File name: Pandora169s1_Egbert_20250708_L2Fit_fout2c18d20240515p1-8.txt
File generation date: 20250709T054104.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c18p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 169
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora169_OF_v5d20200220.txt
Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt
Level 1 file used: Pandora169s1_Egbert_20250708_L1_smca1c18d20240515p1-8.txt
Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert
Short location name: Egbert
Country of location: Canada
Location latitude [deg]: 44.2300
Location longitude [deg]: -79.7800
Location altitude [m]: 251
Local noon date: 20250708
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 228 370
Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250708T122630.6Z 9320.518409 190 1 10.51 2 63.68 83.58 141.76 279.42 0.00 1 0.00 1 0 17 1.247e-02 7.135e-03 2.758e-03 9.121e-04 3.069877e-01 4.882676e-04 3.687332e-03 -6.000000e+00 7.638091e-03 233.01 -2.00 3.58 -2.00 317.13 0.00e+00 6.459236e-04 6.751557e-05 1.621636e-04 -6.000000e+00 3.361999e-04 285.56 -2.00 20.00 -2.00 316.34 0.00e+00 2.242 0.000 302.00 328.00 3 2.2176e+00 1.2968e-03 2.7418e-02 -6.0000e+00 1.9179e-02 1.5904e-02 1.4497e-03 1.6374e-02 -6.0000e+00 2.0705e-02 -6.5389e-03 8.5364e-04 7.9002e-03 -6.0000e+00 1.2310e-02 -3.0977e-03 4.0532e-04 2.1596e-03 -6.0000e+00 5.0980e-03 4.4273e-03 -4.0174e-04 2.8952e-05 2.8116e-05 -6.0000e+00 3.8880e-04 -2.1891e-02 -3.5179e-05 12 9 1 12 1 1 63.23 23.22 0.18 -0.02189 -0.02491 60 61 1 5 0 172.200 26.83 20.00 23.22 25.76 39.5 1004.67 667 -1437 -1395 -3571 -4911 -3326 -894 -1022 -783 -3458 -4192 -3437 -1581 -306 -178 -167 -1279 847 927 1299 1020 629 1328 977 516 750 -522 -1345 -1043 703 1386 1788 1540 -1535 -4064 -2381 -2384 -1037 222 -26 -1101 -573 -338 -340 -290 39 -681 -322 -861 43 1196 1080 1024 1409 562 1286 1091 239 -24 255 970 1736 2035 1898 328 -752 -76 -571 1169 1211 316 292 251 538 103 -439 -508 -1110 -71 -583 -1369 -1365 -2344 -1978 -986 -554 -120 125 433 206 382 301 -356 347 676 314 294 497 -89 -441 -574 -1288 -438 435 -564 -1497 -925 -936 -221 389 536 193 240 226 99 375 537 375 370 94 -258 145 523 553 838 661 9 1242 920 232 105 -398 -321 166 -17 -185 -253 370 -33 -138 -133 -680 -700 70 -169 -168 -421 -542 -350 -97 -123 -103 -494 -618 -529 -268 -55 -37 -38 -314 214 228 330 266 166 357 277 155 233 -163 -407 -300 199 413 578 537 -567 -1497 -861 -877 -438 103 -14 -625 -342 -197 -201 -172 23 -400 -196 -523 26 724 701 673 972 405 946 816 180 -18 190 740 1341 1695 1598 281 -619 -61 -459 983 1079 296 286 246 506 95 -369 -410 -870 -58 -507 -1288 -1359 -2432 -2166 -1097 -654 -143 153 529 243 436 329 -380 360 708 349 350 627 -115 -568 -725 -1579 -528 512 -714 -1956 -1218 -1296 -310 560 810 288 359 328 138 496 731 513 520 139 -381 212 763 774 1155 901 12 1637 1245 327 157 -598 -495 257 -27 -309 -423 626 -56 -231 -221 -1095 -1146
SS 20250708T123039.9Z 9320.521295 193 1 50.45 2 62.94 84.27 142.46 280.27 0.00 1 0.00 1 0 17 1.239e-02 6.955e-03 6.796e-04 2.177e-04 2.996168e-01 1.164996e-04 3.596813e-03 -6.000000e+00 7.592465e-03 233.01 -2.00 3.58 -2.00 317.22 0.00e+00 6.573113e-04 1.655807e-05 1.669074e-04 -6.000000e+00 3.341848e-04 285.56 -2.00 20.00 -2.00 316.43 0.00e+00 2.186 0.000 302.00 328.00 3 9.3631e-01 3.0972e-04 2.6746e-02 -6.0000e+00 1.9064e-02 1.1563e-02 3.4664e-04 1.5981e-02 -6.0000e+00 2.0581e-02 -5.0083e-03 2.0506e-04 7.7068e-03 -6.0000e+00 1.2236e-02 -5.2210e-03 9.7796e-05 2.1114e-03 -6.0000e+00 5.0676e-03 1.7047e-02 -3.0741e-04 6.9310e-06 2.7117e-05 -6.0000e+00 3.8646e-04 -2.1826e-02 -2.5746e-05 11 8 0 10 0 0 98.87 23.22 0.19 -0.02183 -0.02414 1609 344 1 5 0 30.720 26.83 19.99 23.22 26.00 39.6 1006.59 916 -961 -1150 -4556 -4903 -3453 -1751 -590 -467 -2915 -4314 -3070 -1206 -591 440 8 -340 639 826 1292 710 227 1248 1223 889 785 -688 -1602 -1048 281 1304 1748 1628 -1300 -3901 -2520 -2394 -990 40 -324 -1020 -656 -488 -631 -239 7 -582 -293 -696 51 1043 1035 990 1277 562 1187 991 351 82 410 899 1739 1911 1878 210 -669 -302 -361 1163 1432 237 461 315 568 177 -395 -537 -985 -282 -563 -1335 -1509 -2327 -1813 -871 -578 -18 118 367 289 391 249 -266 388 606 170 404 593 19 -459 -581 -1254 -531 471 -592 -1489 -820 -950 -221 477 563 235 236 160 96 268 547 232 514 72 -261 84 513 476 789 561 44 1179 851 259 93 -466 -378 107 -51 -228 -183 417 -14 -41 -59 -632 -709 96 -104 -128 -539 -538 -361 -189 -70 -61 -381 -585 -432 -187 -105 89 2 -76 148 199 321 181 59 328 338 260 238 -210 -473 -294 77 377 548 549 -463 -1386 -881 -851 -404 18 -169 -558 -378 -289 -380 -144 4 -346 -171 -405 30 639 643 655 887 407 833 708 252 58 290 655 1345 1519 1577 179 -547 -244 -288 927 1264 220 445 305 529 161 -329 -431 -767 -228 -485 -1240 -1482 -2474 -1946 -989 -670 -22 141 438 347 438 267 -279 396 649 193 488 755 24 -595 -742 -1556 -627 563 -731 -1969 -1089 -1327 -312 688 853 362 353 234 134 356 723 319 723 108 -385 122 751 670 1094 744 59 1568 1158 366 139 -699 -583 165 -83 -379 -314 723 -24 -71 -98 -1047 -1158
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