File name: Pandora75s1_EssexMD_20240524_L2Fit_fout2c1d20221230p1-8.txt File generation date: 20240525T051118.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 75 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora75_OF_v3d20220127.txt Instrument calibration file used: Pandora75s1_CF_v104d20221230.txt Level 1 file used: Pandora75s1_EssexMD_20240524_L1_smca1c1d20221230p1-8.txt Full location name: MDE Essex Monitoring Site Short location name: EssexMD Country of location: United States Location latitude [deg]: 39.3109 Location longitude [deg]: -76.4745 Location altitude [m]: 12 Local noon date: 20240524 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 103 First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.0663 305.2078 305.3493 305.4908 305.6322 305.7737 305.9151 306.0566 306.1980 306.3394 306.4807 306.6221 306.7635 306.9048 307.0461 307.1874 307.3287 307.4700 307.6112 307.7524 307.8937 308.0349 308.1761 308.3172 308.4584 308.5996 308.7407 308.8818 309.0229 309.1640 309.3051 309.4461 309.5872 309.7282 309.8692 310.0102 310.1512 310.2921 310.4331 310.5740 310.7149 310.8558 310.9967 311.1376 311.2784 311.4193 311.5601 311.7009 311.8417 311.9825 312.1233 312.2640 312.4048 312.5455 312.6862 312.8269 312.9676 313.1083 313.2489 313.3896 313.5302 313.6708 313.8114 313.9520 314.0925 314.2331 314.3736 314.5141 314.6547 314.7951 314.9356 315.0761 315.2165 315.3570 315.4974 315.6378 315.7782 315.9186 316.0590 316.1993 316.3397 316.4800 316.6203 316.7606 316.9009 317.0411 317.1814 317.3216 317.4619 317.6021 317.7423 317.8825 318.0227 318.1628 318.3030 318.4431 318.5832 318.7233 318.8634 319.0035 319.1436 319.2836 319.4237 319.5637 319.7037 319.8437 319.9837 320.1237 320.2636 320.4036 320.5435 320.6834 320.8233 320.9632 321.1031 321.2430 321.3828 321.5227 321.6625 321.8023 321.9421 322.0819 322.2217 322.3615 322.5012 322.6409 322.7807 322.9204 323.0601 323.1998 323.3395 323.4791 323.6188 323.7584 323.8980 324.0376 324.1772 324.3168 324.4564 324.5960 324.7355 324.8750 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240524T120434.6Z 8910.503178 245 1 9.56 2 65.26 82.50 110.67 250.78 0.00 1 0.00 1 0 17 3.797e-02 7.347e-03 2.316e-02 3.450e-03 3.731338e-01 1.862693e-03 4.431216e-03 -6.000000e+00 2.341897e-02 231.73 -2.00 3.48 -2.00 318.44 0.00e+00 1.159435e-03 3.729120e-04 7.420966e-04 -6.000000e+00 1.022031e-03 285.57 -2.00 20.00 -2.00 317.71 0.00e+00 2.373 0.000 302.00 328.00 3 3.7060e+00 5.0549e-03 3.0987e-02 -6.0000e+00 5.8647e-02 1.1730e-02 5.7227e-03 1.9668e-02 -6.0000e+00 6.3048e-02 -1.6383e-02 3.8201e-03 9.6023e-03 -6.0000e+00 3.7518e-02 -8.4394e-04 1.9872e-03 2.6594e-03 -6.0000e+00 1.5955e-02 7.3997e-04 -1.1135e-03 1.0828e-04 3.2817e-05 -6.0000e+00 1.1703e-03 -3.5408e-02 1.7152e-04 12 9 1 12 17 1 96.57 23.45 0.38 -0.03541 -0.04378 7 7 1 5 0 1194.700 26.21 20.00 23.45 30.82 4.0 1037.73 -15689 -7627 -4341 576 -7982 -16459 -21199 -8727 -7018 543 -10360 -11532 -14066 -1957 4899 3915 2548 -3995 -636 176 511 2347 643 2025 2765 1744 -4157 200 -3427 -2504 -1200 2223 491 -723 -6195 -3317 -2885 -2941 -1133 -572 -690 612 247 -279 595 964 -905 988 6 -303 -838 1658 1631 1865 61 704 1228 995 -1273 482 1668 1805 2598 1593 1266 243 -12 30 -28 1318 478 -35 400 702 -47 -248 -1970 -1824 -1694 -1118 -1221 -1209 -2185 -1189 -663 -502 405 690 838 1060 618 -378 -615 -1273 -210 8 393 781 -246 -88 -1021 -1605 -593 -588 -1083 -956 -379 -252 402 747 639 368 477 -2 27 292 350 72 772 540 501 516 320 223 227 250 -268 46 213 -277 -436 -641 -559 204 206 -122 571 273 95 -161 -340 -636 -691 -354 -207 26 -360 -770 -1077 -432 -380 29 -648 -768 -1088 -158 433 399 287 -512 -83 24 71 324 93 304 436 290 -744 33 -564 -409 -208 413 102 -159 -1411 -726 -677 -798 -328 -193 -261 243 102 -118 253 410 -390 415 3 -133 -392 818 862 1045 33 394 696 566 -730 270 954 1107 1725 1145 927 172 -8 20 -20 1043 385 -30 338 568 -38 -185 -1376 -1236 -1213 -896 -1022 -1126 -2218 -1177 -697 -562 473 827 1003 1219 665 -409 -625 -1290 -225 9 483 988 -333 -117 -1301 -2043 -710 -718 -1414 -1233 -512 -359 568 1128 1023 603 761 -3 41 417 500 108 1140 837 787 799 482 322 334 351 -368 64 318 -420 -703 -1079 -915 346 371 -231 1040 508 176 -291 -627 -1134 SS 20240524T121642.2Z 8910.511599 253 1 31.19 2 62.93 84.28 112.81 252.34 0.00 1 0.00 1 0 25 2.207e-02 8.052e-03 1.880e-03 5.234e-04 3.461360e-01 2.832922e-04 4.126278e-03 -6.000000e+00 1.361150e-02 231.73 -2.00 3.48 -2.00 317.42 0.00e+00 1.008035e-03 4.220777e-05 4.215939e-04 -6.000000e+00 5.940680e-04 285.58 -2.00 20.00 -2.00 316.66 0.00e+00 2.185 0.000 302.00 328.00 3 1.7333e+00 7.5117e-04 2.8519e-02 -6.0000e+00 3.4087e-02 4.2270e-03 8.3748e-04 1.7964e-02 -6.0000e+00 3.6647e-02 -1.6836e-02 5.0822e-04 8.7379e-03 -6.0000e+00 2.1807e-02 6.7097e-04 2.5220e-04 2.4155e-03 -6.0000e+00 9.2724e-03 6.6643e-03 -1.2418e-03 1.6323e-05 3.0584e-05 -6.0000e+00 6.8031e-04 -3.4667e-02 1.4950e-04 12 9 1 12 1 1 99.96 23.45 0.41 -0.03467 -0.04400 223 60 1 5 0 139.200 26.21 20.00 23.45 31.26 4.1 1041.11 -4959 -5648 -2380 -5030 -5947 -8549 -7194 -5952 -6183 -6382 -7763 -6225 -5199 -3195 -1471 508 251 1236 2304 2016 2684 1546 1794 1464 1571 725 812 -696 -1126 -1117 -205 490 182 -1232 -3395 -3483 -3959 -2182 -836 -434 -285 89 454 371 583 793 481 -155 -131 25 568 1278 1262 1375 1048 1032 771 572 139 441 834 1595 2248 1942 1168 67 -409 -497 491 1196 848 966 746 388 -162 -1170 -1883 -2165 -2292 -1817 -1805 -1958 -1994 -1696 -886 -408 314 852 719 569 244 -157 -629 -587 -400 76 477 712 223 -289 -944 -1378 -983 -544 -785 -1022 -577 -212 478 871 925 669 401 87 -99 -24 132 470 542 476 437 654 636 603 425 26 8 154 223 0 -269 -445 -314 -34 -34 79 347 310 -71 -175 -490 -944 -412 -536 -231 -492 -541 -758 -651 -585 -677 -753 -957 -790 -733 -469 -247 95 51 263 511 467 634 372 441 380 395 192 217 -182 -307 -304 -54 141 57 -411 -1131 -1147 -1409 -812 -366 -206 -151 47 245 204 321 438 264 -85 -72 14 333 800 792 914 729 738 530 393 100 318 580 1180 1799 1572 964 53 -329 -396 389 1049 773 922 714 358 -139 -977 -1540 -1719 -1919 -1604 -1703 -1950 -2039 -1832 -969 -473 364 1012 855 682 273 -171 -674 -621 -426 85 571 900 298 -385 -1197 -1700 -1202 -648 -998 -1322 -781 -290 688 1286 1388 1024 598 127 -140 -33 178 659 775 716 667 982 930 879 591 36 11 211 313 0 -416 -688 -501 -55 -58 136 608 536 -122 -306 -824 -1595 SS 20240524T122213.1Z 8910.515429 256 1 51.58 2 61.87 85.10 113.79 253.05 0.00 1 0.00 1 0 17 1.862e-02 7.889e-03 8.826e-04 2.715e-04 3.342395e-01 1.472413e-04 3.987673e-03 -6.000000e+00 1.148294e-02 231.73 -2.00 3.48 -2.00 317.24 0.00e+00 1.046209e-03 2.074199e-05 3.618700e-04 -6.000000e+00 5.011625e-04 285.58 -2.00 20.00 -2.00 316.48 0.00e+00 2.110 0.000 302.00 328.00 3 1.0295e+00 3.8933e-04 2.7528e-02 -6.0000e+00 2.8756e-02 2.6128e-03 4.3364e-04 1.7321e-02 -6.0000e+00 3.0916e-02 -1.6023e-02 2.5983e-04 8.4360e-03 -6.0000e+00 1.8397e-02 5.5614e-04 1.2747e-04 2.3471e-03 -6.0000e+00 7.8225e-03 1.4758e-02 -1.1508e-03 8.4628e-06 2.9171e-05 -6.0000e+00 5.7391e-04 -3.4747e-02 1.5505e-04 11 9 0 11 8 0 99.95 23.45 0.40 -0.03475 -0.04339 823 134 1 5 0 62.670 26.21 20.00 23.45 31.47 4.1 1042.51 -4250 -2318 -2145 -3294 -5359 -6842 -5820 -5022 -4036 -5133 -6093 -6019 -4663 -2968 -1038 175 483 1341 1936 1919 2006 1769 1722 1558 1323 1127 405 -770 -967 -923 -104 486 299 -1199 -3191 -3839 -3606 -2261 -845 -405 -310 3 250 539 565 774 334 -62 -121 99 730 1027 1196 1272 1113 990 836 409 185 384 881 1614 2200 1897 1005 48 -420 -368 481 1151 823 919 702 401 -180 -1089 -1754 -2169 -2078 -1778 -1820 -1853 -2001 -1663 -860 -392 265 762 732 548 318 -127 -662 -544 -320 -34 476 641 272 -285 -906 -1472 -982 -609 -815 -1010 -579 -221 424 906 896 705 409 75 -112 -84 186 438 579 421 462 633 666 596 425 63 -18 181 186 -22 -200 -441 -385 11 8 102 339 293 11 -181 -557 -992 -405 -245 -239 -363 -554 -682 -592 -557 -492 -679 -838 -862 -670 -488 -194 37 109 316 478 493 484 431 429 409 367 326 119 -221 -265 -252 -30 152 102 -434 -1148 -1372 -1276 -910 -371 -207 -164 2 145 318 334 458 197 -36 -70 58 426 642 796 844 770 704 606 298 133 275 647 1191 1754 1532 827 40 -334 -289 398 998 744 869 666 367 -162 -949 -1412 -1695 -1706 -1544 -1692 -1818 -2117 -1774 -972 -450 318 898 863 651 369 -136 -698 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