File name: Pandora75s1_EssexMD_20241107_L2Fit_fout2c1d20221230p1-8.txt
File generation date: 20241113T124614.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c1p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 75
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora75_OF_v3d20220127.txt
Instrument calibration file used: Pandora75s1_CF_v104d20221230.txt
Level 1 file used: Pandora75s1_EssexMD_20241107_L1_smca1c1d20221230p1-8.txt
Full location name: MDE Essex Monitoring Site
Short location name: EssexMD
Country of location: United States
Location latitude [deg]: 39.3109
Location longitude [deg]: -76.4745
Location altitude [m]: 12
Local noon date: 20241107
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB-data based on session 103
First and last pixel inside fitting window: 196 337
Nominal wavelengths inside fitting window [nm]: 305.0663 305.2078 305.3493 305.4908 305.6322 305.7737 305.9151 306.0566 306.1980 306.3394 306.4807 306.6221 306.7635 306.9048 307.0461 307.1874 307.3287 307.4700 307.6112 307.7524 307.8937 308.0349 308.1761 308.3172 308.4584 308.5996 308.7407 308.8818 309.0229 309.1640 309.3051 309.4461 309.5872 309.7282 309.8692 310.0102 310.1512 310.2921 310.4331 310.5740 310.7149 310.8558 310.9967 311.1376 311.2784 311.4193 311.5601 311.7009 311.8417 311.9825 312.1233 312.2640 312.4048 312.5455 312.6862 312.8269 312.9676 313.1083 313.2489 313.3896 313.5302 313.6708 313.8114 313.9520 314.0925 314.2331 314.3736 314.5141 314.6547 314.7951 314.9356 315.0761 315.2165 315.3570 315.4974 315.6378 315.7782 315.9186 316.0590 316.1993 316.3397 316.4800 316.6203 316.7606 316.9009 317.0411 317.1814 317.3216 317.4619 317.6021 317.7423 317.8825 318.0227 318.1628 318.3030 318.4431 318.5832 318.7233 318.8634 319.0035 319.1436 319.2836 319.4237 319.5637 319.7037 319.8437 319.9837 320.1237 320.2636 320.4036 320.5435 320.6834 320.8233 320.9632 321.1031 321.2430 321.3828 321.5227 321.6625 321.8023 321.9421 322.0819 322.2217 322.3615 322.5012 322.6409 322.7807 322.9204 323.0601 323.1998 323.3395 323.4791 323.6188 323.7584 323.8980 324.0376 324.1772 324.3168 324.4564 324.5960 324.7355 324.8750
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20241107T144540.5Z 9077.615052 6 1 4.57 2 62.90 146.33 118.90 101.61 0.00 1 0.00 1 0 25 1.364e-02 8.729e-03 6.052e-03 2.776e-03 2.455456e-01 1.464797e-03 3.011277e-03 -6.000000e+00 8.176123e-03 224.16 -2.00 3.48 -2.00 316.38 0.00e+00 7.487814e-04 1.710469e-04 2.378287e-04 -6.000000e+00 3.625958e-04 282.57 -2.00 20.00 -2.00 315.72 0.00e+00 2.183 0.000 302.00 328.00 3 3.1391e+00 3.7714e-03 2.4954e-02 -6.0000e+00 2.0132e-02 3.9716e-02 4.2055e-03 1.2384e-02 -6.0000e+00 2.1774e-02 -1.2422e-02 2.4510e-03 6.1188e-03 -6.0000e+00 1.3012e-02 -2.1175e-03 1.1605e-03 1.7547e-03 -6.0000e+00 5.6007e-03 1.9541e-03 -1.0159e-03 8.7210e-05 2.4089e-05 -6.0000e+00 4.1962e-04 -3.0790e-02 1.8988e-04 12 9 1 12 17 1 98.78 22.13 0.55 -0.03079 -0.03842 6 13 1 5 0 651.800 25.07 20.01 22.13 34.60 5.5 1050.62 -1641 -2593 470 -3102 -2562 -1187 -3290 -1450 -2930 -1256 -4191 -3447 -2887 -556 -848 -237 646 1014 1243 2653 2867 1344 1709 1211 848 1341 729 351 -1897 -1067 -434 341 297 -1743 -3003 -3538 -3844 -2913 -187 -397 -51 65 565 -2 1289 593 146 42 178 -189 154 782 902 1478 599 855 282 733 5 -433 1133 1877 2463 1398 967 128 -653 -654 592 969 775 740 924 495 -351 -1504 -2016 -1675 -2937 -1566 -1893 -1897 -1964 -1799 -637 -227 787 350 1022 646 138 -751 -539 -249 -688 597 376 363 91 -57 -721 -1187 -1053 -779 -651 -1218 -680 -142 964 1198 1108 616 649 205 -136 -71 17 120 722 550 482 246 492 681 96 398 44 313 119 -143 -534 -812 -359 151 22 191 249 527 86 -65 -365 -1299 -278 -491 90 -590 -441 -190 -549 -259 -586 -262 -914 -762 -630 -134 -233 -72 205 333 423 917 1008 480 618 459 309 503 276 139 -722 -394 -165 138 118 -727 -1224 -1425 -1664 -1432 -97 -241 -32 42 378 -1 867 400 97 27 113 -121 103 552 672 1151 454 659 222 573 4 -337 895 1570 2206 1251 866 116 -557 -547 514 871 760 715 892 492 -328 -1375 -1691 -1340 -2471 -1440 -1827 -1895 -2102 -2030 -717 -272 929 428 1239 799 159 -849 -563 -253 -735 691 456 457 120 -75 -895 -1457 -1241 -941 -796 -1585 -924 -191 1354 1691 1633 917 930 289 -187 -93 23 163 989 797 713 362 703 931 132 520 55 401 161 -196 -770 -1209 -545 227 36 301 405 870 143 -105 -574 -2100
SS 20241107T144940.0Z 9077.617825 9 1 7.48 2 62.48 147.29 118.18 102.14 0.00 1 0.00 1 0 17 1.254e-02 8.313e-03 1.461e-03 7.406e-04 2.414591e-01 3.922632e-04 2.955625e-03 -6.000000e+00 7.516797e-03 224.16 -2.00 3.48 -2.00 316.08 0.00e+00 7.412081e-04 4.242351e-05 1.749147e-04 -6.000000e+00 3.332868e-04 282.57 -2.00 20.00 -2.00 315.43 0.00e+00 2.153 0.000 302.00 328.00 3 1.2613e+00 1.0055e-03 2.4583e-02 -6.0000e+00 1.8509e-02 2.6284e-02 1.1182e-03 1.2166e-02 -6.0000e+00 2.0016e-02 -1.2395e-02 6.4926e-04 6.0183e-03 -6.0000e+00 1.1962e-02 -2.2773e-03 3.0318e-04 1.7394e-03 -6.0000e+00 5.1502e-03 1.3342e-02 -8.7084e-04 2.3245e-05 2.4438e-05 -6.0000e+00 3.8563e-04 -3.1949e-02 2.3932e-04 12 9 1 12 1 1 99.98 22.54 0.38 -0.03195 -0.03849 103 117 1 5 0 71.860 25.47 20.00 22.54 34.20 5.4 1047.73 -1309 -542 -381 -1644 -3010 -2587 -3171 -1942 -1004 -2589 -2721 -3141 -2196 -1291 42 413 885 1775 1670 2176 1877 2024 1709 1752 1048 1132 342 -177 -334 -443 199 759 66 -1411 -3117 -3648 -3398 -2511 -980 -643 -328 -254 -89 258 279 542 -158 -199 -411 103 438 1006 1072 1376 932 1149 1011 451 391 407 985 1715 1936 1682 873 -30 -777 -528 388 970 682 905 642 467 -73 -1021 -1753 -2314 -2283 -1943 -1831 -1969 -1896 -1648 -699 -268 265 814 720 468 76 -257 -836 -655 -256 15 687 804 336 -173 -856 -1403 -914 -511 -820 -966 -631 -181 535 1037 969 720 394 138 -103 -65 106 280 554 420 445 621 603 514 435 112 -10 258 255 23 -142 -529 -374 -103 -6 64 294 286 14 -159 -513 -1010 -252 -115 -83 -352 -595 -478 -602 -397 -224 -624 -666 -787 -594 -359 13 142 320 609 595 796 702 757 651 695 438 489 149 -74 -132 -171 79 321 30 -671 -1456 -1682 -1553 -1303 -552 -393 -221 -169 -61 179 193 373 -107 -140 -286 71 315 721 811 1091 725 910 812 364 311 324 802 1479 1700 1560 814 -27 -684 -454 346 905 661 915 652 459 -71 -907 -1511 -1918 -1962 -1746 -1742 -2063 -2025 -1770 -795 -310 321 1010 894 562 89 -289 -877 -701 -273 17 802 1027 433 -221 -1086 -1670 -1087 -623 -1026 -1228 -840 -242 746 1464 1428 1070 565 192 -138 -83 135 372 752 603 628 903 855 700 586 145 -14 338 338 31 -202 -779 -542 -155 -10 103 465 461 23 -252 -820 -1575
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