File name: Pandora75s1_EssexMD_20250718_L2Fit_fwvt1c3d20230525p1-8.txt
File generation date: 20250719T052229.8Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 75
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora75_OF_v3d20220127.txt
Instrument calibration file used: Pandora75s1_CF_v3d20230525.txt
Level 1 file used: Pandora75s1_EssexMD_20250718_L1_smca1c3d20230525p1-8.txt
Full location name: MDE Essex Monitoring Site
Short location name: EssexMD
Country of location: United States
Location latitude [deg]: 39.3109
Location longitude [deg]: -76.4745
Location altitude [m]: 12
Local noon date: 20250718
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based on session 2
First and last pixel inside fitting window: 1614 1763
Nominal wavelengths inside fitting window [nm]: 492.0447 492.1659 492.2871 492.4083 492.5295 492.6507 492.7718 492.8929 493.0140 493.1351 493.2562 493.3772 493.4983 493.6193 493.7403 493.8613 493.9823 494.1032 494.2242 494.3451 494.4660 494.5869 494.7078 494.8286 494.9495 495.0703 495.1911 495.3119 495.4326 495.5534 495.6741 495.7948 495.9155 496.0362 496.1569 496.2776 496.3982 496.5188 496.6394 496.7600 496.8806 497.0011 497.1216 497.2422 497.3627 497.4831 497.6036 497.7240 497.8445 497.9649 498.0853 498.2057 498.3260 498.4464 498.5667 498.6870 498.8073 498.9276 499.0479 499.1681 499.2883 499.4085 499.5287 499.6489 499.7691 499.8892 500.0093 500.1294 500.2495 500.3696 500.4896 500.6097 500.7297 500.8497 500.9697 501.0897 501.2096 501.3296 501.4495 501.5694 501.6893 501.8091 501.9290 502.0488 502.1686 502.2884 502.4082 502.5280 502.6477 502.7675 502.8872 503.0069 503.1265 503.2462 503.3659 503.4855 503.6051 503.7247 503.8443 503.9638 504.0834 504.2029 504.3224 504.4419 504.5614 504.6808 504.8002 504.9197 505.0391 505.1585 505.2778 505.3972 505.5165 505.6358 505.7551 505.8744 505.9937 506.1129 506.2322 506.3514 506.4706 506.5897 506.7089 506.8281 506.9472 507.0663 507.1854 507.3045 507.4235 507.5426 507.6616 507.7806 507.8996 508.0185 508.1375 508.2564 508.3754 508.4943 508.6131 508.7320 508.8509 508.9697 509.0885 509.2073 509.3261 509.4449 509.5636 509.6823 509.8010 509.9197
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250718T132123.4Z 9330.556521 270 1 5.90 2 52.25 92.90 36.22 237.62 0.00 1 0.00 1 0 15 3.101e-03 3.096e-03 1.050e-04 1.049e-04 4.060808e+03 6.949853e+00 2.778303e+02 -6.000000e+00 1.846560e+02 290.53 -2.00 20.00 -2.00 505.27 0.00e+00 4.867582e-04 2.993549e-06 3.137396e-05 -6.000000e+00 9.015058e-05 290.53 -2.00 20.00 -2.00 500.49 0.00e+00 -1.848503e-02 2.109209e-03 2.734672e-02 -6.000000e+00 6.275548e-02 232.67 -2.00 3.48 -2.00 502.08 0.00e+00 1.629 0.000 489.00 513.00 1 1.2416e+00 1.6246e-04 3.3693e-03 -6.0000e+00 4.8364e-03 -6.0728e-03 4.1197e-05 6.5865e-04 -6.0000e+00 1.2362e-03 4.4364e-01 2.9932e-04 1.1687e-05 2.6957e-05 -6.0000e+00 3.5943e-04 9.1080e-03 5.1976e-05 10 0 0 10 0 0 88.27 23.51 1.85 0.00911 0.01118 847 138 1 4 0 6.960 26.21 19.99 23.51 38.09 6.7 1086.61 -546 -363 -185 -183 -15 395 581 482 414 377 316 6 -238 -179 -264 -370 -185 59 19 -70 33 164 293 426 483 342 203 -109 -356 -346 -305 -376 -23 253 -50 -262 -91 71 -52 -26 88 146 219 354 440 405 346 212 -20 -330 -483 -624 -672 -519 -278 -250 -252 -170 -26 207 389 436 339 319 279 158 72 -63 -211 -218 -129 -155 -97 63 -23 -312 -370 -281 -300 -265 -315 -488 -409 -134 -131 -287 -215 -31 30 118 325 519 436 309 390 276 -29 -231 -282 -469 -539 -406 -136 -176 -423 -482 -443 -310 -111 13 -63 -32 138 279 456 655 662 445 378 312 228 248 420 354 188 199 196 152 195 4 -219 -294 -371 -572 -320 -102 -124 -172 21 126 180 323 399 298 157 -33 -247 -274 -257 -228 -531 -356 -184 -185 -16 405 604 505 434 391 324 6 -241 -180 -264 -372 -188 61 19 -73 34 172 303 442 502 356 213 -113 -366 -347 -306 -379 -24 258 -52 -274 -95 73 -54 -26 90 150 224 365 457 421 357 217 -21 -333 -482 -611 -654 -509 -274 -250 -256 -172 -27 210 394 443 346 325 282 160 72 -63 -208 -213 -125 -151 -95 63 -22 -310 -363 -272 -292 -257 -307 -472 -399 -131 -128 -284 -213 -31 29 117 321 517 438 310 387 273 -28 -222 -268 -443 -511 -386 -132 -173 -419 -480 -438 -307 -109 13 -63 -32 138 280 460 663 672 452 381 310 227 244 410 347 185 196 193 149 191 4 -215 -286 -356 -546 -307 -99 -121 -171 21 126 181 322 399 298 157 -33 -244 -269 -249 -221
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SQ 20250718T132135.4Z 9330.556659 270 3 5.92 2 52.21 92.93 36.25 237.68 0.00 1 0.00 1 0 15 3.019e-03 3.017e-03 1.989e-04 1.986e-04 4.053732e+03 1.315160e+01 2.772093e+02 -6.000000e+00 1.798190e+02 290.53 -2.00 20.00 -2.00 505.27 0.00e+00 4.707462e-04 5.663879e-06 3.065907e-05 -6.000000e+00 8.778794e-05 290.53 -2.00 20.00 -2.00 500.47 0.00e+00 -9.788227e-03 3.998616e-03 2.725097e-02 -6.000000e+00 6.110823e-02 232.67 -2.00 3.48 -2.00 502.06 0.00e+00 1.628 0.000 489.00 513.00 1 2.4620e+00 3.0788e-04 3.3583e-03 -6.0000e+00 4.7094e-03 -3.9354e-03 7.8134e-05 6.5662e-04 -6.0000e+00 1.2037e-03 1.3090e-01 3.0541e-04 2.2108e-05 2.7227e-05 -6.0000e+00 3.5001e-04 9.2005e-03 5.5310e-05 10 0 0 10 0 0 99.04 23.51 1.84 0.00920 0.01132 847 138 1 4 0 6.960 26.21 19.99 23.51 38.09 6.7 1086.61 -513 -336 -172 -198 6 382 535 431 382 376 309 11 -195 -148 -253 -368 -178 62 9 -74 34 189 271 423 503 331 210 -122 -369 -343 -331 -365 -27 246 -40 -293 -92 40 -25 21 62 132 207 358 400 412 335 220 -36 -334 -454 -632 -652 -551 -276 -255 -223 -194 -36 185 417 450 330 340 253 169 84 -37 -219 -213 -122 -160 -93 40 -31 -293 -340 -283 -246 -252 -288 -471 -373 -168 -136 -276 -231 -23 44 115 307 474 466 304 379 250 -25 -240 -275 -462 -464 -396 -80 -172 -432 -489 -433 -303 -92 -35 -57 14 108 288 455 617 669 423 378 253 217 258 427 348 152 203 182 144 195 -75 -226 -299 -366 -517 -305 -104 -125 -196 -6 121 190 330 405 281 153 -50 -223 -245 -226 -208 -503 -332 -171 -199 6 391 557 453 401 390 316 11 -199 -150 -255 -373 -182 63 10 -77 35 197 283 442 526 347 218 -125 -379 -344 -335 -371 -27 255 -42 -307 -96 42 -26 21 62 134 213 372 417 430 348 226 -36 -337 -447 -623 -638 -544 -272 -258 -226 -198 -37 189 425 460 338 348 257 169 85 -37 -216 -208 -118 -156 -91 40 -31 -290 -333 -273 -235 -240 -276 -455 -363 -165 -135 -270 -227 -23 44 113 305 475 470 306 377 245 -24 -229 -263 -438 -441 -375 -78 -170 -426 -485 -426 -301 -91 -34 -56 14 109 292 454 618 672 426 377 254 215 252 416 340 149 199 179 141 190 -73 -218 -291 -352 -495 -292 -101 -121 -193 -6 119 188 329 405 282 153 -50 -218 -239 -218 -201
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