File name: Pandora144s1_Eureka-PEARL_20190613_L2Fit_fwvt1c4d20190120p1-8.txt File generation date: 20241125T215426.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190613_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190613 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1789 Nominal wavelengths inside fitting window [nm]: 492.0500 492.1708 492.2917 492.4125 492.5333 492.6541 492.7748 492.8956 493.0163 493.1371 493.2578 493.3784 493.4991 493.6198 493.7404 493.8610 493.9816 494.1022 494.2228 494.3433 494.4639 494.5844 494.7049 494.8254 494.9458 495.0663 495.1867 495.3072 495.4276 495.5479 495.6683 495.7887 495.9090 496.0293 496.1496 496.2699 496.3902 496.5104 496.6306 496.7508 496.8710 496.9912 497.1114 497.2315 497.3517 497.4718 497.5919 497.7120 497.8320 497.9521 498.0721 498.1921 498.3121 498.4321 498.5520 498.6720 498.7919 498.9118 499.0317 499.1516 499.2714 499.3913 499.5111 499.6309 499.7507 499.8705 499.9902 500.1100 500.2297 500.3494 500.4691 500.5887 500.7084 500.8280 500.9476 501.0672 501.1868 501.3064 501.4259 501.5455 501.6650 501.7845 501.9040 502.0234 502.1429 502.2623 502.3817 502.5011 502.6205 502.7398 502.8592 502.9785 503.0978 503.2171 503.3364 503.4556 503.5749 503.6941 503.8133 503.9325 504.0516 504.1708 504.2899 504.4090 504.5281 504.6472 504.7663 504.8853 505.0044 505.1234 505.2424 505.3614 505.4803 505.5993 505.7182 505.8371 505.9560 506.0748 506.1937 506.3125 506.4314 506.5502 506.6689 506.7877 506.9065 507.0252 507.1439 507.2626 507.3813 507.5000 507.6186 507.7372 507.8558 507.9744 508.0930 508.2116 508.3301 508.4486 508.5671 508.6856 508.8041 508.9225 509.0410 509.1594 509.2778 509.3962 509.5145 509.6329 509.7512 509.8695 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190613T054723.0Z 7103.241238 2 1 32.00 2 76.76 0.41 91.72 230.52 0.00 1 0.00 1 0 15 1.400e-02 1.402e-02 1.010e-02 1.003e-02 3.319986e+03 5.865710e+02 2.802179e+02 -6.000000e+00 7.185442e+02 266.10 -2.00 20.00 -2.00 505.25 0.00e+00 4.576184e-04 2.624617e-04 2.924041e-05 -6.000000e+00 3.740124e-04 266.10 -2.00 20.00 -2.00 500.17 0.00e+00 6.341489e-01 2.033697e-01 2.140238e-02 -6.000000e+00 2.802585e-01 236.13 -2.00 5.57 -2.00 501.83 0.00e+00 4.256 0.002 489.00 513.00 1 9.7152e+00 1.5470e-02 5.9710e-03 -6.0000e+00 2.1345e-02 1.6065e-02 4.0416e-03 6.6124e-04 -6.0000e+00 5.5719e-03 6.3761e-05 1.2042e-03 9.3863e-04 4.4154e-05 -6.0000e+00 1.3510e-03 1.3153e-02 -2.4621e-04 12 8 8 10 0 0 95.06 19.67 1.78 0.01315 0.02151 8 2 1 7 0 4000.000 23.22 15.00 19.67 842 684 -816 1220 568 1832 -790 650 -587 2109 -1301 2509 -1348 1307 -1041 -1513 1429 -783 2340 -810 498 -1269 316 -1145 735 -1148 763 447 -53 2181 -1739 1686 -1325 1123 -3823 924 -508 998 -1242 466 -1293 -3091 2218 -1651 1414 -1386 2607 -1721 46 -222 2563 664 278 -334 133 861 -1473 2244 -266 -1049 -1400 299 -1499 1325 543 379 -833 500 -800 -474 1987 -2386 2571 295 -728 -569 -687 -238 -1750 -1698 -2884 1517 -1849 1235 -1901 733 -519 -686 -318 211 498 354 2007 -1598 2310 -327 612 -1664 643 -584 -499 -803 -988 199 -768 1402 -664 2366 -2562 255 -280 1950 481 1407 -621 408 -717 -471 2328 -1956 255 -1945 1852 -1660 323 1121 585 -12 423 750 -758 2674 -1744 312 -2477 1967 -1026 1692 172 2917 581 -633 366 -397 2815 -1116 86 -1108 -234 530 -747 806 663 -826 1255 605 1970 -889 729 -667 2308 -1451 2656 -1460 1358 -1099 -1609 1494 -856 2545 -923 563 -1462 359 -1225 835 -1235 803 466 -58 2279 -1848 1729 -1322 1129 -4169 974 -540 1033 -1297 474 -1335 -3264 2243 -1755 1473 -1490 2682 -1828 47 -223 2426 623 258 -312 126 840 -1508 2244 -273 -1083 -1449 305 -1565 1345 552 381 -833 486 -778 -454 1835 -2302 2381 284 -713 -556 -662 -224 -1651 -1591 -2738 1390 -1766 1153 -1852 702 -506 -670 -309 204 483 348 1969 -1636 2256 -322 584 -1583 582 -523 -443 -722 -915 190 -763 1379 -663 2256 -2533 245 -273 1894 481 1407 -637 417 -745 -490 2347 -2033 254 -1955 1772 -1647 316 1092 573 -12 414 730 -746 2507 -1679 291 -2359 1805 -924 1517 159 2659 547 -606 349 -383 2638 -1083 81 -1035 -212 470 -675 SO 20190613T055341.0Z 7103.245613 5 1 32.00 2 76.75 1.90 91.94 232.02 0.00 1 0.00 1 0 15 1.037e-02 1.029e-02 9.199e-03 9.141e-03 3.247308e+03 5.307707e+02 2.082930e+02 -6.000000e+00 5.324153e+02 266.10 -2.00 20.00 -2.00 505.23 0.00e+00 6.340377e-04 2.395548e-04 3.833936e-05 -6.000000e+00 2.771167e-04 266.10 -2.00 20.00 -2.00 500.22 0.00e+00 4.077932e-01 1.845527e-01 3.481083e-02 -6.000000e+00 2.076026e-01 236.13 -2.00 5.57 -2.00 501.85 0.00e+00 4.254 0.002 489.00 513.00 1 9.6271e+00 1.4027e-02 6.3638e-03 -6.0000e+00 1.5812e-02 2.0737e-02 3.6673e-03 8.0344e-04 -6.0000e+00 4.1263e-03 7.0678e-05 -4.3462e-04 8.5384e-04 3.3708e-05 -6.0000e+00 1.0010e-03 1.6359e-02 -2.4433e-04 12 8 8 10 0 0 -12.34 19.68 0.51 0.01636 0.01334 8 2 1 7 0 4000.000 23.22 15.00 19.68 -978 -948 -1199 -462 726 -304 1378 -1429 836 -1125 374 -675 -757 885 1309 -569 -133 -323 -794 -334 -695 1447 -553 580 -731 59 663 -213 -934 -1251 2740 -763 1 145 1760 86 1540 -704 136 -471 1556 508 -205 1439 -924 1813 -528 2009 322 229 -991 -4 15 -1318 429 -446 -208 -1483 1631 -955 805 68 290 56 -37 920 -700 151 -1536 145 -2203 813 1312 855 -454 831 -916 718 336 -115 681 -2090 -32 -616 1838 -1340 619 -892 -252 1405 -1045 919 12 1488 -1207 4 -442 1098 -1534 575 804 -463 -984 -659 -100 -901 1009 -1876 1654 -1460 2065 -634 -479 -441 446 1673 495 588 -271 1227 -921 1317 1363 330 -276 1011 -372 -1418 605 -1830 2256 -472 1140 -1612 1420 -1813 -680 222 1102 619 19 -788 -298 42 -1890 666 -1731 187 -1040 72 -16 -961 -940 -1226 -486 777 -336 1528 -1648 943 -1282 414 -743 -821 930 1359 -603 -143 -353 -895 -354 -742 1514 -591 613 -787 63 702 -225 -973 -1266 2601 -749 1 148 1822 92 1615 -746 141 -486 1570 520 -213 1491 -991 1900 -564 2070 332 231 -981 -4 14 -1252 410 -443 -211 -1550 1657 -993 821 70 300 59 -38 928 -706 149 -1520 139 -2141 766 1240 823 -448 809 -895 676 314 -107 629 -2002 -30 -591 1739 -1323 602 -880 -247 1355 -1039 906 12 1492 -1235 4 -432 1029 -1436 515 712 -418 -919 -637 -99 -915 1000 -1885 1583 -1440 1988 -637 -488 -454 457 1703 513 612 -283 1248 -941 1294 1324 324 -275 995 -346 -1334 556 -1721 2174 -430 1077 -1441 1311 -1624 -614 204 1017 581 18 -761 -288 41 -1868 639 -1678 173 -955 65 -14 SO 20190613T060044.0Z 7103.250509 8 1 32.00 2 76.73 3.56 92.20 233.69 0.00 1 0.00 1 0 15 6.790e-03 6.803e-03 7.165e-03 7.121e-03 1.842611e+03 4.056459e+02 1.128958e+02 -6.000000e+00 3.485051e+02 266.11 -2.00 20.00 -2.00 505.26 0.00e+00 4.676518e-04 1.855130e-04 2.658747e-05 -6.000000e+00 1.814020e-04 266.11 -2.00 20.00 -2.00 500.25 0.00e+00 5.233394e-01 1.436590e-01 2.217956e-02 -6.000000e+00 1.359577e-01 236.13 -2.00 5.57 -2.00 501.85 0.00e+00 4.250 0.002 489.00 513.00 1 9.3506e+00 1.0953e-02 5.9274e-03 -6.0000e+00 1.0354e-02 1.6848e-02 2.8413e-03 5.5555e-04 -6.0000e+00 2.7036e-03 9.2934e-05 1.6945e-04 6.7314e-04 1.6645e-05 -6.0000e+00 6.5526e-04 9.7086e-03 -2.4416e-04 12 8 8 10 0 0 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