File name: Pandora144s1_Eureka-PEARL_20190321_L2Fit_fwvt1c4d20190120p1-8.txt File generation date: 20241125T210951.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190321_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190321 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1789 Nominal wavelengths inside fitting window [nm]: 492.0500 492.1708 492.2917 492.4125 492.5333 492.6541 492.7748 492.8956 493.0163 493.1371 493.2578 493.3784 493.4991 493.6198 493.7404 493.8610 493.9816 494.1022 494.2228 494.3433 494.4639 494.5844 494.7049 494.8254 494.9458 495.0663 495.1867 495.3072 495.4276 495.5479 495.6683 495.7887 495.9090 496.0293 496.1496 496.2699 496.3902 496.5104 496.6306 496.7508 496.8710 496.9912 497.1114 497.2315 497.3517 497.4718 497.5919 497.7120 497.8320 497.9521 498.0721 498.1921 498.3121 498.4321 498.5520 498.6720 498.7919 498.9118 499.0317 499.1516 499.2714 499.3913 499.5111 499.6309 499.7507 499.8705 499.9902 500.1100 500.2297 500.3494 500.4691 500.5887 500.7084 500.8280 500.9476 501.0672 501.1868 501.3064 501.4259 501.5455 501.6650 501.7845 501.9040 502.0234 502.1429 502.2623 502.3817 502.5011 502.6205 502.7398 502.8592 502.9785 503.0978 503.2171 503.3364 503.4556 503.5749 503.6941 503.8133 503.9325 504.0516 504.1708 504.2899 504.4090 504.5281 504.6472 504.7663 504.8853 505.0044 505.1234 505.2424 505.3614 505.4803 505.5993 505.7182 505.8371 505.9560 506.0748 506.1937 506.3125 506.4314 506.5502 506.6689 506.7877 506.9065 507.0252 507.1439 507.2626 507.3813 507.5000 507.6186 507.7372 507.8558 507.9744 508.0930 508.2116 508.3301 508.4486 508.5671 508.6856 508.8041 508.9225 509.0410 509.1594 509.2778 509.3962 509.5145 509.6329 509.7512 509.8695 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190321T114906.0Z 7019.492431 410 1 32.00 2 89.94 89.01 87.77 262.11 0.00 1 0.00 1 0 29 8.885e-02 8.307e-02 9.649e-02 9.330e-02 1.114803e+04 6.022196e+03 9.588711e+02 -6.000000e+00 4.227478e+03 248.64 -2.00 20.00 -2.00 505.13 0.00e+00 -2.595994e-03 2.338330e-03 1.219320e-04 -6.000000e+00 2.280671e-03 248.64 -2.00 20.00 -2.00 499.65 0.00e+00 -1.667046e+00 1.953334e+00 4.713266e-02 -6.000000e+00 1.768444e+00 222.68 -2.00 5.57 -2.00 501.33 0.00e+00 21.035 0.308 489.00 513.00 1 1.0084e+01 1.4766e-01 4.9452e-02 -6.0000e+00 1.3412e-01 2.3545e-01 3.9035e-02 3.0951e-03 -6.0000e+00 3.5132e-02 5.8915e-06 -8.1373e-03 7.9273e-03 1.2925e-04 -6.0000e+00 8.5607e-03 2.3853e-02 -4.0175e-04 12 8 8 10 0 0 -66.48 19.31 6.18 0.02385 -0.03259 8 2 1 7 0 4000.000 22.90 14.99 19.31 7714 13012 551 -798 -4831 7403 -6105 -6642 -2051 7650 -4200 -1052 -1898 13003 -7827 11900 -8243 2978 -6269 9145 -15303 9194 -2084 15417 64 -977 1002 -6500 -11788 -4243 10215 -518 -1293 8630 -3504 -7057 -3868 -1467 3004 5280 -4836 8477 3047 14313 7810 3353 3252 4860 7847 -11128 -1546 7948 -3509 -4006 18055 -9853 -58 -8898 -3405 7890 -9304 6062 2561 934 5876 -3926 5414 5811 -974 11761 -11079 5403 -12483 1427 23932 -1738 6996 10986 -14311 7798 -4738 1084 10846 -9575 2090 4253 -757 35253 -5215 23205 -2998 15000 -10662 -3382 4862 11538 -604 -822 925 7753 -2621 -4795 -5270 6701 9787 -4720 5445 -905 -4304 -3652 2295 13171 -2228 5977 -3555 10562 -2900 11793 -7816 7498 -2739 -19896 -18328 -10169 5416 -11853 6533 -7517 5259 -4515 5719 -4633 16460 21059 -5464 -1709 505 -7799 -8633 5928 -11693 221 -1864 12149 -546 6858 8138 -5511 11709 -131 11533 7596 12080 589 -893 -5810 8070 -7771 -8642 -2568 8662 -5288 -1266 -2270 13169 -8945 11969 -9475 3351 -7369 9436 -20388 9607 -2436 15103 73 -1129 1132 -7854 -14781 -4794 9673 -538 -1359 8398 -3982 -8526 -4547 -1667 3217 5448 -5464 8360 3184 13460 7906 3570 3462 5047 7789 -13081 -1606 7267 -3506 -3977 14504 -10746 -59 -10111 -3692 7626 -10633 5938 2609 970 5795 -4231 5233 5503 -973 10216 -11939 4905 -13614 1370 18599 -1760 6442 9543 -15702 6773 -4641 1006 9208 -10067 1980 4000 -756 24634 -5449 18185 -3055 12833 -11907 -3534 4636 10022 -572 -751 803 6127 -2259 -4227 -4784 5646 8437 -4902 5192 -916 -4441 -3697 2188 11355 -2256 5582 -3645 9381 -2758 10474 -7956 7002 -2605 -21950 -19439 -9794 4775 -11632 5336 -7056 4328 -4073 4637 -4123 12469 14991 -4696 -1416 415 -7130 -8104 4878 -11618 197 -1704 9701 -495 5768 6697 -5106 8922 -110 8576 SO 20190321T115324.0Z 7019.495417 414 1 32.00 2 89.75 90.07 87.96 263.13 0.00 1 0.00 1 0 50 1.031e-01 9.853e-02 9.370e-02 8.977e-02 7.471498e+03 5.691748e+03 5.451196e+02 -6.000000e+00 4.904341e+03 248.64 -2.00 20.00 -2.00 505.16 0.00e+00 -5.013115e-05 2.267250e-03 3.383102e-05 -6.000000e+00 2.645799e-03 248.64 -2.00 20.00 -2.00 499.51 0.00e+00 7.689305e-01 1.891205e+00 4.567421e-02 -6.000000e+00 2.051017e+00 222.68 -2.00 5.57 -2.00 501.22 0.00e+00 20.761 0.296 489.00 513.00 1 9.8711e+00 1.4303e-01 4.7858e-02 -6.0000e+00 1.5556e-01 2.0779e-01 3.7527e-02 2.8974e-03 -6.0000e+00 4.0728e-02 6.1032e-06 6.4969e-03 8.1779e-03 6.9829e-05 -6.0000e+00 9.9271e-03 -3.8199e-02 -3.4292e-06 12 9 8 11 8 0 99.18 19.31 3.09 -0.03820 0.00687 8 2 1 7 0 4000.000 22.90 15.00 19.31 13592 -1641 23543 4167 11507 -14008 -4664 3816 6680 -1842 9031 1756 7835 -5120 4989 4667 -3469 2533 -23352 -472 -12925 5173 -3846 341 3022 5411 -5807 -8263 10548 10681 10110 5996 21066 6361 -172 2469 -7111 -1575 -2982 17982 -8975 2314 7061 -3212 -13101 1885 -3639 -5645 -8197 6876 9362 -9037 11203 -13714 6556 -6493 11784 -6318 4316 -5685 8432 5999 -1590 11636 5803 -6791 -3542 6473 1488 13468 13255 -4339 6458 2551 4039 -10527 9799 -14424 16064 -12774 1118 -3966 21158 -9255 -3464 23895 -416 659 -6642 21390 -23288 5948 3348 -5699 -4187 13997 18629 -433 -9959 12251 5393 -8219 12181 -3096 19438 -9084 1982 1217 -2205 9151 2534 12188 -5417 6306 2754 3790 -8454 11233 -11192 17608 -4858 -1255 14839 8161 1661 -4002 -17291 -21780 -12192 9515 21869 -845 -16026 -2077 2470 16522 -7052 -4400 -1527 17872 -14337 18339 -4187 16574 -1169 917 643 -3253 1350 17367 16191 12753 -1817 20882 4643 12231 -19612 -6051 4588 7786 -2309 9996 2060 8500 -6230 5450 5131 -4195 2952 -33340 -542 -16879 5636 -4580 390 3374 5895 -7034 -10120 10420 10190 9509 5882 19611 6543 -195 2740 -8613 -1779 -3369 16305 -10628 2459 7215 -3673 -16665 2066 -4186 -6532 -9540 6699 8616 -9722 9703 -15311 6121 -7118 11003 -7139 4381 -6347 8159 5967 -1710 10944 5733 -7490 -3715 6044 1440 11391 11121 -4346 5856 2434 3826 -11468 8554 -15713 12717 -13397 1021 -3838 16034 -9581 -3422 18108 -403 629 -6786 16500 -28207 5433 3172 -5900 -4193 11365 13992 -381 -9366 9035 4233 -7508 9396 -2912 15126 -9528 1851 1128 -2089 7740 2315 10226 -5462 5675 2571 3514 -8924 9805 -12193 14178 -4799 -1172 11648 6848 1495 -3818 -17491 -22990 -12539 7854 15833 -754 -15205 -1827 2073 12186 -6247 -3870 -1324 13907 -14413 14395 -3841 13345 -1043 795 550 -2821 1094 12809 11292 SO 20190321T115740.0Z 7019.498380 418 1 32.00 2 89.57 91.12 88.16 264.14 0.00 1 0.00 1 0 106 9.143e-02 8.737e-02 8.511e-02 8.196e-02 5.533585e+03 4.965956e+03 2.080850e+02 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