File name: Pandora169s1_Egbert_20250712_L2Fit_fout2c18d20240515p1-8.txt File generation date: 20250713T054504.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt Level 1 file used: Pandora169s1_Egbert_20250712_L1_smca1c18d20240515p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20250712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0852 305.2260 305.3669 305.5077 305.6485 305.7892 305.9300 306.0708 306.2115 306.3523 306.4930 306.6337 306.7744 306.9151 307.0558 307.1965 307.3372 307.4778 307.6185 307.7591 307.8997 308.0403 308.1809 308.3215 308.4621 308.6027 308.7432 308.8838 309.0243 309.1648 309.3054 309.4459 309.5864 309.7268 309.8673 310.0078 310.1482 310.2887 310.4291 310.5695 310.7099 310.8503 310.9907 311.1311 311.2714 311.4118 311.5521 311.6924 311.8328 311.9731 312.1134 312.2536 312.3939 312.5342 312.6744 312.8147 312.9549 313.0951 313.2353 313.3755 313.5157 313.6559 313.7961 313.9362 314.0764 314.2165 314.3566 314.4967 314.6368 314.7769 314.9170 315.0570 315.1971 315.3371 315.4772 315.6172 315.7572 315.8972 316.0372 316.1772 316.3171 316.4571 316.5970 316.7370 316.8769 317.0168 317.1567 317.2966 317.4364 317.5763 317.7162 317.8560 317.9958 318.1357 318.2755 318.4153 318.5551 318.6948 318.8346 318.9743 319.1141 319.2538 319.3935 319.5332 319.6729 319.8126 319.9523 320.0920 320.2316 320.3713 320.5109 320.6505 320.7901 320.9297 321.0693 321.2089 321.3484 321.4880 321.6275 321.7670 321.9066 322.0461 322.1856 322.3250 322.4645 322.6040 322.7434 322.8829 323.0223 323.1617 323.3011 323.4405 323.5799 323.7192 323.8586 323.9979 324.1373 324.2766 324.4159 324.5552 324.6945 324.8338 324.9730 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250712T113239.7Z 9324.481015 216 1 3.20 2 73.58 75.20 92.55 241.91 0.00 1 0.00 1 0 25 1.350e-01 1.355e-02 1.797e-01 1.146e-02 4.492439e-01 6.152442e-03 5.303613e-03 -6.000000e+00 8.270686e-02 233.03 -2.00 3.58 -2.00 319.29 0.00e+00 2.165019e-03 1.618556e-03 4.431483e-04 -6.000000e+00 3.644992e-03 285.93 -2.00 20.00 -2.00 318.53 0.00e+00 3.480 0.001 302.00 328.00 3 3.8544e+00 1.7396e-02 4.1790e-02 -6.0000e+00 2.0766e-01 1.5468e-02 2.0267e-02 2.4343e-02 -6.0000e+00 2.2415e-01 -1.1114e-02 1.5073e-02 1.1998e-02 -6.0000e+00 1.3329e-01 -6.0591e-03 7.7846e-03 3.8285e-03 -6.0000e+00 5.5234e-02 2.2343e-04 -3.8263e-04 3.6260e-04 4.6166e-05 -6.0000e+00 4.2087e-03 -2.4146e-02 -5.9997e-05 12 9 9 12 1 1 999.00 23.48 0.28 -0.02415 -0.02702 1 7 1 5 0 1594.510 27.05 19.99 23.48 28.01 39.8 1012.89 33919 12141 -38124 26665 73718 -29734 -63584 23382 -28973 -16666 6070 6903 13410 63792 -3746 14233 -11089 3033 -22545 11899 5701 18075 -14631 5754 -11421 5820 -13832 -8762 -5008 36321 -4444 22915 -8471 8706 -7259 -1197 -11729 11366 -10546 6326 -9453 926 -2121 2952 -885 812 853 9312 -1785 455 2564 3849 -436 3874 -3549 2253 1861 2468 -2580 551 44 940 1851 2790 336 -446 -2282 -792 1307 2025 2465 1249 1317 -625 -979 1774 -1422 -2304 435 -2667 386 -3318 -1348 -3109 426 -698 1612 -404 1075 -1189 1665 1259 2839 -3419 2507 719 -194 -377 -535 58 -648 -1586 -2252 -941 -1 -993 -785 -412 654 496 1798 40 -36 897 -253 659 890 545 -241 -952 -929 1186 -803 150 -173 -111 135 1266 694 899 41 -17 -358 -252 -467 -261 -1170 1525 307 107 1294 -525 -1628 471 230 -1187 457 824 -790 -2423 455 -991 -545 170 209 446 1611 -204 749 -804 208 -2074 840 439 1264 -1427 495 -1219 553 -1587 -940 -513 2647 -517 2336 -1262 1158 -1105 -174 -2035 1854 -2468 1467 -2773 264 -644 877 -275 252 266 2732 -587 153 901 1442 -181 1642 -1663 1039 877 1159 -1251 261 22 489 1033 1644 206 -269 -1360 -471 813 1369 1777 941 992 -463 -688 1137 -883 -1425 279 -1935 302 -2897 -1232 -3015 422 -730 1722 -447 1175 -1291 1695 1220 2620 -3308 2454 773 -228 -476 -705 76 -825 -1930 -2655 -1110 -1 -1270 -1039 -566 933 746 2803 64 -57 1381 -378 951 1282 808 -373 -1522 -1497 1866 -1256 228 -256 -159 192 1805 1043 1426 68 -30 -632 -458 -881 -506 -2326 3017 612 211 2462 -984 -3043 SS 20250712T113906.8Z 9324.485496 220 1 49.48 2 72.46 76.23 93.53 242.99 0.00 1 0.00 1 0 17 2.867e-02 6.388e-03 1.437e-02 1.286e-03 4.253185e-01 6.892771e-04 5.003368e-03 -6.000000e+00 1.756934e-02 233.03 -2.00 3.58 -2.00 319.22 0.00e+00 1.204336e-03 1.765492e-04 4.301076e-04 -6.000000e+00 7.743087e-04 285.93 -2.00 20.00 -2.00 318.45 0.00e+00 3.271 0.001 302.00 328.00 3 3.0847e+00 1.9430e-03 3.9364e-02 -6.0000e+00 4.4113e-02 -8.2779e-03 2.2537e-03 2.2992e-02 -6.0000e+00 4.7617e-02 6.8620e-03 1.6337e-03 1.1191e-02 -6.0000e+00 2.8315e-02 -1.4004e-02 8.4206e-04 3.1925e-03 -6.0000e+00 1.1733e-02 6.1043e-04 -5.2313e-04 4.1129e-05 3.9899e-05 -6.0000e+00 8.9404e-04 -2.3437e-02 -3.7653e-05 10 0 0 10 0 0 99.82 23.44 0.13 -0.02344 -0.02737 141 30 1 5 0 350.820 27.05 19.99 23.44 28.21 40.0 1014.47 61 -1060 -1915 -3928 -11030 -3949 -2064 -13191 2491 -14515 -9077 -16188 479 359 2331 -1559 -4330 -1009 2770 1353 2030 -1361 -1536 -1018 -731 -1018 -1601 -5678 129 3064 2009 1980 1582 -3162 -2020 -4615 -1239 -3295 -192 -1650 -1239 -1642 -402 -1251 -140 -592 370 -1434 -304 -785 1388 546 1274 964 450 1113 1120 138 -611 -85 901 1408 1934 2132 548 -134 -179 -190 1159 2206 527 331 367 648 14 -90 -919 -982 -443 -202 -1170 -1416 -2224 -1714 -864 -190 174 396 546 910 890 797 -66 427 722 381 435 639 -63 -349 -844 -1229 -697 400 -867 -1493 -1071 -946 -330 502 407 210 56 -7 -81 334 481 347 541 74 -337 22 461 288 643 327 -249 1081 784 2 -73 -616 -456 81 105 -232 -118 504 100 -22 98 -429 -472 1 -27 -52 -105 -298 -104 -54 -430 78 -541 -357 -702 21 19 140 -105 -329 -80 225 117 180 -127 -149 -105 -76 -111 -177 -636 14 334 231 256 227 -497 -309 -731 -207 -628 -43 -435 -363 -492 -124 -397 -45 -191 119 -470 -100 -270 503 217 543 420 206 526 540 67 -297 -41 446 750 1076 1274 339 -81 -104 -112 722 1523 388 255 283 478 10 -59 -562 -591 -284 -146 -933 -1212 -2081 -1634 -872 -204 188 440 605 971 924 768 -63 404 704 416 516 809 -82 -457 -1091 -1474 -819 471 -1058 -1946 -1416 -1322 -473 749 648 333 90 -11 -121 474 681 512 843 117 -545 35 707 441 938 474 -353 1540 1165 3 -120 -1060 -790 146 196 -454 -231 1000 200 -44 187 -795 -885 SS 20250712T114352.0Z 9324.488796 223 1 11.56 2 71.63 77.00 94.25 243.79 0.00 1 0.00 1 0 17 2.220e-02 6.454e-03 1.105e-02 1.331e-03 4.103525e-01 7.118312e-04 4.858192e-03 -6.000000e+00 1.360079e-02 233.03 -2.00 3.58 -2.00 318.74 0.00e+00 9.665883e-04 1.565678e-04 4.924990e-04 -6.000000e+00 5.994700e-04 285.93 -2.00 20.00 -2.00 317.95 0.00e+00 3.132 0.001 302.00 328.00 3 2.0093e+00 1.9684e-03 3.7788e-02 -6.0000e+00 3.4149e-02 -2.7678e-03 2.2497e-03 2.2152e-02 -6.0000e+00 3.6863e-02 -9.4919e-03 1.5324e-03 1.0719e-02 -6.0000e+00 2.1920e-02 -6.7569e-03 7.8696e-04 2.9486e-03 -6.0000e+00 9.0818e-03 2.0810e-03 -5.9329e-04 4.2283e-05 3.6859e-05 -6.0000e+00 6.9220e-04 -2.2721e-02 -4.6458e-05 12 9 1 12 9 1 97.07 23.41 0.15 -0.02272 -0.02718 62 58 1 5 0 183.360 27.05 19.99 23.41 28.34 39.9 1014.90 960 -7041 -7399 -9116 -7870 -4953 -1537 -5327 -3893 -7716 -8383 -6541 -4661 880 -2677 -2020 -2391 831 1266 436 553 1118 -73 17 -1501 1400 -2132 -1977 -2031 1348 1181 1874 1463 -1406 -4229 -3577 -2681 -1683 -1075 -484 -1336 -485 -622 -928 -819 79 -166 -557 -678 214 768 934 927 1817 253 1167 998 -149 96 -54 386 1656 2475 2019 734 -536 54 -508 1330 1696 624 625 616 689 119 -328 -976 -1202 -466 -704 -1431 -1507 -1973 -1747 -752 -447 284 237 604 509 447 349 -274 275 558 -1 444 402 224 -518 -729 -1557 -577 476 -673 -1503 -832 -838 -152 657 581 350 325 207 -133 295 459 250 587 -17 -258 90 470 374 465 177 -140 890 623 71 -155 -555 -514 185 -143 -188 -219 618 24 63 195 -448 -568 29 -262 -289 -351 -281 -168 -54 -217 -174 -384 -439 -365 -296 59 -218 -185 -241 87 140 51 66 135 -9 2 -205 194 -308 -296 -296 195 187 308 265 -273 -832 -704 -571 -416 -297 -155 -481 -174 -232 -355 -316 30 -64 -216 -267 86 331 437 442 914 135 640 560 -85 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