File name: Pandora169s1_Egbert_20250519_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20250520T053450.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20250519_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20250519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250519T120739.6Z 9270.505319 211 1 27.35 2 67.12 84.01 66.52 200.37 0.00 1 0.00 1 0 17 2.264e-02 6.306e-03 6.414e-03 7.586e-04 4.386639e-01 4.025769e-04 5.187910e-03 -6.000000e+00 1.376200e-02 231.09 -2.00 3.58 -2.00 318.66 0.00e+00 9.812033e-04 8.659042e-05 3.515336e-04 -6.000000e+00 5.978396e-04 280.62 -2.00 20.00 -2.00 317.98 0.00e+00 2.551 0.000 302.00 328.00 3 2.2296e+00 1.1014e-03 3.4337e-02 -6.0000e+00 3.4448e-02 2.6992e-02 1.2566e-03 2.3279e-02 -6.0000e+00 3.7282e-02 -2.3653e-03 8.7015e-04 1.1430e-02 -6.0000e+00 2.2134e-02 -1.0207e-02 4.5003e-04 3.2878e-03 -6.0000e+00 9.1531e-03 2.6546e-03 -2.0755e-04 2.3627e-05 3.9784e-05 -6.0000e+00 7.0524e-04 -1.8858e-02 -2.4762e-05 12 1 1 12 1 1 99.98 23.23 0.11 -0.01886 -0.02042 193 75 1 5 0 140.970 26.83 20.00 23.23 11.43 38.4 970.38 -2597 -1652 -8692 -4854 -10214 -4874 -8085 -3284 -5520 -6136 -10297 -6845 -5294 -749 -1343 -60 -772 874 -266 1245 143 151 502 163 -1010 -217 -2785 -3542 -1858 -114 1059 1158 1125 -2238 -3851 -3240 -2861 -1796 -251 -613 -1021 -887 -376 -1248 -101 -367 -416 -650 -576 256 1214 842 1207 1114 638 1295 1016 137 -27 261 828 1849 2138 2035 461 -480 -24 -199 1058 1492 522 504 527 621 90 -456 -595 -1044 -282 -565 -1154 -1302 -2101 -1706 -845 -478 149 234 447 381 314 396 -229 307 650 239 396 617 85 -303 -709 -1124 -491 544 -684 -1481 -976 -1029 -220 514 437 224 91 173 36 273 494 376 357 -21 -361 120 546 512 619 393 -160 1231 702 156 -11 -527 -445 61 -38 -245 -188 441 -35 23 98 -536 -429 -80 -57 -337 -175 -365 -163 -298 -130 -249 -278 -510 -359 -320 -52 -104 -5 -74 89 -29 141 17 18 62 22 -144 -32 -424 -528 -266 -17 168 194 208 -445 -765 -645 -622 -454 -71 -202 -356 -329 -144 -493 -40 -146 -166 -261 -235 108 545 392 604 595 341 711 570 77 -15 145 472 1129 1363 1394 327 -331 -16 -133 757 1136 419 422 439 515 69 -335 -406 -707 -203 -443 -992 -1198 -2108 -1742 -913 -527 171 266 523 430 344 401 -230 307 669 266 478 795 113 -401 -919 -1397 -575 639 -863 -1924 -1284 -1433 -315 764 673 355 141 263 53 383 714 547 532 -34 -572 185 814 757 902 550 -219 1694 1013 238 -17 -879 -748 108 -69 -450 -355 840 -67 42 179 -943 -762 SS 20250519T121323.1Z 9270.509296 215 1 22.28 2 66.10 84.97 66.86 201.75 0.00 1 0.00 1 0 17 2.409e-02 6.735e-03 5.104e-03 7.680e-04 4.209782e-01 4.074111e-04 5.003521e-03 -6.000000e+00 1.464093e-02 231.09 -2.00 3.58 -2.00 318.34 0.00e+00 1.019237e-03 7.949196e-05 3.314115e-04 -6.000000e+00 6.360931e-04 280.62 -2.00 20.00 -2.00 317.65 0.00e+00 2.450 0.000 302.00 328.00 3 2.2333e+00 1.1037e-03 3.2945e-02 -6.0000e+00 3.6649e-02 2.4580e-02 1.2500e-03 2.2291e-02 -6.0000e+00 3.9667e-02 -1.0332e-02 8.2782e-04 1.0924e-02 -6.0000e+00 2.3550e-02 -6.1059e-03 4.2472e-04 3.1053e-03 -6.0000e+00 9.7364e-03 2.9904e-03 -5.2221e-04 2.3938e-05 3.7384e-05 -6.0000e+00 7.5052e-04 -1.8534e-02 -7.6005e-05 12 9 1 12 1 1 99.59 23.25 0.19 -0.01853 -0.02246 121 58 1 5 0 182.260 26.83 20.01 23.25 11.84 38.5 972.75 -3398 -7363 -2561 -9717 -10345 -7314 -5198 -6160 -5498 -8441 -8722 -8105 -3858 -2239 -262 -537 -1713 81 876 540 451 -433 401 523 -970 -196 -1724 -2876 -1798 -44 1071 1657 1172 -2113 -4084 -3360 -3308 -1504 90 -135 -1135 -708 -650 -658 56 151 -231 -91 -805 437 1143 1087 1249 1585 593 1388 942 333 -119 594 740 2011 2175 2077 374 -176 -88 -289 1023 1459 287 473 273 498 87 -370 -721 -1052 -428 -482 -1244 -1425 -2225 -1867 -779 -587 96 162 301 333 362 360 -214 365 587 226 351 589 87 -443 -677 -1276 -426 501 -770 -1558 -990 -970 -234 403 507 175 141 131 109 334 646 391 516 -40 -236 125 598 458 766 406 10 1222 792 151 8 -472 -465 49 -11 -280 -187 348 16 41 -17 -523 -608 -138 -350 -121 -475 -476 -321 -238 -320 -315 -490 -531 -534 -284 -194 -26 -61 -215 10 113 73 63 -62 59 81 -163 -34 -305 -498 -300 -7 196 338 264 -510 -986 -811 -815 -427 30 -50 -465 -289 -276 -284 24 66 -101 -40 -359 199 556 575 670 901 356 853 561 199 -75 368 448 1298 1535 1493 278 -127 -61 -202 759 1146 249 407 234 426 69 -282 -538 -774 -318 -387 -1090 -1391 -2261 -1925 -847 -651 111 192 355 378 400 384 -216 367 631 251 420 750 118 -600 -867 -1574 -514 609 -966 -2008 -1335 -1333 -330 609 787 270 221 194 156 474 910 554 772 -61 -365 188 900 663 1095 557 14 1706 1151 232 13 -759 -776 83 -18 -508 -339 636 30 75 -29 -914 -1045 SS 20250519T122313.5Z 9270.516128 223 1 18.58 2 64.34 86.62 67.50 204.11 0.00 1 0.00 1 0 17 1.833e-02 6.594e-03 6.352e-03 1.069e-03 3.934743e-01 5.668035e-04 4.677716e-03 -6.000000e+00 1.114551e-02 231.09 -2.00 3.58 -2.00 318.20 0.00e+00 9.607316e-04 1.057971e-04 2.659819e-04 -6.000000e+00 4.841369e-04 280.62 -2.00 20.00 -2.00 317.50 0.00e+00 2.295 0.000 302.00 328.00 3 2.8298e+00 1.5317e-03 3.0818e-02 -6.0000e+00 2.7899e-02 2.9346e-02 1.7314e-03 2.0816e-02 -6.0000e+00 3.0193e-02 -6.1571e-03 1.1266e-03 1.0194e-02 -6.0000e+00 1.7925e-02 -6.1677e-03 5.7352e-04 2.9202e-03 -6.0000e+00 7.4136e-03 1.9683e-03 -1.5807e-04 3.3611e-05 3.5341e-05 -6.0000e+00 5.7109e-04 -1.9405e-02 -1.1261e-05 12 9 1 12 1 1 99.97 23.26 0.17 -0.01940 -0.02059 86 50 1 5 0 213.460 26.83 20.00 23.26 12.30 38.1 973.83 1720 -1506 -4159 -6912 -6276 -2841 -6643 -2274 -5847 -4595 -7312 -5155 -3764 -542 -1986 477 -2208 2079 -365 1304 -98 408 -205 2006 -147 610 -1992 -2229 -2213 1389 653 2223 1188 -1863 -4052 -3354 -2006 -1315 -632 -475 -1644 -424 -335 -856 -171 16 -89 -256 -617 -63 1150 959 1177 1206 654 1443 1102 118 -201 282 932 1792 2024 2128 381 -575 -214 -591 1309 1390 415 528 250 303 193 -615 -546 -1213 -411 -633 -1077 -1418 -2314 -1644 -757 -495 93 112 406 402 366 400 -209 259 759 132 431 586 73 -414 -567 -1091 -530 436 -560 -1461 -900 -905 -88 492 350 280 183 225 15 346 446 370 454 -119 -376 -3 555 489 683 548 -187 1174 724 244 -36 -557 -573 74 -60 -135 -223 561 -8 8 -14 -527 -561 79 -80 -234 -385 -324 -139 -358 -131 -361 -298 -507 -378 -314 -52 -226 60 -289 278 -53 193 -15 63 -33 337 -27 115 -384 -416 -400 247 127 476 281 -442 -1022 -844 -512 -390 -210 -183 -710 -182 -149 -389 -78 7 -40 -116 -284 -30 573 518 647 702 400 901 702 75 -127 178 604 1181 1452 1554 287 -419 -156 -433 965 1142 359 474 225 261 161 -469 -402 -881 -315 -524 -969 -1361 -2322 -1739 -814 -565 107 132 475 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