File name: Pandora280s1_Eureka-0PAL_20250308_L2Fit_fwvt1c2d20240201p1-8.txt File generation date: 20250309T055954.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Kimberly Strong Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 280 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora280_OF_v3d20230919.txt Instrument calibration file used: Pandora280s1_CF_v2d20240201.txt Level 1 file used: Pandora280s1_Eureka-0PAL_20250308_L1_smca1c2d20240201p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) 0PAL facility Short location name: Eureka-0PAL Country of location: Canada Location latitude [deg]: 79.9903 Location longitude [deg]: -85.9389 Location altitude [m]: 14 Local noon date: 20250308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1623 1772 Nominal wavelengths inside fitting window [nm]: 492.1190 492.2398 492.3605 492.4813 492.6020 492.7227 492.8434 492.9641 493.0847 493.2054 493.3260 493.4466 493.5672 493.6878 493.8084 493.9289 494.0494 494.1699 494.2904 494.4109 494.5314 494.6518 494.7722 494.8926 495.0130 495.1334 495.2538 495.3741 495.4944 495.6147 495.7350 495.8553 495.9756 496.0958 496.2160 496.3362 496.4564 496.5766 496.6967 496.8169 496.9370 497.0571 497.1772 497.2973 497.4173 497.5374 497.6574 497.7774 497.8974 498.0173 498.1373 498.2572 498.3771 498.4970 498.6169 498.7368 498.8566 498.9765 499.0963 499.2161 499.3359 499.4556 499.5754 499.6951 499.8148 499.9345 500.0542 500.1739 500.2935 500.4132 500.5328 500.6524 500.7719 500.8915 501.0110 501.1306 501.2501 501.3696 501.4890 501.6085 501.7279 501.8474 501.9668 502.0862 502.2055 502.3249 502.4442 502.5636 502.6829 502.8022 502.9214 503.0407 503.1599 503.2791 503.3983 503.5175 503.6367 503.7558 503.8750 503.9941 504.1132 504.2323 504.3513 504.4704 504.5894 504.7084 504.8274 504.9464 505.0654 505.1843 505.3032 505.4221 505.5410 505.6599 505.7788 505.8976 506.0164 506.1352 506.2540 506.3728 506.4916 506.6103 506.7290 506.8477 506.9664 507.0851 507.2037 507.3224 507.4410 507.5596 507.6782 507.7967 507.9153 508.0338 508.1523 508.2708 508.3893 508.5077 508.6262 508.7446 508.8630 508.9814 509.0998 509.2181 509.3365 509.4548 509.5731 509.6914 509.8097 509.9279 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250308T143951.1Z 9198.611008 369 1 8.22 2 88.00 131.52 72.59 15.41 0.00 1 0.00 1 0 22 3.875e-03 3.893e-03 1.209e-03 1.207e-03 2.544004e+03 6.394885e+01 1.798613e+02 -6.000000e+00 1.911236e+02 250.08 -2.00 20.00 -2.00 505.35 0.00e+00 8.383249e-04 3.108202e-05 5.041329e-05 -6.000000e+00 1.011915e-04 250.08 -2.00 20.00 -2.00 500.89 0.00e+00 1.365408e+00 2.386011e-02 3.365994e-02 -6.000000e+00 7.859618e-02 220.32 -2.00 5.56 -2.00 502.42 0.00e+00 16.273 0.143 489.00 513.00 1 4.0533e+00 1.8066e-03 3.1203e-02 -6.0000e+00 5.9646e-03 -2.7267e-02 4.6762e-04 1.8374e-03 -6.0000e+00 1.5666e-03 2.9825e-03 -1.8785e-03 1.2478e-04 3.9739e-05 -6.0000e+00 4.1101e-04 5.5518e-02 -7.1642e-04 12 9 1 12 1 1 67.04 25.56 2.24 0.05552 0.04249 6 6 1 4 0 1173.010 33.50 19.99 25.56 -24.05 2.4 1041.19 484 32 -23 -341 385 648 240 193 64 89 124 103 -122 95 337 34 390 95 -308 -350 -295 198 530 292 23 73 57 -566 -524 488 604 685 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658 690 333 22 -14 320 196 261 48 -451 -266 150 307 718 504 -107 -323 -198 -131 31 215 442 -2 -272 -689 -827 -197 285 340 SQ 20250308T144407.6Z 9198.613977 374 1 53.26 2 87.86 132.58 72.54 16.37 0.00 1 0.00 1 0 15 3.549e-03 3.569e-03 1.609e-04 1.606e-04 2.524910e+03 8.503458e+00 1.780562e+02 -6.000000e+00 1.750988e+02 250.08 -2.00 20.00 -2.00 505.34 0.00e+00 7.930725e-04 4.135375e-06 4.744668e-05 -6.000000e+00 9.272427e-05 250.08 -2.00 20.00 -2.00 500.86 0.00e+00 1.366730e+00 3.176959e-03 3.267507e-02 -6.000000e+00 7.204368e-02 220.32 -2.00 5.56 -2.00 502.40 0.00e+00 15.886 0.133 489.00 513.00 1 2.1247e+00 2.4055e-04 2.9847e-02 -6.0000e+00 5.4669e-03 -2.7846e-02 6.2268e-05 1.7643e-03 -6.0000e+00 1.4369e-03 2.1692e-02 1.7788e-04 1.6582e-05 3.8885e-05 -6.0000e+00 3.7653e-04 1.2651e-02 -5.1184e-04 10 0 0 10 0 0 84.26 25.56 2.18 0.01265 0.01389 332 42 1 4 0 160.400 33.50 20.00 25.56 -23.38 2.3 1042.53 478 121 -230 -297 130 400 265 43 -17 217 250 54 0 44 136 279 373 40 -399 -291 69 244 357 298 109 110 2 -432 -436 357 635 608 490 -218 -850 -640 -113 81 118 212 230 145 145 90 -81 -126 -54 -70 -312 -455 -295 -46 258 357 -44 -529 -658 -427 -22 318 465 265 -18 -135 -153 44 290 110 -188 -144 133 119 28 -350 -759 -708 -188 218 120 -24 -187 -346 -368 -65 -259 -397 -330 -142 -5 76 270 125 -318 -533 -275 -122 -166 -270 -293 -19 227 362 -25 -748 -1276 -871 -363 180 586 507 181 -6 47 190 507 657 519 175 110 242 415 616 756 424 10 73 229 274 341 -12 -430 -154 191 310 519 476 -47 -304 -196 -49 -24 210 271 54 -219 -640 -703 -340 243 313 433 111 -212 -280 124 386 258 42 -16 212 242 52 0 41 130 264 359 38 -393 -290 68 242 355 298 109 110 2 -433 -428 347 612 582 474 -217 -856 -650 -114 81 118 210 228 144 145 91 -83 -128 -55 -71 -314 -448 -289 -44 246 343 -43 -524 -661 -430 -22 319 466 267 -18 -136 -153 44 289 108 -184 -141 129 116 27 -346 -753 -701 -185 213 116 -23 -181 -336 -361 -64 -257 -393 -329 -142 -5 76 269 125 -324 -542 -278 -122 -166 -266 -286 -18 218 351 -24 -750 -1295 -890 -368 181 584 508 182 -7 48 197 527 679 541 184 115 251 429 628 773 432 11 76 235 281 350 -12 -442 -158 193 313 522 480 -48 -315 -205 -52 -26 222 288 58 -234 -685 -751 -359 253 323 SQ 20250308T144718.7Z 9198.616189 378 1 53.19 2 87.76 133.37 72.51 17.08 0.00 1 0.00 1 0 15 3.549e-03 3.569e-03 1.356e-04 1.353e-04 2.471774e+03 7.166138e+00 1.724676e+02 -6.000000e+00 1.750910e+02 250.08 -2.00 20.00 -2.00 505.34 0.00e+00 7.811565e-04 3.483565e-06 4.668251e-05 -6.000000e+00 9.270938e-05 250.08 -2.00 20.00 -2.00 500.86 0.00e+00 1.360512e+00 2.677183e-03 3.269881e-02 -6.000000e+00 7.201575e-02 220.32 -2.00 5.56 -2.00 502.40 0.00e+00 15.606 0.126 489.00 513.00 1 1.8232e+00 2.0268e-04 2.8910e-02 -6.0000e+00 5.4651e-03 -2.8930e-02 5.2470e-05 1.7159e-03 -6.0000e+00 1.4357e-03 3.0541e-02 -5.3773e-04 1.3998e-05 3.7510e-05 -6.0000e+00 3.7651e-04 7.0344e-03 -4.4361e-04 10 0 0 10 0 0 93.97 25.56 2.13 0.00703 0.00330 505 64 1 4 0 105.320 33.50 20.00 25.56 -23.47 2.3 1043.37 478 142 -231 -345 90 397 239 -12 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