File name: Pandora144s1_Eureka-PEARL_20190327_L2Fit_fwvt1c4d20190120p1-8.txt File generation date: 20241125T211055.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190327_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1789 Nominal wavelengths inside fitting window [nm]: 492.0500 492.1708 492.2917 492.4125 492.5333 492.6541 492.7748 492.8956 493.0163 493.1371 493.2578 493.3784 493.4991 493.6198 493.7404 493.8610 493.9816 494.1022 494.2228 494.3433 494.4639 494.5844 494.7049 494.8254 494.9458 495.0663 495.1867 495.3072 495.4276 495.5479 495.6683 495.7887 495.9090 496.0293 496.1496 496.2699 496.3902 496.5104 496.6306 496.7508 496.8710 496.9912 497.1114 497.2315 497.3517 497.4718 497.5919 497.7120 497.8320 497.9521 498.0721 498.1921 498.3121 498.4321 498.5520 498.6720 498.7919 498.9118 499.0317 499.1516 499.2714 499.3913 499.5111 499.6309 499.7507 499.8705 499.9902 500.1100 500.2297 500.3494 500.4691 500.5887 500.7084 500.8280 500.9476 501.0672 501.1868 501.3064 501.4259 501.5455 501.6650 501.7845 501.9040 502.0234 502.1429 502.2623 502.3817 502.5011 502.6205 502.7398 502.8592 502.9785 503.0978 503.2171 503.3364 503.4556 503.5749 503.6941 503.8133 503.9325 504.0516 504.1708 504.2899 504.4090 504.5281 504.6472 504.7663 504.8853 505.0044 505.1234 505.2424 505.3614 505.4803 505.5993 505.7182 505.8371 505.9560 506.0748 506.1937 506.3125 506.4314 506.5502 506.6689 506.7877 506.9065 507.0252 507.1439 507.2626 507.3813 507.5000 507.6186 507.7372 507.8558 507.9744 508.0930 508.2116 508.3301 508.4486 508.5671 508.6856 508.8041 508.9225 509.0410 509.1594 509.2778 509.3962 509.5145 509.6329 509.7512 509.8695 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190327T105305.0Z 7025.453530 512 1 32.00 2 89.94 75.26 102.29 173.54 0.00 1 0.00 1 0 15 2.022e-02 1.979e-02 1.990e-02 1.946e-02 1.286200e+03 1.068200e+03 1.006779e+02 -6.000000e+00 9.653089e+02 249.34 -2.00 20.00 -2.00 505.17 0.00e+00 5.023082e-04 4.880887e-04 4.334350e-05 -6.000000e+00 5.199310e-04 249.34 -2.00 20.00 -2.00 499.62 0.00e+00 3.096782e+00 4.056755e-01 2.427621e-02 -6.000000e+00 4.031098e-01 223.92 -2.00 5.57 -2.00 501.29 0.00e+00 20.993 0.306 489.00 513.00 1 8.0792e+00 3.0892e-02 4.9027e-02 -6.0000e+00 3.0573e-02 1.5618e-01 8.0181e-03 2.7443e-03 -6.0000e+00 8.0119e-03 3.0369e-05 1.5391e-03 1.8076e-03 2.3793e-05 -6.0000e+00 1.9484e-03 1.0533e-02 -3.4831e-04 12 8 8 10 0 0 41.37 19.80 1.09 0.01053 0.02121 8 2 1 7 0 4000.000 23.32 15.00 19.80 -668 -1823 1049 1079 -704 2172 -3847 2673 -1394 2650 484 2230 -2275 -777 -581 -2509 396 -2395 -479 -413 -1041 916 -630 -265 999 1804 -1345 1451 -1796 -377 317 2411 -2194 1740 -2031 -631 -58 1483 1787 1271 4901 -751 3527 -757 2110 1667 2006 -1948 -374 1906 -2484 -4146 825 -1002 -1735 -1326 518 1597 -2716 2105 756 646 -2039 -378 -164 314 1193 -970 1009 -2287 223 -1762 2458 200 714 592 -4306 4971 488 -1466 -2493 1023 1371 1270 3544 -2024 547 -1235 1711 -1895 -2096 19 1369 2192 498 -1310 2115 -1361 -1384 4753 -1006 -1627 -633 644 -2250 1220 -3898 1 -129 2234 748 -286 -3964 444 1930 -1147 4527 -703 4361 955 949 631 1604 80 -2781 1204 -3176 1151 -4249 353 2398 62 -1712 1999 -889 3221 -2720 -887 5265 -1498 -1252 553 1931 -895 1239 1107 -2575 -650 -3599 2669 -1678 -668 -1855 1066 1136 -778 2383 -4570 3012 -1638 2962 544 2430 -2552 -845 -625 -2757 428 -2716 -547 -479 -1222 1054 -736 -309 1154 2072 -1588 1650 -2063 -413 336 2494 -2407 1891 -2368 -737 -67 1666 1974 1394 5162 -840 3807 -861 2355 1876 2239 -2234 -415 2015 -2660 -4378 813 -1004 -1784 -1398 550 1701 -3023 2223 807 691 -2246 -409 -175 330 1221 -997 1002 -2311 217 -1742 2343 197 707 586 -4409 4542 459 -1393 -2391 953 1281 1194 3286 -2001 528 -1213 1629 -1870 -1933 17 1248 1998 460 -1211 1852 -1203 -1190 3748 -829 -1356 -534 556 -2063 1092 -3642 0 -112 1895 651 -255 -3731 404 1745 -1075 4026 -660 3879 867 848 557 1387 70 -2530 1056 -2911 1010 -3924 311 2065 54 -1490 1653 -751 2624 -2397 -785 4460 -1376 -1156 504 1744 -836 1138 1014 -2417 -584 -3250 2232 -1470 SO 20190327T105714.0Z 7025.456412 516 1 32.01 2 89.77 76.28 102.28 174.49 0.00 1 0.00 1 0 22 2.339e-02 2.318e-02 1.843e-02 1.801e-02 1.400223e+02 9.453396e+02 3.102999e+01 -6.000000e+00 1.116439e+03 249.34 -2.00 20.00 -2.00 505.19 0.00e+00 9.287756e-04 4.541317e-04 4.423231e-05 -6.000000e+00 6.012821e-04 249.34 -2.00 20.00 -2.00 499.60 0.00e+00 3.659591e+00 3.754672e-01 2.254846e-02 -6.000000e+00 4.660934e-01 223.92 -2.00 5.57 -2.00 501.28 0.00e+00 20.740 0.295 489.00 513.00 1 7.9885e+00 2.8663e-02 4.7642e-02 -6.0000e+00 3.5351e-02 1.4630e-01 7.4005e-03 2.6602e-03 -6.0000e+00 9.2607e-03 3.2854e-05 3.2138e-03 1.6770e-03 1.8434e-05 -6.0000e+00 2.2530e-03 -9.3328e-03 -2.0620e-04 12 9 8 11 8 0 -157.31 19.81 0.19 -0.00933 0.01296 8 2 1 7 0 4000.000 23.32 15.00 19.81 -6367 -1737 -3264 327 -1132 197 -54 3066 -356 -1182 3177 -831 -1110 -890 -938 -4312 -115 -759 2495 -699 2306 -118 -1986 -895 2567 5372 1117 623 -1032 654 -1355 2134 -3185 1406 -619 -958 330 -51 1333 -2194 3228 -102 161 1321 56 2976 2204 3111 871 2364 -5853 3561 -4007 1382 -3508 2586 78 2812 -3752 -312 1624 -954 4405 -122 1067 -219 2675 -2235 233 -1616 -1964 -558 2174 3091 -209 1538 -1378 1725 -3644 2613 87 384 -893 -2245 1841 -1495 -588 796 -1799 -5772 2403 -796 1719 -342 1383 -2565 3126 1672 42 4369 -1834 -2544 -2603 881 -754 1503 1668 630 2143 -1188 3875 2494 1701 -3869 5525 -3850 2621 384 2189 -1962 149 -1251 -1796 2923 -2550 4921 -131 1506 -556 1579 -350 -1663 -3285 -2683 -1 478 2965 -1185 799 -2982 2745 -4356 1820 1040 35 764 -4350 1137 -1749 -662 -2351 -6742 -1774 -3483 349 -1261 221 -62 3450 -415 -1373 3480 -935 -1232 -970 -1015 -4835 -125 -850 2774 -815 2620 -138 -2357 -1052 2927 5965 1289 715 -1175 708 -1462 2220 -3546 1542 -715 -1125 380 -58 1480 -2496 3466 -113 181 1479 64 3316 2462 3400 955 2491 -6484 3486 -4156 1359 -3696 2640 84 2970 -4233 -338 1721 -1040 4562 -132 1131 -231 2698 -2328 233 -1622 -1952 -546 2080 2962 -209 1505 -1365 1623 -3562 2380 81 360 -852 -2182 1732 -1466 -572 763 -1639 -5479 2111 -730 1558 -319 1262 -2403 2715 1438 35 3470 -1530 -2152 -2255 762 -681 1334 1461 548 1810 -1036 3253 2160 1510 -3677 4820 -3708 2376 356 1981 -1826 133 -1121 -1605 2499 -2318 4163 -116 1317 -496 1378 -310 -1474 -2907 -2327 -1 402 2478 -1056 710 -2785 2440 -4173 1647 954 33 704 -4151 1002 -1548 -572 -2077 SO 20190327T110117.0Z 7025.459225 520 1 32.00 2 89.60 77.28 102.26 175.42 0.00 1 0.00 1 0 15 2.126e-02 2.092e-02 1.734e-02 1.694e-02 1.503827e+03 9.445075e+02 1.092464e+02 -6.000000e+00 1.015196e+03 249.34 -2.00 20.00 -2.00 505.21 0.00e+00 5.653830e-04 4.258488e-04 2.734771e-05 -6.000000e+00 5.465586e-04 249.34 -2.00 20.00 -2.00 499.63 0.00e+00 3.030070e+00 3.559841e-01 1.936896e-02 -6.000000e+00 4.232503e-01 223.92 -2.00 5.57 -2.00 501.30 0.00e+00 20.444 0.283 489.00 513.00 1 8.0129e+00 2.7110e-02 4.6064e-02 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