File name: Pandora280s1_Eureka-0PAL_20250721_L2Fit_fout2c3d20240808p1-8.txt File generation date: 20250722T070850.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Kimberly Strong Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 280 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora280_OF_v3d20230919.txt Instrument calibration file used: Pandora280s1_CF_v3d20240808.txt Level 1 file used: Pandora280s1_Eureka-0PAL_20250721_L1_smca1c3d20240808p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) 0PAL facility Short location name: Eureka-0PAL Country of location: Canada Location latitude [deg]: 79.9903 Location longitude [deg]: -85.9389 Location altitude [m]: 14 Local noon date: 20250721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1972 305.3379 305.4787 305.6194 305.7602 305.9009 306.0416 306.1823 306.3230 306.4637 306.6043 306.7450 306.8856 307.0263 307.1669 307.3075 307.4481 307.5887 307.7292 307.8698 308.0104 308.1509 308.2914 308.4320 308.5725 308.7130 308.8534 308.9939 309.1344 309.2748 309.4153 309.5557 309.6961 309.8365 309.9769 310.1173 310.2577 310.3980 310.5384 310.6787 310.8191 310.9594 311.0997 311.2400 311.3803 311.5205 311.6608 311.8010 311.9413 312.0815 312.2217 312.3619 312.5021 312.6423 312.7824 312.9226 313.0627 313.2029 313.3430 313.4831 313.6232 313.7633 313.9034 314.0434 314.1835 314.3235 314.4636 314.6036 314.7436 314.8836 315.0236 315.1635 315.3035 315.4435 315.5834 315.7233 315.8632 316.0031 316.1430 316.2829 316.4228 316.5627 316.7025 316.8423 316.9822 317.1220 317.2618 317.4016 317.5413 317.6811 317.8209 317.9606 318.1003 318.2401 318.3798 318.5195 318.6592 318.7988 318.9385 319.0781 319.2178 319.3574 319.4970 319.6366 319.7762 319.9158 320.0554 320.1949 320.3345 320.4740 320.6136 320.7531 320.8926 321.0321 321.1715 321.3110 321.4505 321.5899 321.7293 321.8687 322.0082 322.1476 322.2869 322.4263 322.5657 322.7050 322.8444 322.9837 323.1230 323.2623 323.4016 323.5409 323.6801 323.8194 323.9586 324.0979 324.2371 324.3763 324.5155 324.6547 324.7939 324.9330 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250721T091340.6Z 9333.384498 95 1 52.68 2 76.11 48.50 62.07 94.93 0.00 1 0.00 1 0 25 3.515e-01 1.984e-02 1.033e-01 4.162e-03 4.941659e-01 2.184679e-03 9.079321e-03 -6.000000e+00 2.059668e-01 236.31 -2.00 5.56 -2.00 320.11 0.00e+00 1.088359e-03 6.708716e-04 2.005032e-03 -6.000000e+00 8.928782e-03 272.75 -2.00 20.00 -2.00 319.59 0.00e+00 4.068 0.002 302.00 328.00 3 3.6787e+00 6.3905e-03 6.0346e-02 -6.0000e+00 5.2453e-01 7.2299e-02 7.5811e-03 4.3891e-02 -6.0000e+00 5.6678e-01 -1.4916e-01 6.4093e-03 2.1542e-02 -6.0000e+00 3.3320e-01 7.2390e-02 3.2861e-03 5.9591e-03 -6.0000e+00 1.3846e-01 1.3475e-04 -6.4206e-04 1.1925e-04 7.1749e-05 -6.0000e+00 9.4620e-03 4.7370e-03 0.0000e+00 12 9 8 11 8 0 99.98 25.69 0.02 0.00474 -0.00009 29 4 1 5 0 1816.310 33.50 20.00 25.69 10.01 0.1 1100.00 -38962 -32494 -68717 -51103 -114363 -102428 -141966 -96081 -21985 239080 900000 -113003 -73787 -49296 31185 -22977 -55396 -25843 60529 2147 31895 -280 -13187 -384 -6309 4736 -21142 53983 -33545 20686 26586 40129 30223 67065 -9282 -666 10332 3787 12331 27071 -4448 19944 15131 11288 1917 2231 -1149 5109 11277 3597 9447 555 7976 9712 3629 -4009 7918 132 7769 8017 680 5464 1567 3622 -3155 4924 3719 6953 -2277 -1451 536 -5163 -3854 -979 -96 5965 -1050 -2872 -2362 -5937 -1128 1474 -376 791 -227 -2193 -2207 -1678 -657 -1675 410 2284 -2764 671 -541 -802 -538 2219 338 1422 -1075 -2194 -588 -1935 -2693 202 -1476 -1349 148 1588 -381 22 1056 -525 -283 24 413 -673 616 1236 226 1519 677 335 2818 1333 -511 198 449 1527 -134 -111 -552 339 -751 -343 752 192 -545 -239 -1229 -151 -122 -632 -563 -1800 -1075 -4092 -3450 -6913 -3704 -455 970 900000 -6833 -3593 -2300 785 -1147 -4181 -1563 1646 110 1242 -15 -829 -23 -430 304 -1767 2037 -2913 1074 1467 2231 2097 3402 -964 -62 943 438 1601 3603 -906 3391 2812 2222 417 490 -262 1103 2329 836 2254 160 2314 2976 1243 -1397 2773 50 2661 2700 253 2113 640 1598 -1543 2127 1552 2821 -1104 -802 322 -3444 -2532 -598 -53 2821 -488 -1332 -1180 -3574 -749 1077 -305 671 -191 -2020 -2152 -1684 -655 -1632 365 2012 -2398 561 -499 -774 -591 2684 417 1744 -1378 -2579 -629 -2130 -3237 251 -1959 -1747 203 2360 -629 35 1778 -857 -430 34 590 -1016 981 2069 387 2500 1087 521 4089 1883 -701 275 683 2547 -229 -198 -1027 657 -1573 -706 1572 412 -1182 -502 -2652 -306 -238 SS 20250721T092433.4Z 9333.392053 102 1 11.83 2 75.75 51.10 61.60 97.52 0.00 1 0.00 1 0 25 1.392e-01 8.277e-03 3.027e-02 2.444e-03 5.006054e-01 1.266956e-03 9.138164e-03 -6.000000e+00 8.158628e-02 236.31 -2.00 5.56 -2.00 319.28 0.00e+00 1.527872e-03 3.081775e-04 3.934901e-04 -6.000000e+00 3.359527e-03 272.75 -2.00 20.00 -2.00 318.74 0.00e+00 3.973 0.002 302.00 328.00 3 1.6261e+00 3.5505e-03 5.9436e-02 -6.0000e+00 2.0777e-01 4.7504e-02 4.0736e-03 4.2767e-02 -6.0000e+00 2.2442e-01 -5.0737e-02 3.2013e-03 2.0944e-02 -6.0000e+00 1.3196e-01 1.8365e-02 1.6893e-03 6.0029e-03 -6.0000e+00 5.4755e-02 1.1188e-03 -4.4405e-04 6.7036e-05 5.9057e-05 -6.0000e+00 3.7156e-03 1.1170e-04 0.0000e+00 12 9 1 12 1 1 98.48 25.70 0.24 0.00011 -0.00323 22 13 1 5 0 513.760 33.50 20.00 25.70 10.43 0.1 1100.00 -50187 -35661 -52789 -30203 -52880 -82781 -62807 -27238 -30770 -17324 7406 -31517 -26905 -12910 -1504 -6592 -16411 -9843 167 2008 -6498 -8820 -4660 1543 -7870 -6110 -14333 -1751 -12984 202 -241 3439 2215 6134 -3554 -6368 -4457 -1523 3964 5991 -1705 465 2141 1915 -32 347 -2743 2418 960 1687 3350 789 2430 1550 2313 610 1576 341 2007 532 508 2162 2400 2073 907 1224 -278 85 -352 39 1531 -34 -143 200 -215 519 -562 -1399 -929 -1512 -977 -848 -1519 -1272 -1363 -1390 -731 -13 108 155 1256 483 -370 -37 -95 487 415 -64 176 501 -187 -1400 -948 -248 -1073 -857 -541 -1227 -324 197 491 466 438 418 -263 270 -4 -31 307 216 -220 226 -50 459 1038 771 149 794 743 912 648 -178 -324 156 -149 -37 -163 -83 -494 13 -183 -337 -474 -1172 -833 -1560 -691 -1387 -2842 -1901 -662 -880 -467 161 -1097 -1077 -557 -71 -380 -1154 -704 12 145 -528 -736 -387 130 -790 -636 -1643 -171 -1368 19 -26 420 311 883 -541 -979 -668 -264 797 1409 -486 127 603 553 -9 105 -860 728 300 546 1163 311 1026 657 1025 285 753 165 936 249 244 1114 1282 1229 566 731 -161 49 -223 27 1133 -27 -113 151 -150 347 -348 -855 -612 -1086 -758 -744 -1376 -1216 -1394 -1442 -797 -15 121 168 1259 478 -346 -35 -96 525 483 -81 230 653 -242 -1753 -1090 -286 -1352 -1088 -719 -1654 -465 295 764 760 707 645 -397 384 -6 -46 465 346 -358 358 -77 706 1516 1134 210 1130 1110 1445 1070 -312 -565 284 -279 -71 -321 -167 -999 25 -354 -619 -875 SS 20250721T092934.4Z 9333.395537 105 1 3.76 2 75.58 52.30 61.39 98.71 0.00 1 0.00 1 0 17 2.244e-01 1.729e-02 1.986e-01 1.241e-02 5.074387e-01 6.456881e-03 9.198762e-03 -6.000000e+00 1.315883e-01 236.31 -2.00 5.56 -2.00 319.63 0.00e+00 -1.082896e-03 1.728996e-03 4.621323e-04 -6.000000e+00 5.417968e-03 272.75 -2.00 20.00 -2.00 319.09 0.00e+00 3.929 0.002 302.00 328.00 3 2.9333e+00 1.8377e-02 5.9636e-02 -6.0000e+00 3.3510e-01 1.0508e-01 2.1469e-02 4.3500e-02 -6.0000e+00 3.6195e-01 -1.2822e-01 1.7317e-02 2.1302e-02 -6.0000e+00 2.1284e-01 5.2045e-02 8.9967e-03 6.0607e-03 -6.0000e+00 8.8319e-02 3.1123e-04 -9.4495e-04 3.4627e-04 6.1430e-05 -6.0000e+00 5.9922e-03 -4.2265e-04 0.0000e+00 12 9 9 12 33 1 999.00 25.71 0.41 -0.00042 -0.00752 1 4 1 5 0 1877.860 33.50 20.01 25.71 10.72 0.1 1100.00 5707 10412 -57529 20864 -13009 -110809 -116070 -24774 -26002 13770 -27897 -94061 -43435 -68868 22368 -17072 -14017 -30922 109814 17421 -4996 -6621 -24158 -6912 -10759 -10089 -17409 41716 -3855 5423 28252 4917 32989 16563 -7879 381 -815 -15085 10474 10979 -4258 9884 8135 -805 6279 1899 -2465 8350 1927 5634 8068 7940 10211 6466 6258 -2447 11368 1083 26 -216 -2796 -1941 -2485 107 -1159 4244 2451 2969 -2856 2945 -190 -1985 -1707 533 -1850 3020 -388 -2209 -1165 1909 -2462 -1819 -3871 1113 560 275 -1879 -315 -887 -80 1522 610 618 -92 -78 284 -471 17 -210 -729 -850 -2030 -736 -1324 -903 -147 329 -991 -139 -209 -75 -251 368 1693 -1449 713 -1115 -851 239 305 534 2136 498 786 560 174 572 1697 966 1068 95 -72 -250 1209 -81 -574 602 -755 515 237 -741 -620 -1663 76 151 -1741 278 -220 -4829 -5761 -570 -693 267 -844 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