File name: Pandora75s1_EssexMD_20250114_L2Fit_fwvt1c1d20221230p1-8.txt
File generation date: 20250115T053010.8Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c1p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 75
Spectrometer number: 1
Processing software version used: BlickP v1.8.70
Instrument operation file used: Pandora75_OF_v3d20220127.txt
Instrument calibration file used: Pandora75s1_CF_v104d20221230.txt
Level 1 file used: Pandora75s1_EssexMD_20250114_L1_smca1c1d20221230p1-8.txt
Full location name: MDE Essex Monitoring Site
Short location name: EssexMD
Country of location: United States
Location latitude [deg]: 39.3109
Location longitude [deg]: -76.4745
Location altitude [m]: 12
Local noon date: 20250114
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB-data based on session 103
First and last pixel inside fitting window: 1614 1763
Nominal wavelengths inside fitting window [nm]: 492.0244 492.1456 492.2667 492.3879 492.5090 492.6301 492.7512 492.8723 492.9933 493.1144 493.2354 493.3564 493.4774 493.5984 493.7193 493.8403 493.9612 494.0821 494.2030 494.3239 494.4447 494.5655 494.6864 494.8072 494.9280 495.0487 495.1695 495.2902 495.4110 495.5317 495.6524 495.7730 495.8937 496.0143 496.1350 496.2556 496.3761 496.4967 496.6173 496.7378 496.8583 496.9788 497.0993 497.2198 497.3403 497.4607 497.5811 497.7015 497.8219 497.9423 498.0626 498.1830 498.3033 498.4236 498.5439 498.6642 498.7844 498.9047 499.0249 499.1451 499.2653 499.3854 499.5056 499.6257 499.7458 499.8659 499.9860 500.1061 500.2261 500.3462 500.4662 500.5862 500.7062 500.8262 500.9461 501.0660 501.1859 501.3058 501.4257 501.5456 501.6654 501.7853 501.9051 502.0249 502.1447 502.2644 502.3842 502.5039 502.6236 502.7433 502.8630 502.9826 503.1023 503.2219 503.3415 503.4611 503.5807 503.7002 503.8198 503.9393 504.0588 504.1783 504.2978 504.4172 504.5367 504.6561 504.7755 504.8949 505.0142 505.1336 505.2529 505.3722 505.4915 505.6108 505.7301 505.8493 505.9686 506.0878 506.2070 506.3262 506.4453 506.5645 506.6836 506.8027 506.9218 507.0409 507.1599 507.2790 507.3980 507.5170 507.6360 507.7549 507.8739 507.9928 508.1118 508.2307 508.3495 508.4684 508.5873 508.7061 508.8249 508.9437 509.0625 509.1812 509.3000 509.4187 509.5374 509.6561 509.7748 509.8934
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [�C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [�C], 999=no temperature signal
Column 96: Spectrometer control temperature [�C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [�C], 999=no temperature signal
Column 98: Temperature in head sensor [�C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250114T131612.5Z 9145.552922 294 1 51.57 2 82.26 125.65 91.01 301.49 0.00 1 0.00 1 0 15 4.240e-03 4.220e-03 3.030e-04 3.028e-04 9.089209e+02 1.712604e+01 6.132244e+01 -6.000000e+00 2.375730e+02 276.74 -2.00 20.00 -2.00 505.31 0.00e+00 1.379988e-03 8.327213e-06 7.187641e-05 -6.000000e+00 1.189110e-04 276.74 -2.00 20.00 -2.00 500.69 0.00e+00 4.743961e-01 5.974854e-03 1.426142e-02 -6.000000e+00 8.539424e-02 223.88 -2.00 3.48 -2.00 502.25 0.00e+00 6.917 0.006 489.00 513.00 1 4.7436e+00 4.5775e-04 1.0141e-02 -6.0000e+00 6.5478e-03 -9.0220e-03 1.1706e-04 5.8677e-04 -6.0000e+00 1.6839e-03 6.0448e-03 1.6053e-03 3.3888e-05 2.9919e-05 -6.0000e+00 4.8362e-04 -1.2635e-02 2.8667e-04 11 8 0 10 0 0 93.09 22.76 2.09 -0.01264 -0.00150 81 13 1 4 0 636.600 25.68 19.99 22.76 2.56 5.8 845.01 -990 -746 -441 -293 -94 423 699 583 485 453 357 79 -259 -319 -375 -377 -256 54 105 56 179 317 393 495 582 484 369 -28 -398 -543 -465 -471 -138 251 136 -91 6 4 -132 -1 35 51 335 522 558 573 514 326 13 -368 -711 -843 -1051 -667 -408 -176 -128 -12 138 357 521 628 568 613 394 339 204 -26 -337 -403 -240 -309 -230 -42 -82 -280 -365 -513 -553 -541 -415 -549 -542 -275 -162 -239 -285 -104 -133 50 220 518 554 501 465 395 153 -289 -563 -739 -805 -623 -159 -60 -250 -334 -474 -349 -238 -190 -63 123 281 474 621 862 892 716 579 369 314 232 316 344 142 294 337 239 302 227 -158 -295 -438 -695 -521 -195 -217 -187 7 163 181 339 466 427 284 -111 -293 -438 -612 -579 -936 -712 -424 -287 -93 426 702 591 491 455 354 79 -255 -311 -365 -369 -254 54 107 57 183 323 402 507 589 490 378 -28 -396 -536 -459 -461 -137 252 138 -93 6 4 -134 -1 35 52 339 533 566 582 528 332 14 -366 -702 -819 -1016 -649 -406 -176 -129 -12 139 364 531 632 574 618 395 340 202 -26 -333 -394 -234 -302 -227 -42 -80 -274 -359 -498 -534 -521 -401 -535 -533 -268 -160 -237 -284 -104 -131 50 219 522 556 505 466 396 151 -284 -551 -714 -780 -603 -158 -60 -251 -337 -475 -346 -238 -189 -63 124 287 488 634 884 917 735 590 377 317 232 316 344 143 297 340 241 304 228 -158 -295 -433 -685 -513 -195 -218 -188 8 167 184 347 479 440 292 -114 -299 -439 -614 -581
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SQ 20250114T133210.3Z 9145.564008 300 1 51.43 2 79.80 128.47 93.54 303.93 0.00 1 0.00 1 0 15 4.025e-03 4.004e-03 3.778e-04 3.774e-04 6.731029e+02 2.125966e+01 4.413042e+01 -6.000000e+00 2.255306e+02 276.74 -2.00 20.00 -2.00 505.29 0.00e+00 1.075915e-03 1.036107e-05 5.536819e-05 -6.000000e+00 1.128885e-04 276.74 -2.00 20.00 -2.00 500.63 0.00e+00 3.787398e-01 7.463619e-03 1.085069e-02 -6.000000e+00 8.107894e-02 223.88 -2.00 3.48 -2.00 502.20 0.00e+00 5.412 0.003 489.00 513.00 1 5.1833e+00 5.7195e-04 7.9115e-03 -6.0000e+00 6.2168e-03 -5.3326e-03 1.4661e-04 4.5544e-04 -6.0000e+00 1.5991e-03 4.8801e-03 1.9710e-03 4.2203e-05 2.2793e-05 -6.0000e+00 4.5909e-04 -1.5619e-02 2.9019e-04 11 9 0 11 16 0 99.40 22.76 2.03 -0.01562 -0.00195 74 12 1 4 0 694.910 25.68 20.00 22.76 3.88 5.9 855.35 -951 -762 -460 -325 -52 406 563 485 484 384 360 -62 -222 -336 -418 -341 -172 93 154 2 130 305 430 526 507 424 249 -58 -410 -472 -423 -472 -115 243 90 -79 66 95 -85 -9 12 147 228 585 568 589 458 407 -6 -368 -604 -948 -996 -670 -361 -193 -145 -29 57 315 473 576 536 560 436 275 167 35 -264 -264 -253 -315 -126 -56 -22 -212 -378 -382 -355 -572 -439 -487 -543 -250 -204 -261 -236 -180 -56 -17 252 535 563 491 532 388 105 -341 -543 -643 -778 -489 -186 -109 -311 -350 -435 -290 -296 -118 -82 170 220 397 613 807 730 686 535 349 266 188 350 315 147 190 305 224 256 189 -187 -261 -476 -715 -461 -150 -191 -253 -67 99 188 354 511 416 255 -141 -297 -476 -537 -469 -888 -719 -444 -323 -51 408 575 499 497 392 362 -61 -218 -327 -406 -333 -170 94 158 2 136 320 437 535 517 433 254 -61 -418 -469 -415 -466 -116 250 91 -81 67 96 -85 -9 12 148 231 598 585 607 470 413 -6 -373 -598 -923 -964 -652 -358 -190 -146 -29 58 320 480 586 546 570 441 275 164 34 -263 -261 -249 -312 -126 -55 -21 -206 -364 -375 -345 -557 -429 -479 -523 -242 -199 -257 -233 -178 -55 -17 253 543 577 489 543 391 104 -332 -518 -607 -737 -469 -182 -110 -309 -349 -429 -292 -297 -119 -82 171 224 408 633 836 759 712 551 356 267 187 347 314 148 191 305 224 256 188 -186 -256 -461 -689 -443 -146 -189 -255 -68 102 189 357 518 422 258 -142 -304 -477 -532 -464
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