File name: Pandora144s1_Eureka-PEARL_20190412_L2Fit_fwvt1c4d20190120p1-8.txt File generation date: 20241125T212410.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190412_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1789 Nominal wavelengths inside fitting window [nm]: 492.0500 492.1708 492.2917 492.4125 492.5333 492.6541 492.7748 492.8956 493.0163 493.1371 493.2578 493.3784 493.4991 493.6198 493.7404 493.8610 493.9816 494.1022 494.2228 494.3433 494.4639 494.5844 494.7049 494.8254 494.9458 495.0663 495.1867 495.3072 495.4276 495.5479 495.6683 495.7887 495.9090 496.0293 496.1496 496.2699 496.3902 496.5104 496.6306 496.7508 496.8710 496.9912 497.1114 497.2315 497.3517 497.4718 497.5919 497.7120 497.8320 497.9521 498.0721 498.1921 498.3121 498.4321 498.5520 498.6720 498.7919 498.9118 499.0317 499.1516 499.2714 499.3913 499.5111 499.6309 499.7507 499.8705 499.9902 500.1100 500.2297 500.3494 500.4691 500.5887 500.7084 500.8280 500.9476 501.0672 501.1868 501.3064 501.4259 501.5455 501.6650 501.7845 501.9040 502.0234 502.1429 502.2623 502.3817 502.5011 502.6205 502.7398 502.8592 502.9785 503.0978 503.2171 503.3364 503.4556 503.5749 503.6941 503.8133 503.9325 504.0516 504.1708 504.2899 504.4090 504.5281 504.6472 504.7663 504.8853 505.0044 505.1234 505.2424 505.3614 505.4803 505.5993 505.7182 505.8371 505.9560 506.0748 506.1937 506.3125 506.4314 506.5502 506.6689 506.7877 506.9065 507.0252 507.1439 507.2626 507.3813 507.5000 507.6186 507.7372 507.8558 507.9744 508.0930 508.2116 508.3301 508.4486 508.5671 508.6856 508.8041 508.9225 509.0410 509.1594 509.2778 509.3962 509.5145 509.6329 509.7512 509.8695 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190412T063255.0Z 7041.272859 2 1 32.00 2 91.15 11.45 71.89 288.97 0.00 1 0.00 1 0 22 1.285e-01 1.225e-01 1.031e-01 9.851e-02 -8.385662e+03 5.119212e+03 7.345878e+02 -6.000000e+00 6.189243e+03 251.20 -2.00 20.00 -2.00 505.19 0.00e+00 5.102801e-03 2.484215e-03 2.726167e-04 -6.000000e+00 3.320075e-03 251.20 -2.00 20.00 -2.00 499.79 0.00e+00 5.363527e+00 2.081511e+00 9.058783e-02 -6.000000e+00 2.580566e+00 227.22 -2.00 5.57 -2.00 501.44 0.00e+00 20.929 0.303 489.00 513.00 1 9.5425e+00 1.5785e-01 4.9694e-02 -6.0000e+00 1.9556e-01 1.1249e-01 4.1082e-02 3.4035e-03 -6.0000e+00 5.1633e-02 5.5914e-06 3.7642e-03 8.8833e-03 1.6519e-04 -6.0000e+00 1.2428e-02 -6.4894e-02 -1.9814e-05 12 8 8 10 0 0 -705.38 19.93 8.53 -0.06489 -0.03878 8 2 1 7 0 4000.000 23.43 15.00 19.93 900000 -5471 -10871 9032 11470 -10334 2938 832 13979 -9981 733 -12161 17140 6269 3794 5900 -9545 -544 9541 21197 -19423 6729 10324 3660 -5284 1523 4071 -3821 10254 -12232 12525 -4245 10638 -1567 13831 -9521 3318 17212 -2423 6063 -2307 28634 -13928 21880 -6051 3407 -3151 224 1829 -1796 -7391 -967 11468 -18799 12937 -19945 2778 -11706 13292 827 11848 8332 14623 5726 -5046 10841 3105 7920 -7242 4632 -19393 15472 -12082 13239 -1456 -5758 18603 -9251 21440 -5965 27421 -31801 5559 -7334 23654 17483 3172 12901 -6875 28039 -8850 13049 -8529 2697 -13620 17217 -2482 -49 3328 10895 14018 -16832 8217 -14529 -3214 -4860 15330 -8098 314 -14610 16746 1392 3540 16886 -9492 14080 9517 30337 -7140 7843 -12966 16646 2503 -16901 8115 -21027 6291 4823 32089 8253 28381 16370 7052 -25847 12011 10913 2480 13841 -215 6148 -12414 7391 2995 10601 -800 4240 -12962 -9064 17927 -20898 20236 900000 -5768 -12431 8785 11242 -12890 3272 957 14116 -12673 821 -15260 15781 6331 3887 5914 -11269 -598 9705 19516 -26967 7194 10655 4049 -6434 1741 4534 -4567 10431 -15077 11717 -4665 10189 -1746 13658 -12089 3695 16486 -2788 6347 -2621 24024 -18097 20145 -7459 3845 -3790 258 2037 -2027 -8561 -1019 10473 -23170 11815 -26063 2970 -14688 13028 915 11700 8537 14115 6037 -5462 10625 3228 7704 -7489 4505 -21928 13211 -12662 11697 -1395 -5757 15470 -9248 16715 -5635 19953 -39028 4714 -7079 18090 13259 2778 10229 -6636 20611 -8786 10526 -8703 2511 -15119 14126 -2482 -47 3029 8939 10921 -17755 6798 -15326 -3058 -4658 11732 -7649 268 -14505 12354 1228 3149 13505 -10078 11940 8464 21753 -7335 6813 -13677 12968 2243 -18528 6993 -24356 5552 4323 21903 7169 20154 12979 6029 -30117 9440 8653 2171 11069 -201 5468 -13352 6522 2767 9137 -778 3917 -14031 -9186 13472 -22765 14649 SO 20190412T063726.0Z 7041.275995 6 1 32.01 2 91.11 12.56 72.07 290.02 0.00 1 0.00 1 0 22 1.018e-01 9.777e-02 1.011e-01 9.727e-02 -8.871662e+03 4.889835e+03 6.975831e+02 -6.000000e+00 4.903802e+03 251.20 -2.00 20.00 -2.00 505.09 0.00e+00 -1.406576e-04 2.477234e-03 6.232566e-05 -6.000000e+00 2.627864e-03 251.20 -2.00 20.00 -2.00 499.63 0.00e+00 6.993140e+00 2.026994e+00 8.999230e-02 -6.000000e+00 2.033954e+00 227.22 -2.00 5.57 -2.00 501.31 0.00e+00 20.995 0.306 489.00 513.00 1 9.4742e+00 1.5422e-01 4.9633e-02 -6.0000e+00 1.5432e-01 9.5468e-02 4.0468e-02 3.4556e-03 -6.0000e+00 4.0389e-02 5.7184e-06 -6.4780e-03 8.7966e-03 1.2317e-04 -6.0000e+00 9.8134e-03 4.9726e-03 -2.1863e-04 12 8 8 10 0 0 -218.35 19.93 10.26 0.00497 -0.03996 8 2 1 7 0 4000.000 23.43 15.00 19.93 6675 15198 -1811 5817 -8702 13087 3206 -1256 4857 -6817 -8667 -8904 -6853 -9560 17756 10230 18486 -2071 -12021 4678 -6065 9671 -4097 16468 3894 11108 -14185 4547 -14032 17246 9915 5994 -3602 -526 3511 -815 7805 -6914 7777 1330 13663 -11762 983 -7025 -6699 19229 7340 10203 -15832 4840 8633 -4803 11681 9878 -13536 -17899 18549 -4105 1348 2846 246 2024 19501 -3673 32266 -9923 -11175 -3615 138 -1505 -2445 13487 1170 11232 -12013 12505 -9025 15080 370 -2917 -4648 7346 8850 -7382 10520 -14156 10909 -13533 -3257 -5669 -3714 -9068 4930 3599 2518 19890 -10303 13388 -11432 3095 -6178 -898 -2822 10555 -7996 -13139 6490 8785 5904 1871 14231 -6556 -6211 24535 7397 3332 10309 6800 -4376 12253 -8303 -814 -9506 22825 -624 5738 -12996 -4425 11958 -2218 11510 6157 14327 -1665 9309 -5103 5320 -14152 4011 -14648 3451 -2532 8568 -4089 8767 16923 -3520 -3678 -13683 13213 3310 6558 13706 -1978 6099 -10910 13530 3737 -1556 5698 -8947 -10621 -10790 -8642 -11325 17054 10576 17755 -2312 -15223 5128 -7474 10205 -4965 16257 4375 11646 -19121 5046 -18437 16085 9653 5999 -3997 -580 3848 -954 8396 -8520 8154 1467 13209 -14654 1084 -8465 -8118 18066 7746 10350 -20479 4975 8287 -5101 10259 8742 -15298 -21690 16038 -4528 1413 2926 258 2081 16861 -4000 24383 -11281 -12629 -3716 135 -1465 -2364 11019 1083 9482 -12922 10557 -9339 12012 335 -2701 -4367 6151 7350 -7237 8666 -15034 9060 -14373 -3126 -5596 -3616 -9383 4498 3381 2417 16114 -11293 11484 -12297 2802 -6014 -825 -2671 8910 -8275 -14312 5699 7356 4984 1631 11045 -6383 -6173 18374 6697 3175 9194 6250 -4143 10344 -7914 -765 -9060 16938 -551 4777 -13048 -4077 10013 -2001 9069 5086 10742 -1439 7098 -4475 4260 -14118 3416 -15265 3026 -2365 7186 -3924 7465 13334 -3377 -3459 -13824 9991 2755 SO 20190412T064156.0Z 7041.279120 10 1 32.00 2 91.06 13.68 72.25 291.06 0.00 1 0.00 1 0 22 9.008e-02 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