502.4176 502.5370 502.6564 502.7758 502.8952 503.0146 503.1339 503.2532 503.3726 503.4918 503.6111 503.7304 503.8496 503.9689 504.0881 504.2073 504.3265 504.4456 504.5648 504.6839 504.8030 504.9221 505.0412 505.1603 505.2794 505.3984 505.5174 505.6364 505.7554 505.8744 505.9933 506.1123 506.2312 506.3501 506.4690 506.5878 506.7067 506.8255 506.9444 507.0632 507.1820 507.3007 507.4195 507.5382 507.6569 507.7757 507.8943 508.0130 508.1317 508.2503 508.3689 508.4876 508.6061 508.7247 508.8433 508.9618 509.0804 509.1989 509.3174 509.4358 509.5543 509.6727 509.7912 509.9096 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241228T185947.5Z 9128.791522 289 1 49.37 2 71.14 203.93 86.99 225.58 0.00 1 0.00 1 0 15 3.191e-03 3.185e-03 7.965e-04 7.951e-04 2.579094e+03 4.726804e+01 2.014239e+02 -6.000000e+00 1.742093e+02 272.08 -2.00 20.00 -2.00 505.25 0.00e+00 5.370880e-04 2.153452e-05 3.190327e-05 -6.000000e+00 8.817910e-05 272.08 -2.00 20.00 -2.00 500.42 0.00e+00 1.389353e-01 1.597217e-02 1.885097e-02 -6.000000e+00 6.427119e-02 222.64 -2.00 3.58 -2.00 502.01 0.00e+00 3.057 0.001 489.00 513.00 1 7.2932e+00 1.2211e-03 4.5968e-03 -6.0000e+00 4.9150e-03 1.5048e-02 3.1500e-04 5.2530e-04 -6.0000e+00 1.2750e-03 8.5655e-04 -4.4556e-06 8.5362e-05 3.0648e-05 -6.0000e+00 3.5376e-04 -1.2465e-02 -1.9249e-05 10 0 0 10 0 0 99.98 23.15 1.36 -0.01247 -0.01250 35 7 1 4 0 1410.190 26.73 20.00 23.15 13.82 38.0 991.72 -590 -370 80 92 153 266 803 592 519 261 116 35 -144 -404 -180 -353 -356 95 276 181 179 83 206 319 474 219 424 281 -46 -602 -636 -464 -454 157 654 52 -178 65 -287 -187 -370 13 -52 165 224 269 88 150 46 -199 -440 -787 -899 -548 -437 123 -22 105 -119 -155 191 406 278 334 551 224 203 171 -114 -160 -408 -244 -142 57 163 -134 -358 -375 -442 -423 -279 -320 -304 -113 -61 -195 -50 -172 -113 -132 -39 27 533 406 482 168 54 35 -103 -555 -657 -675 -279 10 156 -202 -145 -242 -244 -171 -92 -118 117 201 193 196 440 632 339 430 132 64 183 135 315 -22 159 333 208 154 153 -198 -42 -369 -414 -121 65 -101 -45 190 94 171 208 500 157 317 -41 -297 -321 -394 -584 -360 79 95 157 278 847 613 552 276 121 36 -146 -406 -180 -355 -363 99 284 188 188 87 216 335 499 231 443 290 -48 -613 -638 -465 -465 160 678 55 -187 67 -295 -191 -378 13 -54 172 235 282 92 155 46 -202 -437 -768 -870 -533 -434 124 -23 107 -122 -158 195 414 284 342 557 224 201 172 -113 -157 -399 -238 -140 57 163 -133 -352 -364 -425 -405 -268 -309 -297 -111 -59 -190 -49 -168 -111 -129 -39 27 535 409 481 166 52 34 -98 -520 -614 -641 -272 10 155 -203 -144 -238 -239 -167 -91 -115 116 200 194 198 445 638 341 427 130 64 181 133 312 -22 154 321 206 151 150 -191 -40 -348 -391 -115 63 -97 -44 186 93 170 208 501 158 315 -40 -286 -304 -381 SQ 20241228T212352.6Z 9128.891582 359 1 32.89 2 87.29 233.35 107.92 248.48 0.00 1 0.00 1 0 22 7.749e-03 7.661e-03 4.790e-04 4.778e-04 9.183028e+03 3.132909e+01 6.551127e+02 -6.000000e+00 4.230105e+02 272.07 -2.00 20.00 -2.00 505.38 0.00e+00 3.068830e-03 1.308922e-05 1.683859e-04 -6.000000e+00 2.141155e-04 272.07 -2.00 20.00 -2.00 500.95 0.00e+00 8.822609e-01 9.405165e-03 7.290097e-02 -6.000000e+00 1.560591e-01 222.64 -2.00 3.58 -2.00 502.47 0.00e+00 14.312 0.057 489.00 513.00 1 4.2544e+00 7.1778e-04 2.2603e-02 -6.0000e+00 1.1934e-02 -4.4988e-02 1.8116e-04 2.0867e-03 -6.0000e+00 3.0957e-03 3.4301e-03 6.6637e-04 5.0037e-05 1.1347e-04 -6.0000e+00 8.5901e-04 6.9887e-04 -9.3453e-05 12 9 9 12 1 1 91.03 23.13 4.13 0.00070 0.00532 45 15 1 4 0 714.870 26.73 19.99 23.13 13.96 38.0 991.33 -1768 -1181 -418 265 562 981 1424 1450 1201 781 498 33 -452 -714 -924 -874 -397 161 453 477 513 461 596 711 953 863 683 347 -352 -1147 -1329 -1166 -645 246 654 247 -21 -66 -244 -359 -260 -49 291 602 716 722 616 458 137 -510 -1196 -1553 -1680 -1390 -600 82 265 304 334 398 654 903 980 940 768 514 122 -231 -416 -699 -851 -767 -501 -246 -7 -425 -828 -1072 -1086 -1215 -1099 -995 -782 -539 -309 -403 -435 -411 -334 -139 143 639 1072 1181 1063 759 355 -237 -836 -1484 -1792 -1652 -974 -237 14 -143 -501 -754 -744 -420 -26 298 673 792 979 1279 1485 1452 1073 735 296 145 227 403 641 449 506 492 462 490 246 -349 -581 -783 -743 -339 -99 -50 163 370 454 437 509 680 558 307 -155 -807 -1307 -1138 -1612 -1065 -386 245 534 930 1368 1404 1165 754 475 31 -425 -682 -863 -821 -378 156 437 466 504 456 590 707 932 847 669 337 -344 -1104 -1266 -1115 -628 239 650 249 -21 -66 -243 -357 -259 -48 290 606 728 737 627 462 136 -500 -1178 -1506 -1622 -1354 -595 81 269 306 338 402 662 918 999 959 780 517 121 -228 -415 -694 -842 -761 -500 -244 -7 -421 -814 -1064 -1068 -1192 -1080 -984 -762 -530 -306 -403 -436 -411 -334 -139 144 636 1072 1179 1069 748 349 -229 -793 -1399 -1694 -1589 -945 -232 14 -143 -504 -756 -745 -422 -26 307 698 813 1010 1327 1554 1531 1134 772 308 149 232 412 658 465 526 512 481 509 255 -359 -593 -798 -760 -351 -103 -53 171 393 487 473 543 728 598 327 -167 -860 -1381 -1199 SQ 20241228T212658.5Z 9128.893732 363 1 49.36 2 87.73 233.91 108.42 248.93 0.00 1 0.00 1 0 29 8.991e-03 8.872e-03 5.178e-04 5.162e-04 9.558567e+03 3.400535e+01 6.754728e+02 -6.000000e+00 4.908016e+02 272.07 -2.00 20.00 -2.00 505.41 0.00e+00 3.366308e-03 1.415177e-05 1.840747e-04 -6.000000e+00 2.484224e-04 272.07 -2.00 20.00 -2.00 501.02 0.00e+00 8.531010e-01 1.013075e-02 7.841337e-02 -6.000000e+00 1.810239e-01 222.64 -2.00 3.58 -2.00 502.52 0.00e+00 15.467 0.072 489.00 513.00 1 4.6276e+00 7.7319e-04 2.4971e-02 -6.0000e+00 1.3844e-02 -4.7834e-02 1.9461e-04 2.2485e-03 -6.0000e+00 3.5897e-03 2.0104e-03 5.8606e-04 5.3816e-05 1.1789e-04 -6.0000e+00 9.9666e-04 2.8981e-04 -6.6726e-05 12 8 8 10 0 0 99.89 23.13 5.35 0.00029 0.00435 77 16 1 4 0 640.880 26.73 20.00 23.13 13.81 38.4 991.42 -2113 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