File name: Pandora144s1_Eureka-PEARL_20190620_L2Fit_fwvt1c3d20190119p1-8.txt File generation date: 20241120T181936.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v3d20190119.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190620_L1_smca1c3d20190119p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190620 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB data based on session1 First and last pixel inside fitting window: 1640 1789 Nominal wavelengths inside fitting window [nm]: 492.0838 492.2045 492.3253 492.4461 492.5668 492.6875 492.8083 492.9290 493.0496 493.1703 493.2909 493.4116 493.5322 493.6528 493.7733 493.8939 494.0144 494.1350 494.2555 494.3760 494.4965 494.6169 494.7374 494.8578 494.9782 495.0986 495.2190 495.3393 495.4597 495.5800 495.7003 495.8206 495.9409 496.0612 496.1814 496.3016 496.4219 496.5421 496.6622 496.7824 496.9025 497.0227 497.1428 497.2629 497.3830 497.5030 497.6231 497.7431 497.8631 497.9831 498.1031 498.2231 498.3430 498.4629 498.5828 498.7027 498.8226 498.9425 499.0623 499.1822 499.3020 499.4218 499.5415 499.6613 499.7811 499.9008 500.0205 500.1402 500.2599 500.3795 500.4992 500.6188 500.7384 500.8580 500.9776 501.0972 501.2167 501.3362 501.4557 501.5752 501.6947 501.8142 501.9336 502.0531 502.1725 502.2919 502.4112 502.5306 502.6499 502.7693 502.8886 503.0079 503.1271 503.2464 503.3657 503.4849 503.6041 503.7233 503.8425 503.9616 504.0808 504.1999 504.3190 504.4381 504.5572 504.6762 504.7953 504.9143 505.0333 505.1523 505.2713 505.3902 505.5092 505.6281 505.7470 505.8659 505.9847 506.1036 506.2224 506.3413 506.4601 506.5789 506.6976 506.8164 506.9351 507.0538 507.1725 507.2912 507.4099 507.5285 507.6472 507.7658 507.8844 508.0030 508.1216 508.2401 508.3586 508.4772 508.5957 508.7141 508.8326 508.9511 509.0695 509.1879 509.3063 509.4247 509.5431 509.6614 509.7797 509.8980 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190620T054849.0Z 7110.242234 2 1 32.01 2 76.52 0.39 103.73 146.18 0.00 1 0.00 1 0 8 1.714e-02 1.702e-02 1.525e-02 1.512e-02 1.312975e+03 8.513731e+02 1.373612e+02 -6.000000e+00 8.839049e+02 267.19 -2.00 20.00 -2.00 505.29 0.00e+00 1.074329e-03 3.940454e-04 5.917831e-05 -6.000000e+00 4.593153e-04 267.19 -2.00 20.00 -2.00 500.24 0.00e+00 5.995165e-01 3.081304e-01 1.281865e-02 -6.000000e+00 3.437328e-01 236.43 -2.00 5.57 -2.00 501.85 0.00e+00 4.186 0.002 489.00 513.00 1 8.2608e+00 2.3433e-02 5.7990e-03 -6.0000e+00 2.6169e-02 1.9006e-02 6.1015e-03 4.0348e-04 -6.0000e+00 6.8615e-03 2.7513e-04 1.0073e-03 1.4257e-03 2.8275e-05 -6.0000e+00 1.6558e-03 5.2192e-02 8.9387e-05 12 8 8 10 0 0 96.54 20.46 0.60 0.05219 0.05918 8 2 1 7 0 4000.000 23.83 15.00 20.46 -351 2082 210 -2402 2381 -1701 -201 -2452 1172 815 -411 -944 2138 548 1775 -582 835 1627 1182 2775 -827 2102 -1446 1282 -185 1521 -562 -1101 1628 -1360 -287 -1946 -804 -1554 3275 -1083 2414 -1519 -3346 2536 -831 -33 410 1660 -2552 1915 -1012 -943 -2906 -1706 -2025 1030 2793 -250 1189 -1891 -927 -1344 2555 -499 -514 1007 191 411 478 -277 -356 1161 -2236 115 -1738 1304 -1968 3657 228 -1127 3033 275 1720 -1998 786 1240 -487 -2595 526 -3846 -1316 407 194 -416 343 -290 -364 -1144 2396 3010 -3278 1537 -1064 -1763 -674 -734 -453 -647 845 -2342 1591 -746 378 -2898 3744 -1186 -815 1130 -1200 1606 -697 322 1863 1744 -634 1119 634 1057 -1428 1121 1680 -470 -1423 249 2843 119 458 -119 3625 -2364 1520 352 -11 615 1129 86 -3049 690 -1226 1872 -2468 4512 -4206 796 -333 1984 212 -2554 2467 -1871 -220 -2748 1253 861 -433 -984 2130 550 1765 -600 867 1719 1275 2958 -915 2257 -1611 1397 -205 1651 -617 -1186 1652 -1390 -289 -2028 -855 -1720 3502 -1203 2559 -1654 -3673 2619 -892 -35 445 1795 -2891 2067 -1112 -1018 -3124 -1758 -2036 988 2640 -249 1205 -2028 -999 -1457 2657 -534 -553 1071 205 437 501 -288 -364 1156 -2273 113 -1739 1276 -1872 3581 214 -1058 2886 247 1511 -1825 704 1114 -448 -2467 489 -3754 -1253 380 182 -395 327 -283 -359 -1131 2255 2762 -3126 1360 -945 -1560 -595 -665 -424 -625 811 -2300 1478 -701 351 -2816 3464 -1171 -811 1113 -1215 1590 -707 321 1808 1667 -611 1051 600 1001 -1391 1064 1585 -452 -1379 237 2594 110 414 -108 3177 -2245 1419 338 -10 601 1100 85 -3131 684 -1234 1799 -2416 4021 -4042 731 SO 20190620T060120.0Z 7110.250926 5 1 32.00 2 76.50 3.34 103.43 149.06 0.00 1 0.00 1 0 15 1.616e-02 1.597e-02 1.464e-02 1.452e-02 2.340792e+03 8.531281e+02 1.532536e+02 -6.000000e+00 8.332187e+02 267.19 -2.00 20.00 -2.00 505.31 0.00e+00 3.959509e-04 3.790364e-04 2.762305e-05 -6.000000e+00 4.329930e-04 267.19 -2.00 20.00 -2.00 500.24 0.00e+00 5.425710e-01 2.975820e-01 2.605524e-02 -6.000000e+00 3.242217e-01 236.43 -2.00 5.57 -2.00 501.86 0.00e+00 4.181 0.002 489.00 513.00 1 8.2312e+00 2.2601e-02 5.9500e-03 -6.0000e+00 2.4681e-02 1.6556e-02 5.8767e-03 6.4069e-04 -6.0000e+00 6.4764e-03 2.8698e-04 -2.3092e-03 1.3631e-03 2.0437e-05 -6.0000e+00 1.5613e-03 6.6938e-02 -4.4903e-05 12 8 8 10 0 0 98.09 20.47 -1.61 0.06694 0.05092 8 2 1 7 0 4000.000 23.83 15.00 20.47 -1008 -2417 -1247 -1959 2858 1300 -804 -104 2145 -2660 818 -1340 -922 577 -89 957 -1241 537 632 2712 -390 2028 -1257 1127 -1275 431 -1012 -2600 -1399 -1379 -927 1219 496 -2058 1827 -221 638 1358 1257 1525 1845 -1680 -63 2637 -1104 1871 -536 3190 -1109 -1860 -2369 100 -975 2295 1579 -612 1601 -1559 -1193 -521 381 -553 2080 281 26 -108 131 -545 2426 1796 -2360 1457 -828 2039 -2747 1865 319 128 -297 -3652 736 -283 5136 -1238 -2152 -1975 -1252 924 -1213 -1238 95 1046 -118 2289 1921 -699 -764 -464 -650 1873 829 1995 132 -1305 -1070 -3122 2173 3095 1442 -1681 756 -1483 1773 -666 338 -1761 293 1909 1401 3006 528 -1222 -2101 -1494 -588 -1906 769 601 999 1493 1761 -1768 -1491 -1003 -318 270 -3216 2927 -2379 -957 1945 959 -516 -749 860 1310 -111 1135 -1813 -1376 -958 -2389 -1263 -2060 2931 1381 -884 -114 2279 -2923 856 -1410 -951 581 -91 969 -1312 573 686 2902 -431 2188 -1403 1234 -1433 475 -1122 -2871 -1479 -1419 -943 1229 519 -2284 1987 -245 694 1446 1325 1596 1930 -1836 -69 2822 -1234 2025 -589 3320 -1178 -1934 -2404 97 -954 2213 1581 -644 1676 -1693 -1287 -557 405 -597 2188 299 27 -113 134 -554 2360 1738 -2204 1420 -776 1882 -2666 1707 291 116 -266 -3388 658 -258 4467 -1160 -2058 -1896 -1194 862 -1157 -1188 91 1005 -116 2189 1817 -666 -710 -418 -574 1591 716 1741 121 -1265 -1052 -3118 2029 2822 1331 -1616 721 -1468 1718 -666 336 -1801 295 1885 1375 2857 506 -1177 -2039 -1450 -568 -1865 732 571 945 1401 1630 -1666 -1380 -916 -290 249 -3140 2737 -2377 -951 1887 944 -519 -757 854 1279 -107 1059 -1715 -1298 SO 20190620T061423.0Z 7110.259988 8 1 32.01 2 76.45 6.42 103.15 152.06 0.00 1 0.00 1 0 15 1.860e-02 1.843e-02 1.709e-02 1.696e-02 8.999312e+02 9.418108e+02 1.539865e+02 -6.000000e+00 9.588191e+02 267.19 -2.00 20.00 -2.00 505.27 0.00e+00 1.485832e-03 4.438865e-04 9.706391e-05 -6.000000e+00 4.982003e-04 267.19 -2.00 20.00 -2.00 500.25 0.00e+00 9.250215e-01 3.461352e-01 2.043557e-02 -6.000000e+00 3.724647e-01 236.43 -2.00 5.57 -2.00 501.85 0.00e+00 4.167 0.002 489.00 513.00 1 8.3504e+00 2.6426e-02 6.1416e-03 -6.0000e+00 2.8361e-02 1.4554e-02 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