File name: Pandora144s1_Eureka-PEARL_20190410_L2Fit_fout2c4d20190120p1-8.txt File generation date: 20241125T211855.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190410_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190410 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 217 359 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2448 305.3856 305.5264 305.6672 305.8079 305.9487 306.0895 306.2302 306.3709 306.5116 306.6524 306.7931 306.9337 307.0744 307.2151 307.3557 307.4964 307.6370 307.7776 307.9182 308.0588 308.1994 308.3399 308.4805 308.6211 308.7616 308.9021 309.0426 309.1831 309.3236 309.4641 309.6046 309.7450 309.8855 310.0259 310.1663 310.3067 310.4471 310.5875 310.7279 310.8683 311.0086 311.1490 311.2893 311.4296 311.5699 311.7102 311.8505 311.9908 312.1311 312.2713 312.4116 312.5518 312.6920 312.8322 312.9724 313.1126 313.2528 313.3929 313.5331 313.6732 313.8134 313.9535 314.0936 314.2337 314.3737 314.5138 314.6539 314.7939 314.9340 315.0740 315.2140 315.3540 315.4940 315.6340 315.7739 315.9139 316.0538 316.1938 316.3337 316.4736 316.6135 316.7534 316.8933 317.0331 317.1730 317.3128 317.4527 317.5925 317.7323 317.8721 318.0119 318.1516 318.2914 318.4312 318.5709 318.7106 318.8503 318.9900 319.1297 319.2694 319.4091 319.5487 319.6884 319.8280 319.9676 320.1073 320.2469 320.3864 320.5260 320.6656 320.8051 320.9447 321.0842 321.2237 321.3632 321.5027 321.6422 321.7817 321.9212 322.0606 322.2000 322.3395 322.4789 322.6183 322.7577 322.8971 323.0364 323.1758 323.3151 323.4545 323.5938 323.7331 323.8724 324.0117 324.1510 324.2902 324.4295 324.5687 324.7080 324.8472 324.9864 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20190410T174635.6Z 7039.740690 1643 1 33.20 2 72.02 179.89 66.01 110.86 0.00 1 0.00 1 0 25 2.065e-01 7.551e-03 2.089e-01 7.691e-03 6.038838e-01 4.254455e-03 1.108339e-02 -6.000000e+00 1.255540e-01 226.90 -2.00 5.57 -2.00 320.47 0.00e+00 2.184796e-03 1.243125e-03 1.238218e-03 -6.000000e+00 5.087203e-03 251.02 -2.00 20.00 -2.00 320.27 0.00e+00 3.198 0.001 302.00 328.00 3 4.3237e+00 1.1897e-02 5.9443e-02 -6.0000e+00 3.1403e-01 1.6759e-01 1.4598e-02 5.0626e-02 -6.0000e+00 3.4149e-01 -7.7070e-02 1.5463e-02 2.7431e-02 -6.0000e+00 2.0000e-01 2.4782e-02 8.2692e-03 8.9174e-03 -6.0000e+00 8.3793e-02 1.5489e-04 -1.6964e-03 2.4518e-04 1.2016e-04 -6.0000e+00 6.6056e-03 1.2751e-02 -4.0448e-04 11 8 0 10 0 0 99.99 19.00 0.34 0.01275 0.00000 51 10 1 8 0 650.796 22.71 15.00 19.00 -95199 900000 -81711 900000 -100320 -62550 -111209 -54859 24039 -49776 28953 -60525 -6989 -16056 19774 -35115 -9704 -22382 -7226 4052 -20201 1219 -8318 -846 -11153 -9718 10131 -4460 11486 -5113 -5571 -2406 1438 -2589 6482 595 -1612 -2729 5846 -5862 3703 -5465 3249 -4904 -6433 5889 2928 2207 5824 5258 852 1044 -181 1166 1883 2211 710 1759 1313 1829 4541 2393 1194 -680 1324 -218 1510 1917 -1460 1601 412 -722 -2384 -417 -1799 668 1393 475 -592 594 -1667 -1863 -605 -1576 -158 -1742 -473 -521 -426 606 511 -43 3110 1121 1771 1063 -328 539 -424 -281 -406 838 469 -131 -1175 -342 142 -215 -601 -513 -397 86 -335 -212 867 572 478 173 -297 -203 -164 380 -491 472 -389 1073 1238 958 -430 24 -117 248 -81 202 -26 -583 683 -425 -96 -160 -47 16 900000 -1285 900000 -1103 900000 -1504 -656 -2084 -658 180 -672 217 -1180 -100 -313 326 -1158 -276 -789 -233 121 -788 39 -312 -32 -493 -437 372 -187 422 -245 -313 -151 96 -184 418 42 -133 -272 640 -831 525 -901 509 -849 -1148 945 494 387 1035 1013 189 254 -49 329 552 666 219 530 390 543 1385 823 420 -262 560 -92 568 832 -662 784 218 -394 -1282 -205 -898 297 591 212 -301 347 -1034 -1288 -445 -1243 -130 -1540 -429 -477 -382 510 402 -32 2198 851 1493 1031 -366 658 -545 -351 -471 875 468 -135 -1290 -392 171 -279 -856 -801 -663 147 -563 -339 1298 835 707 268 -482 -336 -266 592 -740 677 -539 1407 1611 1327 -667 41 -214 475 -163 429 -59 -1364 1608 -1015 -224 -357 -98 32 900000 SU 20190410T174800.3Z 7039.741670 1645 1 12.57 2 72.02 180.26 65.95 111.21 0.00 1 0.00 1 0 25 1.817e-01 7.117e-03 1.431e-01 4.497e-03 6.050016e-01 2.417623e-03 1.117961e-02 -6.000000e+00 1.104133e-01 226.90 -2.00 5.57 -2.00 320.01 0.00e+00 2.343137e-03 6.539451e-04 1.096284e-03 -6.000000e+00 4.325334e-03 251.02 -2.00 20.00 -2.00 319.84 0.00e+00 3.198 0.001 302.00 328.00 3 3.5259e+00 6.6528e-03 5.9302e-02 -6.0000e+00 2.7627e-01 1.6770e-01 7.9794e-03 5.0322e-02 -6.0000e+00 3.0030e-01 -1.1050e-01 8.0042e-03 2.6598e-02 -6.0000e+00 1.7583e-01 4.1484e-02 4.3204e-03 8.4601e-03 -6.0000e+00 7.2984e-02 3.4752e-04 -1.1981e-03 1.3575e-04 1.0796e-04 -6.0000e+00 5.7489e-03 1.1436e-02 -3.5655e-04 12 9 1 12 1 1 99.96 19.00 0.26 0.01144 0.00243 12 7 1 8 0 954.120 22.71 15.00 19.00 -33300 -67573 -67930 -89413 -4555 -80100 75502 -84616 -20901 39494 -4717 -20410 -26503 37150 -21429 13176 -17874 11770 -10608 -6769 -963 -9511 537 -14750 172 -14009 -3230 -15179 1230 10475 2521 -8219 -1714 -2738 5172 1649 -6773 7135 -3972 848 -2252 1655 -869 1348 -750 2123 1106 2300 359 3395 5835 1677 1493 1642 720 785 333 -2777 -167 1393 597 1076 650 340 -705 1385 183 1609 605 -63 280 215 -635 907 490 -465 -102 -521 225 -1354 -452 -1907 -1367 -1391 -192 -592 520 253 260 697 152 576 612 938 681 1547 800 -291 -910 -437 -66 364 543 -664 -1517 -1161 -130 -68 31 -262 -728 -108 -6 -121 673 1022 959 105 -524 -1063 -240 -60 315 313 673 694 1284 542 580 -120 -183 -271 401 75 -261 40 220 -180 -161 -200 -224 -145 900000 -336 -1067 -1102 -1725 -36 -1370 331 -1855 -266 294 -60 -358 -616 570 -714 358 -737 392 -470 -300 -41 -450 24 -834 9 -860 -177 -925 65 560 170 -649 -139 -230 438 150 -691 756 -562 132 -396 297 -166 256 -147 412 221 469 78 775 1433 472 456 535 248 278 120 -1014 -58 481 219 435 293 165 -352 664 89 811 314 -37 173 136 -391 514 277 -242 -51 -272 132 -856 -324 -1543 -1185 -1281 -186 -559 504 248 250 686 141 499 520 838 682 1621 960 -389 -1187 -595 -83 415 590 -747 -1819 -1461 -172 -89 45 -414 -1237 -174 -10 -195 1026 1510 1436 165 -868 -1802 -397 -95 480 457 939 1004 1834 770 911 -209 -319 -498 770 153 -560 82 465 -383 -337 -426 -449 -278 900000 SU 20190410T174942.8Z 7039.742856 1647 1 33.60 2 72.02 180.70 65.88 111.62 0.00 1 0.00 1 0 25 2.027e-01 8.066e-03 2.260e-01 7.695e-03 5.987884e-01 4.221510e-03 1.089582e-02 -6.000000e+00 1.232398e-01 226.90 -2.00 5.57 -2.00 320.45 0.00e+00 1.552205e-03 1.229891e-03 8.432084e-04 -6.000000e+00 4.827174e-03 251.02 -2.00 20.00 -2.00 320.25 0.00e+00 3.198 0.001 302.00 328.00 3 4.2969e+00 1.1810e-02 5.8808e-02 -6.0000e+00 3.0836e-01 1.5725e-01 1.4479e-02 4.9817e-02 -6.0000e+00 3.3516e-01 -9.5427e-02 1.5251e-02 2.7155e-02 -6.0000e+00 1.9624e-01 4.0385e-02 8.1698e-03 8.9295e-03 -6.0000e+00 8.1472e-02 1.6206e-04 -8.6333e-04 2.4424e-04 1.1736e-04 -6.0000e+00 6.4147e-03 1.1455e-02 -2.8410e-04 11 8 0 10 0 0 99.98 19.00 0.17 0.01145 0.00497 57 11 1 8 0 589.425 22.71 15.00 19.00 9548 -25273 -13420 51759 -80729 -89187 -50997 -45618 -72282 -112649 -79202 -56014 -30736 -19962 -20135 16199 -1269 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