File name: Pandora144s1_Eureka-PEARL_20190304_L2Fit_fwvt1c4d20190120p1-8.txt File generation date: 20241125T211918.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190304_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1789 Nominal wavelengths inside fitting window [nm]: 492.0500 492.1708 492.2917 492.4125 492.5333 492.6541 492.7748 492.8956 493.0163 493.1371 493.2578 493.3784 493.4991 493.6198 493.7404 493.8610 493.9816 494.1022 494.2228 494.3433 494.4639 494.5844 494.7049 494.8254 494.9458 495.0663 495.1867 495.3072 495.4276 495.5479 495.6683 495.7887 495.9090 496.0293 496.1496 496.2699 496.3902 496.5104 496.6306 496.7508 496.8710 496.9912 497.1114 497.2315 497.3517 497.4718 497.5919 497.7120 497.8320 497.9521 498.0721 498.1921 498.3121 498.4321 498.5520 498.6720 498.7919 498.9118 499.0317 499.1516 499.2714 499.3913 499.5111 499.6309 499.7507 499.8705 499.9902 500.1100 500.2297 500.3494 500.4691 500.5887 500.7084 500.8280 500.9476 501.0672 501.1868 501.3064 501.4259 501.5455 501.6650 501.7845 501.9040 502.0234 502.1429 502.2623 502.3817 502.5011 502.6205 502.7398 502.8592 502.9785 503.0978 503.2171 503.3364 503.4556 503.5749 503.6941 503.8133 503.9325 504.0516 504.1708 504.2899 504.4090 504.5281 504.6472 504.7663 504.8853 505.0044 505.1234 505.2424 505.3614 505.4803 505.5993 505.7182 505.8371 505.9560 506.0748 506.1937 506.3125 506.4314 506.5502 506.6689 506.7877 506.9065 507.0252 507.1439 507.2626 507.3813 507.5000 507.6186 507.7372 507.8558 507.9744 508.0930 508.2116 508.3301 508.4486 508.5671 508.6856 508.8041 508.9225 509.0410 509.1594 509.2778 509.3962 509.5145 509.6329 509.7512 509.8695 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190304T144016.0Z 7002.611296 4 1 32.00 2 89.87 131.12 98.58 152.23 0.00 1 0.00 1 0 38 4.923e-01 2.852e-01 3.836e-01 2.694e-01 -2.294168e+03 1.536661e+04 7.221939e+02 -6.000000e+00 2.334785e+04 247.86 -2.00 20.00 -2.00 505.59 0.00e+00 4.421109e-03 7.251563e-03 9.907105e-05 -6.000000e+00 1.263762e-02 247.86 -2.00 20.00 -2.00 499.92 0.00e+00 7.038110e+00 5.844688e+00 1.326302e-01 -6.000000e+00 9.808127e+00 219.36 -2.00 5.57 -2.00 501.73 0.00e+00 21.029 0.308 489.00 513.00 1 1.0401e+01 4.4972e-01 5.0101e-02 -6.0000e+00 7.4328e-01 3.6662e-02 1.0947e-01 3.0761e-03 -6.0000e+00 1.9595e-01 1.8235e-06 -4.9891e-03 2.5775e-02 1.2388e-04 -6.0000e+00 4.7624e-02 -1.1608e-01 1.0287e-03 12 8 8 10 0 0 78.38 20.25 13.16 -0.11608 -0.15069 8 2 1 7 0 4000.000 23.64 15.00 20.25 29706 21104 45534 -21416 46658 -23098 10333 -37500 54573 -32973 16130 69171 -5105 2254 -16578 26652 -11738 37512 15672 51913 6318 8243 -15296 35368 29379 -31601 4678 -28068 75697 76053 48039 16554 36622 -5439 16859 -13196 38663 16081 18841 59650 -23651 34167 -25387 36797 -12257 21206 -16497 11900 -3533 41863 13908 9235 67790 27695 67099 11710 145235 7657 132897 -22022 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20199 16573 -3771 6680 20795 2888 29103 -55865 37627 22075 6978 13793 20120 23058 6108 36754 -16179 36683 17521 39554 -80858 38060 16518 12703 37348 535 13582 -28371 36075 23813 37824 23239 38876 -29266 29481 31826 37257 9614 772 33358 -34465 29767 -667 37712 -35688 38523 -21158 -5976 7695 1523 -10283 -15539 5162 -13814 14396 -11063 14772 3177 9921 -12234 -11940 6069 30560 6679 -41571 33159 14274 33159 -3395 46625 -27643 11283 -10639 28559 -18423 8699 -2607 -35546 900000 SO 20190304T144115.0Z 7002.611979 5 1 32.00 2 89.84 131.37 98.56 152.46 0.00 1 0.00 1 0 61 3.799e-01 2.581e-01 3.220e-01 2.476e-01 8.546378e+03 1.550388e+04 4.283399e+02 -6.000000e+00 1.799406e+04 247.86 -2.00 20.00 -2.00 505.07 0.00e+00 -2.444295e-02 6.342608e-03 1.221538e-03 -6.000000e+00 9.786893e-03 247.86 -2.00 20.00 -2.00 499.50 0.00e+00 -5.000173e+00 5.168840e+00 1.720734e-01 -6.000000e+00 7.662805e+00 219.36 -2.00 5.57 -2.00 501.21 0.00e+00 20.982 0.306 489.00 513.00 1 1.1637e+01 3.8829e-01 5.7765e-02 -6.0000e+00 5.7884e-01 2.8952e-01 1.0828e-01 3.2817e-03 -6.0000e+00 1.5613e-01 2.0045e-06 -3.6180e-02 1.6209e-02 4.0329e-04 -6.0000e+00 3.6744e-02 1.1458e-01 -2.1739e-03 12 8 8 10 0 0 96.29 20.25 11.85 0.11458 -0.13638 8 2 1 7 0 4000.000 23.64 15.00 20.25 900000 900000 1582 -2416 6035 3646 -13217 20273 -12579 -15826 68582 -4899 107255 -22220 51779 24975 47542 46595 -15061 1941 -36387 38724 30413 42148 4519 21118 38267 -3912 -11406 32669 -5365 5795 17871 34399 19331 14516 80838 -13953 20718 -486 30932 -17744 -16471 -48082 -19906 54288 -1650 -2382 -31469 59023 9276 3659 -13485 35824 13316 16566 34667 -22674 19337 6981 33700 -12139 36223 7831 15573 -10968 20195 13477 17140 25193 -23768 4947 67482 14120 23522 40868 -3454 -10078 -3312 52518 126742 -12071 -11504 -2546 -29138 10781 24272 -14214 53833 -58 50409 -5833 25205 -19038 49423 -18554 89291 21579 -19993 19896 -11787 88396 -8933 16412 -20852 32225 41388 5926 1150 -17066 17247 15378 33188 19034 50082 -42366 26294 -16155 -5987 72385 43101 77093 -29110 15796 7686 120438 22907 17171 142880 24670 4128 -22818 61669 -13777 19206 -14837 -9408 84259 10503 -15370 -3438 -11477 40025 -10855 -24511 50392 -14806 19930 6329 52297 67159 900000 900000 1712 -2660 6081 3810 -16771 18915 -16666 -22149 42233 -6399 46034 -34830 38649 24235 36374 35650 -21360 2354 -66543 34686 30646 38539 6072 24039 36419 -5621 -17454 31701 -7509 7138 19009 30170 19480 15440 45255 -19343 22424 -654 30016 -25520 -22832 -89149 -27249 37483 -1971 -2642 -46350 37448 9520 3892 -15422 26072 11679 13602 23289 -25145 15517 6514 24526 -13041 25686 6785 13368 -11403 16582 10976 14393 19275 -27181 4200 32741 10766 16303 25930 -3232 -10304 -3214 31361 35477 -12340 -11562 -2338 -35343 8967 18085 -16009 31716 -60 32319 -6671 21401 -25401 33399 -24755 43322 18696 -25289 16203 -12663 36290 -8823 12513 -23486 22335 27969 6161 1335 -24544 17632 15721 27604 17810 33845 -71209 21870 -20155 -6640 36374 29127 37404 -40857 13959 7192 35478 17465 13686 34661 17954 3648 -26095 29921 -14085 13978 -14911 -8803 30661 8008 -15447 -3158 -11733 24968 -11474 -28145 29688 -15804 16231 5923 30811 33748 SO 20190304T144214.0Z 7002.612662 6 1 32.00 2 89.81 131.61 98.54 152.69 0.00 1 0.00 1 0 22 3.550e-01 2.415e-01 3.110e-01 2.524e-01 -8.629993e+03 1.229104e+04 6.353397e+02 -6.000000e+00 1.681244e+04 247.86 -2.00 20.00 -2.00 505.14 0.00e+00 -9.739098e-04 6.510049e-03 1.407990e-04 -6.000000e+00 9.164203e-03 247.86 -2.00 20.00 -2.00 499.78 0.00e+00 3.691143e+00 5.210749e+00 9.921769e-02 -6.000000e+00 7.182120e+00 219.36 -2.00 5.57 -2.00 501.50 0.00e+00 20.933 0.304 489.00 513.00 1 1.0717e+01 3.9640e-01 4.9396e-02 -6.0000e+00 5.4204e-01 9.6202e-02 1.0652e-01 3.4596e-03 -6.0000e+00 1.4707e-01 1.9893e-06 2.4801e-02 2.3609e-02 1.0972e-04 -6.0000e+00 3.4326e-02 2.8937e-01 -3.6251e-03 12 8 8 10 0 0 95.34 20.25 7.75 0.28937 0.46140 8 2 1 7 0 4000.000 23.64 14.99 20.25 900000 900000 55757 -22118 10850 9494 9789 -12760 -6310 25024 -6561 14477 488 4207 -13187 25079 4251 47743 469 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