File name: Pandora169s1_Egbert_20250717_L2Fit_fwvt1c18d20240515p1-8.txt
File generation date: 20250718T053844.4Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c18p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 169
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora169_OF_v5d20200220.txt
Instrument calibration file used: Pandora169s1_CF_v18d20240515.txt
Level 1 file used: Pandora169s1_Egbert_20250717_L1_smca1c18d20240515p1-8.txt
Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert
Short location name: Egbert
Country of location: Canada
Location latitude [deg]: 44.2300
Location longitude [deg]: -79.7800
Location altitude [m]: 251
Local noon date: 20250717
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1650 1799
Nominal wavelengths inside fitting window [nm]: 492.0857 492.2066 492.3274 492.4482 492.5690 492.6897 492.8105 492.9312 493.0519 493.1726 493.2933 493.4140 493.5346 493.6552 493.7759 493.8965 494.0170 494.1376 494.2582 494.3787 494.4992 494.6197 494.7402 494.8607 494.9811 495.1016 495.2220 495.3424 495.4628 495.5832 495.7035 495.8239 495.9442 496.0645 496.1848 496.3051 496.4253 496.5456 496.6658 496.7860 496.9062 497.0264 497.1466 497.2667 497.3868 497.5069 497.6270 497.7471 497.8672 497.9872 498.1073 498.2273 498.3473 498.4673 498.5872 498.7072 498.8271 498.9470 499.0669 499.1868 499.3067 499.4266 499.5464 499.6662 499.7860 499.9058 500.0256 500.1453 500.2651 500.3848 500.5045 500.6242 500.7439 500.8635 500.9832 501.1028 501.2224 501.3420 501.4616 501.5811 501.7007 501.8202 501.9397 502.0592 502.1787 502.2981 502.4176 502.5370 502.6564 502.7758 502.8952 503.0146 503.1339 503.2532 503.3726 503.4918 503.6111 503.7304 503.8496 503.9689 504.0881 504.2073 504.3265 504.4456 504.5648 504.6839 504.8030 504.9221 505.0412 505.1603 505.2794 505.3984 505.5174 505.6364 505.7554 505.8744 505.9933 506.1123 506.2312 506.3501 506.4690 506.5878 506.7067 506.8255 506.9444 507.0632 507.1820 507.3007 507.4195 507.5382 507.6569 507.7757 507.8943 508.0130 508.1317 508.2503 508.3689 508.4876 508.6061 508.7247 508.8433 508.9618 509.0804 509.1989 509.3174 509.4358 509.5543 509.6727 509.7912 509.9096
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250717T102820.7Z 9329.436351 191 1 49.47 2 85.03 65.18 35.84 176.09 0.00 1 0.00 1 0 22 5.711e-03 5.634e-03 1.386e-04 1.384e-04 2.105237e+04 1.066048e+01 1.382990e+03 -6.000000e+00 3.300003e+02 286.27 -2.00 20.00 -2.00 505.37 0.00e+00 1.815829e-03 3.919272e-06 1.245294e-04 -6.000000e+00 1.632637e-04 286.27 -2.00 20.00 -2.00 500.69 0.00e+00 9.309355e-01 2.764125e-03 1.191845e-01 -6.000000e+00 1.155855e-01 233.00 -2.00 3.58 -2.00 502.25 0.00e+00 9.849 0.019 489.00 513.00 1 2.7573e+00 2.1180e-04 1.7560e-02 -6.0000e+00 8.8739e-03 -4.7408e-02 5.3103e-05 3.1527e-03 -6.0000e+00 2.2990e-03 2.7869e-02 1.4281e-03 1.3013e-05 1.4071e-04 -6.0000e+00 6.3403e-04 -3.9713e-03 -1.0071e-04 12 8 8 10 0 0 98.21 23.75 2.04 -0.00397 0.00593 569 122 1 4 0 86.930 27.35 19.99 23.75 28.49 40.1 1009.39 -918 -514 47 428 568 901 1213 1157 964 606 289 41 -261 -496 -583 -563 -303 195 414 243 177 271 307 462 637 590 446 255 -356 -958 -1071 -848 -399 255 448 68 -140 -176 -397 -405 -294 -121 36 303 500 482 400 227 -12 -481 -919 -1275 -1296 -1065 -390 37 175 167 184 238 427 596 634 620 483 228 -11 -153 -354 -608 -664 -576 -366 -108 51 -289 -675 -839 -738 -741 -604 -551 -481 -297 -122 -146 -245 -201 -120 87 426 860 1202 1142 841 579 233 -90 -530 -1177 -1513 -1354 -782 -195 -37 -258 -478 -606 -596 -278 -75 -26 78 266 397 670 1080 1070 743 327 -3 -172 -20 352 588 487 437 346 237 293 64 -410 -477 -504 -457 -113 122 42 215 455 425 386 476 495 449 423 66 -383 -690 -717 -849 -482 44 415 554 897 1203 1158 966 604 285 40 -257 -485 -570 -553 -297 194 414 246 181 277 309 467 646 599 451 260 -358 -944 -1063 -845 -397 256 459 70 -142 -181 -405 -411 -299 -124 36 311 517 501 414 232 -13 -485 -908 -1262 -1275 -1056 -386 37 178 172 190 245 434 608 649 634 490 234 -11 -153 -350 -608 -662 -575 -361 -107 51 -288 -666 -830 -721 -719 -586 -537 -472 -294 -120 -145 -243 -199 -118 85 418 847 1183 1111 812 549 217 -83 -482 -1067 -1384 -1246 -735 -189 -37 -258 -480 -608 -597 -279 -76 -26 79 268 401 680 1108 1093 765 335 -3 -174 -20 349 584 487 439 349 239 295 64 -407 -469 -496 -453 -113 123 43 220 473 441 405 502 523 473 443 68 -394 -717 -745
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SQ 20250717T110658.8Z 9329.463181 205 1 2.65 2 78.61 71.56 36.15 192.04 0.00 1 0.00 1 0 22 4.672e-03 4.652e-03 2.553e-03 2.550e-03 1.125725e+04 1.821724e+02 7.568382e+02 -6.000000e+00 2.700164e+02 286.28 -2.00 20.00 -2.00 505.30 0.00e+00 9.508370e-04 7.181679e-05 6.722932e-05 -6.000000e+00 1.335868e-04 286.28 -2.00 20.00 -2.00 500.51 0.00e+00 3.682750e-01 5.139163e-02 6.923074e-02 -6.000000e+00 9.457135e-02 233.00 -2.00 3.58 -2.00 502.09 0.00e+00 4.890 0.002 489.00 513.00 1 5.7116e+00 3.9425e-03 9.1632e-03 -6.0000e+00 7.2607e-03 -1.1823e-02 1.0009e-03 1.7521e-03 -6.0000e+00 1.8809e-03 3.0988e-03 8.7249e-04 2.5977e-04 8.0731e-05 -6.0000e+00 5.1878e-04 -2.1690e-02 9.7802e-06 12 9 9 12 1 1 999.00 23.75 1.32 -0.02169 -0.01564 1 8 1 4 0 1314.880 27.35 19.98 23.75 28.88 40.0 1011.20 -805 -767 -76 659 -206 382 726 604 293 263 368 143 -532 -520 -537 -400 -421 638 453 550 -44 526 -250 741 528 176 209 186 -36 -349 -1248 -506 -88 -157 317 52 -129 221 -312 -458 -110 -13 -67 411 833 -32 97 345 215 -661 18 -1277 -631 -689 -745 181 193 42 86 406 161 321 708 761 863 143 585 -476 -515 -306 -310 -494 50 -66 68 -31 -2 -538 -547 -740 -540 -292 -514 -133 5 -69 102 -561 -337 -122 256 558 640 457 712 410 -18 242 -40 -950 -915 -897 -72 181 162 -325 -149 -43 -363 -197 -354 118 -170 65 87 329 915 1272 360 266 -236 61 315 -159 462 132 503 485 -248 103 104 -289 -435 -451 -914 -415 -154 -33 -18 345 185 336 -33 1021 287 305 88 -316 -620 -439 -775 -749 -75 650 -207 390 751 620 301 272 375 144 -533 -524 -540 -403 -423 650 463 569 -45 548 -259 763 547 182 216 193 -37 -353 -1253 -506 -89 -162 327 54 -135 227 -319 -466 -111 -14 -69 426 868 -33 100 355 218 -671 18 -1264 -616 -678 -738 182 196 43 89 416 165 331 729 782 879 145 581 -479 -513 -301 -303 -485 50 -65 68 -31 -2 -523 -536 -722 -526 -285 -500 -130 5 -69 100 -553 -331 -120 251 552 636 453 703 394 -17 228 -37 -875 -844 -843 -68 176 160 -321 -147 -43 -361 -196 -351 118 -171 66 87 330 920 1283 366 267 -234 61 308 -156 453 130 496 478 -246 102 102 -279 -424 -436 -892 -402 -151 -32 -18 348 186 340 -34 1035 292 308 88 -316 -613 -432
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