File name: Pandora144s1_Eureka-PEARL_20200224_L2Fit_fwvt1c4d20190120p1-8.txt File generation date: 20241125T221139.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20200224_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20200224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1789 Nominal wavelengths inside fitting window [nm]: 492.0500 492.1708 492.2917 492.4125 492.5333 492.6541 492.7748 492.8956 493.0163 493.1371 493.2578 493.3784 493.4991 493.6198 493.7404 493.8610 493.9816 494.1022 494.2228 494.3433 494.4639 494.5844 494.7049 494.8254 494.9458 495.0663 495.1867 495.3072 495.4276 495.5479 495.6683 495.7887 495.9090 496.0293 496.1496 496.2699 496.3902 496.5104 496.6306 496.7508 496.8710 496.9912 497.1114 497.2315 497.3517 497.4718 497.5919 497.7120 497.8320 497.9521 498.0721 498.1921 498.3121 498.4321 498.5520 498.6720 498.7919 498.9118 499.0317 499.1516 499.2714 499.3913 499.5111 499.6309 499.7507 499.8705 499.9902 500.1100 500.2297 500.3494 500.4691 500.5887 500.7084 500.8280 500.9476 501.0672 501.1868 501.3064 501.4259 501.5455 501.6650 501.7845 501.9040 502.0234 502.1429 502.2623 502.3817 502.5011 502.6205 502.7398 502.8592 502.9785 503.0978 503.2171 503.3364 503.4556 503.5749 503.6941 503.8133 503.9325 504.0516 504.1708 504.2899 504.4090 504.5281 504.6472 504.7663 504.8853 505.0044 505.1234 505.2424 505.3614 505.4803 505.5993 505.7182 505.8371 505.9560 506.0748 506.1937 506.3125 506.4314 506.5502 506.6689 506.7877 506.9065 507.0252 507.1439 507.2626 507.3813 507.5000 507.6186 507.7372 507.8558 507.9744 508.0930 508.2116 508.3301 508.4486 508.5671 508.6856 508.8041 508.9225 509.0410 509.1594 509.2778 509.3962 509.5145 509.6329 509.7512 509.8695 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20200224T172937.2Z 7359.728902 870 1 34.35 2 89.60 172.78 90.92 160.00 0.00 1 0.00 1 0 15 7.950e-03 7.709e-03 1.586e-03 1.576e-03 1.976603e+03 7.903531e+01 1.451213e+02 -6.000000e+00 3.764568e+02 247.77 -2.00 20.00 -2.00 505.43 0.00e+00 1.352925e-03 3.984999e-05 6.648609e-05 -6.000000e+00 2.037498e-04 247.77 -2.00 20.00 -2.00 501.18 0.00e+00 1.814294e+00 2.998135e-02 2.949155e-02 -6.000000e+00 1.572613e-01 217.85 -2.00 5.57 -2.00 502.67 0.00e+00 20.603 0.289 489.00 513.00 1 5.2683e+00 2.2645e-03 4.7044e-02 -6.0000e+00 1.1931e-02 -3.5277e-02 5.7866e-04 2.6163e-03 -6.0000e+00 3.1212e-03 5.7965e-04 7.3675e-04 1.4956e-04 3.8771e-05 -6.0000e+00 7.6589e-04 3.2685e-02 -4.1625e-04 12 8 8 10 0 0 45.77 20.63 8.67 0.03268 0.03779 9 2 1 7 0 3816.649 24.04 15.00 20.63 -2529 -2414 -1782 -711 179 703 756 1236 1055 704 247 -107 -840 -873 -1068 -928 -647 0 316 350 680 674 728 678 818 608 944 291 -112 -708 -1293 -1343 -973 197 238 656 1017 603 -172 -236 -31 248 439 765 750 1003 1437 529 677 -466 -962 -1544 -1606 -1448 -932 -400 97 491 659 828 819 1177 891 1255 746 837 306 534 -541 -631 -716 -1092 -787 -402 -57 -158 -122 -453 -875 -1036 -663 -849 -607 -630 -392 -227 -142 -163 35 -161 -20 542 369 613 1162 896 500 -199 -714 -1477 -1222 -772 -412 -425 -259 -182 -104 -434 -666 -504 -279 299 633 1161 1138 1321 908 1158 849 756 404 117 48 69 -129 178 363 190 323 527 93 155 -326 -839 -1015 -693 -456 -476 -116 413 575 314 527 735 458 13 53 -563 -989 -1215 -1160 -2121 -2047 -1550 -637 165 658 722 1193 1023 680 237 -102 -795 -816 -995 -868 -612 0 293 331 645 642 695 651 790 591 915 282 -106 -659 -1186 -1233 -906 188 235 656 1012 597 -170 -231 -30 244 437 770 765 1029 1466 540 680 -464 -936 -1473 -1511 -1365 -895 -395 99 503 678 850 792 1142 873 1228 731 811 294 537 -544 -627 -706 -1082 -786 -381 -54 -152 -116 -451 -864 -1021 -653 -796 -574 -601 -378 -221 -139 -159 34 -159 -20 542 377 631 1186 906 499 -196 -688 -1404 -1148 -728 -398 -427 -269 -191 -109 -450 -684 -518 -290 316 678 1187 1176 1374 956 1224 900 794 420 120 50 71 -134 186 379 199 338 552 98 161 -336 -860 -1037 -712 -478 -513 -127 456 641 353 597 837 526 15 61 -633 -1093 -1331 -1279 SO 20200224T173411.9Z 7359.732083 875 1 33.88 2 89.58 173.91 90.84 161.09 0.00 1 0.00 1 0 22 8.937e-03 8.635e-03 1.241e-03 1.232e-03 1.974687e+03 6.163598e+01 1.391096e+02 -6.000000e+00 4.231570e+02 247.77 -2.00 20.00 -2.00 505.44 0.00e+00 1.441406e-03 3.108279e-05 6.970970e-05 -6.000000e+00 2.290422e-04 247.77 -2.00 20.00 -2.00 501.27 0.00e+00 1.747513e+00 2.339254e-02 3.084148e-02 -6.000000e+00 1.768165e-01 217.85 -2.00 5.57 -2.00 502.73 0.00e+00 20.557 0.287 489.00 513.00 1 4.7777e+00 1.7672e-03 4.6810e-02 -6.0000e+00 1.3415e-02 -4.5570e-02 4.5075e-04 2.6058e-03 -6.0000e+00 3.5102e-03 9.5703e-04 1.4405e-03 1.1703e-04 3.8624e-05 -6.0000e+00 8.6089e-04 2.7693e-02 -4.0567e-04 12 8 8 10 0 0 7.91 20.62 9.88 0.02769 0.03769 16 3 1 7 0 2117.212 24.04 15.00 20.62 -3113 -2532 -1925 -690 114 667 1092 1425 1031 919 512 -186 -894 -913 -1089 -1057 -793 -231 131 594 562 699 705 692 904 841 840 219 -34 -403 -1441 -1474 -815 -101 314 949 1010 382 -29 -223 -88 -39 522 1013 1148 1412 1047 1048 477 -309 -910 -1601 -1980 -1942 -1108 -330 295 456 870 929 1152 1027 1263 1102 1169 798 278 192 -481 -708 -948 -792 -811 -366 -234 -397 -329 -725 -1042 -894 -1356 -1072 -768 -471 -600 -441 -276 -276 -103 -180 -122 502 528 843 1233 971 547 21 -1094 -1345 -1428 -1457 -567 -346 -159 82 -15 -526 -601 -488 -261 157 909 1116 1420 1402 1368 1235 886 955 348 314 138 178 78 149 289 250 238 657 -7 -39 -311 -1056 -1045 -932 -398 -183 256 364 152 513 457 661 665 83 -347 -664 -938 -1369 -1102 -2574 -2108 -1645 -606 102 612 1021 1347 982 870 480 -174 -831 -839 -997 -972 -739 -219 119 550 525 655 662 653 859 804 802 209 -32 -368 -1304 -1335 -747 -95 305 933 992 374 -28 -216 -85 -38 513 1005 1153 1426 1060 1052 475 -304 -875 -1513 -1852 -1823 -1057 -324 296 464 887 945 1171 1052 1300 1073 1204 816 282 192 -480 -700 -932 -778 -805 -368 -224 -381 -331 -721 -1027 -877 -1340 -1066 -725 -447 -578 -429 -269 -271 -101 -177 -121 501 537 864 1257 981 545 21 -1058 -1276 -1345 -1385 -549 -348 -165 86 -16 -546 -618 -502 -272 167 975 1212 1468 1462 1439 1309 942 1004 364 324 142 183 81 156 303 263 251 692 -8 -41 -323 -1091 -1075 -967 -420 -198 281 405 172 581 521 759 769 97 -401 -753 -1044 -1515 -1225 SO 20200224T173746.7Z 7359.734569 879 1 33.44 2 89.56 174.79 90.78 161.95 0.00 1 0.00 1 0 15 8.580e-03 8.300e-03 1.238e-03 1.229e-03 2.108165e+03 6.159700e+01 1.488200e+02 -6.000000e+00 4.062578e+02 247.77 -2.00 20.00 -2.00 505.44 0.00e+00 1.442285e-03 3.106603e-05 7.157824e-05 -6.000000e+00 2.198643e-04 247.77 -2.00 20.00 -2.00 501.26 0.00e+00 1.678516e+00 2.333788e-02 3.210614e-02 -6.000000e+00 1.696153e-01 217.85 -2.00 5.57 -2.00 502.73 0.00e+00 20.525 0.286 489.00 513.00 1 4.7715e+00 1.7604e-03 4.6652e-02 -6.0000e+00 1.2870e-02 -4.4730e-02 4.5068e-04 2.6044e-03 -6.0000e+00 3.3643e-03 9.7163e-04 -3.5333e-05 1.1660e-04 4.0413e-05 -6.0000e+00 8.2651e-04 2.3007e-02 -3.1026e-04 12 8 8 10 0 0 -3.84 20.62 9.60 0.02301 0.02276 16 3 1 7 0 2090.083 24.04 14.99 20.62 -2705 -2783 -1654 -760 321 845 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