File name: Pandora280s1_Eureka-0PAL_20250728_L2Fit_fout2c3d20240808p1-8.txt File generation date: 20250729T060745.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Kimberly Strong Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 280 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora280_OF_v3d20230919.txt Instrument calibration file used: Pandora280s1_CF_v3d20240808.txt Level 1 file used: Pandora280s1_Eureka-0PAL_20250728_L1_smca1c3d20240808p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) 0PAL facility Short location name: Eureka-0PAL Country of location: Canada Location latitude [deg]: 79.9903 Location longitude [deg]: -85.9389 Location altitude [m]: 14 Local noon date: 20250728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1972 305.3379 305.4787 305.6194 305.7602 305.9009 306.0416 306.1823 306.3230 306.4637 306.6043 306.7450 306.8856 307.0263 307.1669 307.3075 307.4481 307.5887 307.7292 307.8698 308.0104 308.1509 308.2914 308.4320 308.5725 308.7130 308.8534 308.9939 309.1344 309.2748 309.4153 309.5557 309.6961 309.8365 309.9769 310.1173 310.2577 310.3980 310.5384 310.6787 310.8191 310.9594 311.0997 311.2400 311.3803 311.5205 311.6608 311.8010 311.9413 312.0815 312.2217 312.3619 312.5021 312.6423 312.7824 312.9226 313.0627 313.2029 313.3430 313.4831 313.6232 313.7633 313.9034 314.0434 314.1835 314.3235 314.4636 314.6036 314.7436 314.8836 315.0236 315.1635 315.3035 315.4435 315.5834 315.7233 315.8632 316.0031 316.1430 316.2829 316.4228 316.5627 316.7025 316.8423 316.9822 317.1220 317.2618 317.4016 317.5413 317.6811 317.8209 317.9606 318.1003 318.2401 318.3798 318.5195 318.6592 318.7988 318.9385 319.0781 319.2178 319.3574 319.4970 319.6366 319.7762 319.9158 320.0554 320.1949 320.3345 320.4740 320.6136 320.7531 320.8926 321.0321 321.1715 321.3110 321.4505 321.5899 321.7293 321.8687 322.0082 322.1476 322.2869 322.4263 322.5657 322.7050 322.8444 322.9837 323.1230 323.2623 323.4016 323.5409 323.6801 323.8194 323.9586 324.0979 324.2371 324.3763 324.5155 324.6547 324.7939 324.9330 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250728T103142.5Z 9340.438686 123 1 53.32 2 74.75 67.48 95.98 27.57 0.00 1 0.00 1 0 25 5.938e-02 6.308e-03 3.433e-03 4.639e-04 4.280163e-01 2.386751e-04 7.913626e-03 -6.000000e+00 3.472174e-02 235.60 -2.00 5.56 -2.00 318.59 0.00e+00 8.766972e-04 4.659125e-05 2.397929e-04 -6.000000e+00 1.431696e-03 272.45 -2.00 20.00 -2.00 318.03 0.00e+00 3.728 0.002 302.00 328.00 3 2.6625e-01 6.5581e-04 5.2858e-02 -6.0000e+00 8.8267e-02 9.6645e-03 7.3866e-04 3.6350e-02 -6.0000e+00 9.5402e-02 -2.3292e-02 5.1471e-04 1.7648e-02 -6.0000e+00 5.6124e-02 7.9756e-03 2.6998e-04 4.9029e-03 -6.0000e+00 2.3316e-02 6.1635e-03 -4.4589e-04 1.2882e-05 4.8731e-05 -6.0000e+00 1.5851e-03 1.7443e-04 0.0000e+00 10 0 0 10 0 0 87.50 25.74 0.32 0.00017 -0.00318 577 73 1 5 0 92.400 33.50 20.00 25.74 9.10 0.2 1100.00 -23735 -20066 -17614 -19020 -22371 -29125 -21335 -16308 -15412 -14572 -12567 -15235 -9525 -5427 -2704 -1659 -2143 -1118 1103 -494 141 -184 -137 -280 -375 -287 -2274 -2575 -2932 -1893 -61 1385 2038 902 -2312 -3459 -2685 -1190 233 585 -83 428 205 295 519 526 -123 264 -216 386 1209 1220 1635 1510 795 1013 953 599 838 658 903 1500 1825 2089 1183 723 -597 -724 160 700 495 94 -31 115 -188 -396 -845 -1214 -948 -1068 -629 -1113 -1693 -1628 -1275 -1064 -350 -32 159 340 716 472 -116 220 269 251 409 197 300 386 -227 -1277 -703 -312 -790 -544 -701 -877 -259 370 432 493 508 207 -30 127 -102 136 33 5 -76 62 -78 413 843 509 322 695 570 767 539 39 -263 66 -193 -162 22 -88 -231 60 -152 -531 -457 -913 -849 -767 -810 -895 -1204 -876 -730 -775 -780 -673 -895 -622 -413 -240 -167 -236 -131 123 -59 17 -23 -17 -38 -55 -45 -364 -397 -433 -282 -10 253 415 196 -497 -736 -619 -294 69 190 -31 166 83 122 216 222 -52 112 -93 170 530 588 849 785 437 575 557 353 482 375 529 887 1196 1407 829 484 -407 -491 109 547 405 77 -26 96 -146 -293 -608 -849 -665 -816 -551 -1043 -1647 -1672 -1329 -1136 -394 -37 186 383 784 478 -116 214 282 270 476 248 394 506 -294 -1585 -843 -362 -999 -700 -910 -1203 -362 540 657 779 791 317 -45 178 -142 198 49 8 -118 95 -120 611 1232 716 449 972 837 1192 871 63 -445 114 -342 -304 42 -168 -445 112 -282 -971 -809 SS 20250728T103719.1Z 9340.442583 126 1 53.27 2 74.52 68.83 95.89 28.93 0.00 1 0.00 1 0 17 5.366e-02 6.237e-03 3.221e-03 4.508e-04 4.221955e-01 2.313927e-04 7.807754e-03 -6.000000e+00 3.137680e-02 235.60 -2.00 5.56 -2.00 318.53 0.00e+00 8.038386e-04 4.440582e-05 2.333790e-04 -6.000000e+00 1.293689e-03 272.45 -2.00 20.00 -2.00 317.97 0.00e+00 3.678 0.002 302.00 328.00 3 2.6491e-01 6.3512e-04 5.2128e-02 -6.0000e+00 7.9764e-02 8.2214e-03 7.1493e-04 3.5839e-02 -6.0000e+00 8.6210e-02 -2.1247e-02 4.9449e-04 1.7397e-02 -6.0000e+00 5.0716e-02 6.8581e-03 2.5904e-04 4.8263e-03 -6.0000e+00 2.1070e-02 6.5281e-03 -3.6042e-04 1.2520e-05 4.8364e-05 -6.0000e+00 1.4323e-03 -1.8576e-04 0.0000e+00 10 0 0 10 0 0 15.81 25.74 0.32 -0.00019 -0.00289 609 77 1 5 0 87.460 33.50 19.99 25.74 9.39 0.2 1100.00 -21834 -16689 -16537 -18391 -20380 -25812 -19923 -15943 -10889 -12127 -10521 -14394 -8946 -5215 -2639 -1930 -2186 -2044 1772 -15 378 -802 -180 -335 -242 -494 -2200 -2402 -2759 -1506 -389 1244 2132 586 -2202 -2972 -2824 -817 421 391 179 153 60 219 746 325 -189 154 -231 347 1164 1246 1747 1277 923 921 921 577 618 690 896 1513 1926 1907 1128 720 -645 -737 170 665 533 15 37 121 -46 -339 -970 -1241 -809 -1022 -765 -1209 -1631 -1654 -1368 -958 -278 -46 133 286 710 412 -190 190 329 227 438 201 364 333 -225 -1256 -739 -263 -769 -649 -685 -810 -269 422 434 467 558 241 -43 97 -53 55 14 12 -142 98 -97 391 816 572 306 695 532 852 496 48 -304 80 -159 -189 -3 -44 -233 53 -140 -518 -480 -874 -723 -754 -822 -844 -1091 -852 -751 -553 -669 -582 -883 -611 -415 -245 -204 -252 -229 204 -2 48 -103 -24 -48 -37 -80 -366 -384 -423 -232 -65 235 448 132 -487 -649 -672 -207 129 131 67 61 25 93 318 141 -82 67 -102 146 522 614 925 679 517 534 549 346 363 401 535 912 1284 1310 804 489 -446 -507 118 497 442 12 31 102 -36 -254 -666 -879 -573 -789 -642 -1145 -1600 -1631 -1439 -1030 -315 -52 156 324 785 420 -190 187 330 246 512 255 478 438 -291 -1563 -850 -307 -977 -839 -893 -1116 -378 618 661 738 868 369 -64 136 -74 79 21 18 -223 150 -150 579 1193 803 427 972 780 1321 800 79 -514 136 -280 -353 -6 -84 -446 98 -257 -943 -846 SS 20250728T104748.3Z 9340.449865 129 1 53.25 2 74.10 71.37 95.71 31.48 0.00 1 0.00 1 0 17 4.646e-02 6.106e-03 2.741e-03 4.237e-04 4.104350e-01 2.177439e-04 7.591573e-03 -6.000000e+00 2.716661e-02 235.60 -2.00 5.56 -2.00 318.44 0.00e+00 8.571997e-04 4.059902e-05 2.100972e-04 -6.000000e+00 1.120101e-03 272.45 -2.00 20.00 -2.00 317.88 0.00e+00 3.585 0.001 302.00 328.00 3 2.4953e-01 5.9517e-04 5.0718e-02 -6.0000e+00 6.9061e-02 6.9521e-03 6.6871e-04 3.4788e-02 -6.0000e+00 7.4642e-02 -1.9437e-02 4.5433e-04 1.6844e-02 -6.0000e+00 4.3911e-02 6.2830e-03 2.3681e-04 4.6692e-03 -6.0000e+00 1.8243e-02 7.3473e-03 -3.6978e-04 1.1773e-05 4.7299e-05 -6.0000e+00 1.2401e-03 -1.8969e-04 0.0000e+00 10 0 0 10 0 0 54.49 25.75 0.34 -0.00019 -0.00297 652 82 1 5 0 81.660 33.50 20.00 25.75 9.86 0.1 1100.00 -17227 -14239 -16040 -15493 -17745 -21429 -17740 -12561 -10843 -12149 -9769 -11879 -8324 -4286 -2165 -1320 -1904 -366 1166 195 136 75 269 379 72 219 -1380 -2094 -2386 -1297 -490 1270 2264 528 -2212 -3030 -2509 -1048 373 602 123 430 -36 423 504 371 -6 135 -209 223 814 1051 1652 1363 906 919 972 697 624 553 745 1336 1794 1824 1064 637 -762 -831 258 554 444 72 -165 101 -103 -284 -970 -1243 -761 -819 -729 -1099 -1778 -1526 -1338 -950 -298 -48 47 337 743 472 -196 111 302 191 581 269 336 371 -237 -1240 -680 -190 -755 -599 -634 -877 -354 321 491 458 456 140 -33 84 -35 71 10 19 -117 124 -152 375 880 583 358 656 534 799 491 43 -259 39 -221 -171 2 22 -258 42 -167 -521 -487 -755 -689 -832 -768 -816 -986 -844 -649 -624 -758 -606 -800 -634 -378 -223 -154 -221 -45 149 27 19 10 39 59 12 39 -250 -366 -399 -217 -90 260 514 118 -528 -714 -588 -287 123 217 50 171 -15 178 214 159 -3 58 -91 99 388 512 864 765 535 526 572 412 362 317 440 849 1185 1317 795 454 -519 -561 186 431 363 63 -143 84 -84 -209 -693 -860 -558 -653 -631 -1019 -1715 -1549 -1385 -1053 -333 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