File name: Pandora75s1_EssexMD_20250707_L2Fit_fout2c3d20230525p1-8.txt
File generation date: 20250708T051837.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c3p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 75
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora75_OF_v3d20220127.txt
Instrument calibration file used: Pandora75s1_CF_v3d20230525.txt
Level 1 file used: Pandora75s1_EssexMD_20250707_L1_smca1c3d20230525p1-8.txt
Full location name: MDE Essex Monitoring Site
Short location name: EssexMD
Country of location: United States
Location latitude [deg]: 39.3109
Location longitude [deg]: -76.4745
Location altitude [m]: 12
Local noon date: 20250707
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based on session 2
First and last pixel inside fitting window: 196 338
Nominal wavelengths inside fitting window [nm]: 305.0305 305.1717 305.3128 305.4540 305.5951 305.7363 305.8774 306.0185 306.1596 306.3007 306.4418 306.5828 306.7239 306.8649 307.0060 307.1470 307.2880 307.4290 307.5700 307.7110 307.8519 307.9929 308.1338 308.2747 308.4157 308.5566 308.6975 308.8384 308.9792 309.1201 309.2610 309.4018 309.5426 309.6834 309.8243 309.9651 310.1058 310.2466 310.3874 310.5281 310.6689 310.8096 310.9503 311.0910 311.2317 311.3724 311.5131 311.6537 311.7944 311.9350 312.0757 312.2163 312.3569 312.4975 312.6381 312.7786 312.9192 313.0598 313.2003 313.3408 313.4813 313.6218 313.7623 313.9028 314.0433 314.1838 314.3242 314.4646 314.6051 314.7455 314.8859 315.0263 315.1667 315.3070 315.4474 315.5877 315.7281 315.8684 316.0087 316.1490 316.2893 316.4296 316.5699 316.7101 316.8504 316.9906 317.1308 317.2710 317.4112 317.5514 317.6916 317.8318 317.9719 318.1121 318.2522 318.3923 318.5324 318.6725 318.8126 318.9527 319.0927 319.2328 319.3728 319.5129 319.6529 319.7929 319.9329 320.0729 320.2128 320.3528 320.4927 320.6327 320.7726 320.9125 321.0524 321.1923 321.3322 321.4721 321.6119 321.7518 321.8916 322.0314 322.1712 322.3110 322.4508 322.5906 322.7304 322.8701 323.0099 323.1496 323.2893 323.4290 323.5687 323.7084 323.8481 323.9877 324.1274 324.2670 324.4067 324.5463 324.6859 324.8255 324.9650
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250707T112644.6Z 9319.476905 140 1 51.57 2 73.03 74.47 142.50 276.84 0.00 1 0.00 1 0 17 8.343e-02 7.250e-03 1.335e-02 1.135e-03 4.148099e-01 6.042331e-04 4.782253e-03 -6.000000e+00 5.083889e-02 232.80 -2.00 3.48 -2.00 319.40 0.00e+00 1.728636e-03 1.661957e-04 1.295494e-03 -6.000000e+00 2.279291e-03 289.68 -2.00 20.00 -2.00 318.57 0.00e+00 3.373 0.001 302.00 328.00 3 2.3562e+00 1.7323e-03 4.0350e-02 -6.0000e+00 1.2740e-01 2.0319e-02 2.0306e-03 2.2395e-02 -6.0000e+00 1.3756e-01 -6.2458e-03 1.4754e-03 1.0985e-02 -6.0000e+00 8.2037e-02 -6.4397e-03 7.6062e-04 3.0865e-03 -6.0000e+00 3.4005e-02 1.0561e-03 4.2160e-04 3.6330e-05 4.0533e-05 -6.0000e+00 2.5864e-03 7.0739e-03 5.3692e-05 11 8 0 10 0 0 100.00 23.50 0.48 0.00707 0.01024 577 94 1 5 0 89.370 26.21 19.99 23.50 33.71 6.5 1059.39 -50073 -23650 -11166 -29847 -24321 -42936 -17602 -24037 -14291 -18450 -14781 -21573 -14536 -13500 -8894 -6270 -4586 -2892 -4400 1697 1124 -2052 1204 -5 -361 -1316 -4436 -5552 -3076 -4190 482 -3915 911 -3519 -4357 -4517 -3980 -2203 890 225 -705 -212 165 727 170 1476 209 -645 129 1242 836 1557 1857 1811 1582 1372 828 -67 -227 684 1199 2543 2517 2209 1019 343 -127 -45 838 1547 1017 1129 824 83 282 -1286 -1439 -2058 -2068 -1798 -1770 -1868 -1816 -1415 -807 -235 260 1004 736 716 653 -29 -679 -648 -396 -206 558 473 216 -418 -1054 -1622 -1051 -608 -1075 -931 -620 -203 396 889 799 458 229 -209 -391 -265 84 263 525 315 503 623 735 454 442 -78 -78 -116 209 -160 -484 -470 -298 -33 192 143 489 387 202 166 -295 -679 -727 -1346 -557 -271 -856 -617 -1274 -427 -692 -416 -603 -486 -819 -597 -658 -491 -387 -306 -204 -336 128 88 -168 99 0 -34 -131 -460 -566 -297 -419 50 -481 118 -499 -613 -638 -609 -386 181 54 -191 -61 50 222 53 456 65 -205 41 407 295 593 691 719 660 593 367 -30 -101 300 543 1228 1335 1264 600 196 -70 -25 498 1022 738 856 625 61 191 -805 -836 -1184 -1276 -1256 -1405 -1517 -1595 -1316 -798 -247 285 1125 825 773 659 -27 -609 -582 -381 -222 672 584 283 -545 -1306 -1872 -1243 -732 -1277 -1170 -820 -284 589 1319 1261 742 363 -315 -598 -388 123 401 786 495 795 968 1106 708 659 -112 -110 -167 325 -250 -813 -824 -541 -63 361 282 987 795 414 330 -565 -1257 -1333
SS 20250707T115647.2Z 9319.497769 149 1 51.68 2 67.38 78.75 147.98 282.71 0.00 1 0.00 1 0 17 3.788e-02 8.849e-03 8.739e-03 1.866e-03 3.223819e-01 9.879535e-04 3.767251e-03 -6.000000e+00 2.306378e-02 232.80 -2.00 3.48 -2.00 318.00 0.00e+00 9.973204e-04 1.745799e-04 6.595261e-04 -6.000000e+00 1.034686e-03 289.68 -2.00 20.00 -2.00 317.11 0.00e+00 2.578 0.000 302.00 328.00 3 4.4696e+00 2.6750e-03 3.0839e-02 -6.0000e+00 5.7794e-02 2.4942e-02 3.0246e-03 1.6889e-02 -6.0000e+00 6.2422e-02 -3.6484e-03 1.8643e-03 8.0807e-03 -6.0000e+00 3.7223e-02 -4.5276e-03 9.2586e-04 2.1572e-03 -6.0000e+00 1.5418e-02 3.0930e-04 -3.1746e-04 5.9526e-05 2.6024e-05 -6.0000e+00 1.1743e-03 9.0208e-03 -6.1759e-05 11 8 0 10 0 0 99.99 23.49 0.48 0.00902 0.00664 37 6 1 5 0 1396.520 26.21 20.00 23.49 34.54 6.5 1063.48 -33236 -5483 7765 -2179 -11495 -12769 808 -2920 -10394 -3708 -7372 97 -4992 -2087 715 -2663 426 -3685 -2566 -1475 3330 4054 2063 1206 -1215 24 -2767 -3230 -751 2586 414 482 3044 -2449 -3415 -2742 -2711 -2505 1185 308 -1342 1290 -117 934 21 1188 631 -429 -173 943 806 799 1603 2159 1174 2032 578 7 -567 3 1428 2394 1867 2206 489 -574 -202 -706 971 1502 859 1624 -42 357 -367 -1321 -1754 -1076 -1944 -2624 -1837 -2533 -2082 -1621 -812 -154 75 798 567 312 301 248 -934 -475 -440 376 479 660 317 -648 -895 -1599 -864 -644 -996 -1371 -571 -194 828 1058 1160 623 293 74 -407 320 -73 185 614 593 686 582 727 501 668 -238 93 -357 435 3 -631 -726 -194 -200 -40 -137 565 509 32 198 -132 -580 -868 -2770 -386 499 -149 -799 -864 50 -207 -878 -312 -660 8 -516 -243 94 -404 67 -641 -464 -274 604 736 392 244 -265 5 -640 -721 -156 520 91 115 770 -677 -929 -738 -790 -768 416 127 -622 618 -59 472 11 603 319 -217 -87 478 432 422 896 1269 725 1277 374 4 -367 2 937 1669 1311 1639 371 -418 -151 -526 699 1197 752 1474 -39 315 -304 -1001 -1330 -786 -1510 -2121 -1657 -2362 -2078 -1707 -907 -170 87 945 672 357 343 260 -929 -464 -456 428 566 857 407 -830 -1158 -1937 -995 -759 -1259 -1840 -749 -268 1198 1630 1767 966 441 111 -574 428 -97 259 909 922 1020 908 1102 730 924 -338 128 -502 607 4 -1008 -1132 -310 -334 -71 -240 1007 925 58 350 -226 -1020 -1515
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