File name: Pandora144s1_Eureka-PEARL_20200718_L2Fit_fout2c3d20190119p1-8.txt File generation date: 20241124T003002.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v3d20180302.txt Instrument calibration file used: Pandora144s1_CF_v3d20190119.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20200718_L1_smca1c3d20190119p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20200718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB data based on session1 First and last pixel inside fitting window: 217 359 Nominal wavelengths inside fitting window [nm]: 305.0387 305.1796 305.3206 305.4616 305.6025 305.7435 305.8844 306.0253 306.1662 306.3071 306.4479 306.5888 306.7297 306.8705 307.0113 307.1521 307.2929 307.4337 307.5745 307.7153 307.8560 307.9968 308.1375 308.2782 308.4189 308.5596 308.7003 308.8410 308.9816 309.1223 309.2629 309.4036 309.5442 309.6848 309.8254 309.9659 310.1065 310.2470 310.3876 310.5281 310.6686 310.8091 310.9496 311.0901 311.2306 311.3710 311.5115 311.6519 311.7923 311.9327 312.0731 312.2135 312.3539 312.4942 312.6346 312.7749 312.9153 313.0556 313.1959 313.3362 313.4764 313.6167 313.7569 313.8972 314.0374 314.1776 314.3178 314.4580 314.5982 314.7384 314.8785 315.0187 315.1588 315.2989 315.4390 315.5791 315.7192 315.8593 315.9993 316.1394 316.2794 316.4194 316.5594 316.6994 316.8394 316.9794 317.1194 317.2593 317.3992 317.5392 317.6791 317.8190 317.9589 318.0987 318.2386 318.3785 318.5183 318.6581 318.7979 318.9377 319.0775 319.2173 319.3571 319.4968 319.6366 319.7763 319.9160 320.0557 320.1954 320.3351 320.4748 320.6144 320.7541 320.8937 321.0333 321.1729 321.3125 321.4521 321.5917 321.7312 321.8708 322.0103 322.1498 322.2893 322.4288 322.5683 322.7078 322.8473 322.9867 323.1261 323.2656 323.4050 323.5444 323.6838 323.8231 323.9625 324.1018 324.2412 324.3805 324.5198 324.6591 324.7984 324.9377 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200718T113930.5Z 7504.485770 162 1 51.01 2 69.98 83.17 63.30 112.50 0.00 1 0.00 1 0 17 3.909e-02 6.592e-03 2.920e-02 3.818e-03 3.450784e-01 2.106921e-03 6.437819e-03 -6.000000e+00 2.464425e-02 236.33 -2.00 5.57 -2.00 318.93 0.00e+00 3.439908e-04 4.426867e-04 4.221674e-04 -6.000000e+00 1.003561e-03 270.15 -2.00 20.00 -2.00 318.42 0.00e+00 2.890 0.001 302.00 328.00 3 2.7558e+00 5.8296e-03 4.0768e-02 -6.0000e+00 6.2739e-02 5.3008e-02 6.5629e-03 2.9720e-02 -6.0000e+00 6.7479e-02 -2.0507e-02 4.6216e-03 1.4490e-02 -6.0000e+00 3.9617e-02 9.0842e-03 2.3792e-03 4.0672e-03 -6.0000e+00 1.6366e-02 1.4932e-03 1.4688e-04 1.2740e-04 5.0326e-05 -6.0000e+00 1.2406e-03 5.9015e-02 -1.5525e-04 11 8 0 10 0 0 98.69 22.13 0.23 0.05902 0.06012 19 4 1 8 0 2684.547 25.28 15.00 22.13 2078 9657 -10692 1087 -11997 -13803 15134 -14359 9060 -18029 5645 -13147 3194 -5196 345 10098 -2278 6705 -3684 7563 -2671 2465 -3488 2726 -1218 4001 -3716 2439 5137 -2499 2715 -309 1432 -2261 -531 1378 -1622 -639 -1651 -741 -922 -2643 -2237 -1598 -659 1037 -2299 1975 -816 581 1439 -1219 318 -329 1952 1123 983 -154 2682 585 1755 422 991 532 82 709 360 531 267 1602 -263 147 -431 -74 -795 801 637 657 367 -967 -1248 -1916 -1676 -1427 -42 -675 22 -142 751 129 231 803 1187 798 1140 1388 138 -144 -208 -513 -263 21 -323 -100 -1123 -914 -2 -176 341 -138 48 -416 35 -243 394 409 431 -3 -271 -893 -787 242 -166 416 197 1055 397 694 294 318 367 19 381 329 -290 43 539 -409 197 -722 -36 -469 900000 79 366 -499 43 -503 -589 522 -743 405 -1104 283 -863 204 -420 30 878 -239 678 -433 822 -327 291 -454 354 -173 554 -546 323 643 -347 388 -50 242 -400 -90 237 -322 -148 -458 -232 -314 -961 -832 -596 -244 377 -856 699 -299 218 572 -534 146 -160 962 572 507 -80 1338 301 936 246 621 350 54 434 213 320 176 1157 -207 119 -345 -56 -559 503 375 386 234 -705 -1022 -1732 -1616 -1458 -45 -777 25 -159 895 147 244 780 1090 746 1148 1551 160 -182 -271 -653 -312 25 -381 -123 -1360 -1165 -3 -247 508 -221 79 -695 56 -364 549 550 588 -5 -415 -1432 -1269 379 -252 601 272 1507 559 1007 422 488 591 32 656 596 -557 86 1096 -849 403 -1448 -68 -871 900000 SU 20200718T130746.4Z 7504.547065 203 1 50.81 2 66.21 105.03 60.16 134.56 0.00 1 0.00 1 0 17 1.529e-02 5.700e-03 1.301e-02 2.549e-03 2.933506e-01 1.399067e-03 5.528731e-03 -6.000000e+00 9.637200e-03 236.32 -2.00 5.57 -2.00 318.35 0.00e+00 2.587653e-04 2.460180e-04 1.754976e-04 -6.000000e+00 3.925044e-04 270.14 -2.00 20.00 -2.00 317.83 0.00e+00 2.461 0.000 302.00 328.00 3 2.5294e+00 3.8147e-03 3.4680e-02 -6.0000e+00 2.4534e-02 1.7991e-02 4.2569e-03 2.5185e-02 -6.0000e+00 2.6388e-02 -1.1239e-02 2.7591e-03 1.2213e-02 -6.0000e+00 1.5493e-02 6.5654e-03 1.3846e-03 3.3813e-03 -6.0000e+00 6.3996e-03 3.0211e-03 2.2612e-04 8.4901e-05 4.3415e-05 -6.0000e+00 4.8522e-04 5.8978e-02 -1.9028e-04 10 0 0 10 0 0 99.32 22.25 0.28 0.05898 0.06068 37 7 1 8 0 1371.128 25.39 15.01 22.25 1173 -6736 3188 3293 975 -7064 -1625 -5433 3734 912 3429 -3291 993 -262 1804 2319 -2520 727 1293 980 384 5098 -1285 828 1617 -817 -579 -94 991 -926 -311 -695 -3342 -1593 -121 -935 -1166 -355 56 -1685 -1291 -684 -2106 -1423 -1196 -611 -1290 -1233 -861 252 80 1291 1258 226 1151 880 772 150 1410 650 1355 1464 1389 620 494 719 957 1076 -204 366 -267 426 -221 54 -192 1025 -217 468 258 -263 -825 -1497 -1671 -659 -419 -1063 35 -450 437 -58 421 588 475 1391 794 444 294 180 -512 -532 -342 -188 148 -116 -924 -852 -690 -116 58 -2 -12 -413 -176 -214 413 637 668 26 -184 -508 -488 -182 -29 517 490 982 929 1003 675 42 236 -44 417 303 58 -1 185 -443 -210 -297 -320 -352 900000 73 -484 207 201 57 -442 -104 -401 273 71 268 -294 96 -30 224 311 -375 110 201 158 63 811 -226 150 305 -161 -112 -17 173 -167 -60 -145 -757 -355 -26 -208 -290 -103 19 -662 -547 -301 -963 -651 -547 -276 -577 -543 -377 112 38 647 668 127 661 519 460 90 822 386 837 973 991 462 361 492 624 712 -149 294 -231 376 -194 45 -148 708 -141 300 179 -205 -720 -1436 -1558 -645 -438 -1189 40 -532 507 -64 430 607 462 1353 835 471 346 230 -679 -686 -412 -211 164 -134 -1148 -1116 -947 -166 88 -2 -20 -690 -280 -318 569 846 899 37 -279 -808 -783 -287 -43 748 676 1286 1189 1321 952 63 372 -71 696 531 107 -2 366 -819 -419 -579 -600 -640 900000 SU 20200718T131929.9Z 7504.555207 206 1 49.73 2 65.73 107.98 59.81 137.55 0.00 1 0.00 1 0 25 1.149e-02 5.534e-03 7.616e-03 1.680e-03 2.875203e-01 9.221318e-04 5.426653e-03 -6.000000e+00 7.239259e-03 236.32 -2.00 5.57 -2.00 318.09 0.00e+00 2.226856e-04 1.508571e-04 1.420001e-04 -6.000000e+00 2.948730e-04 270.14 -2.00 20.00 -2.00 317.56 0.00e+00 2.416 0.000 302.00 328.00 3 1.9881e+00 2.5017e-03 3.3960e-02 -6.0000e+00 1.8429e-02 1.1967e-02 2.7830e-03 2.4609e-02 -6.0000e+00 1.9823e-02 -1.3949e-02 1.7649e-03 1.1933e-02 -6.0000e+00 1.1638e-02 8.7206e-03 8.8017e-04 3.2892e-03 -6.0000e+00 4.8069e-03 5.4790e-03 1.4783e-04 5.5553e-05 4.1450e-05 -6.0000e+00 3.6454e-04 5.9276e-02 -2.0904e-04 10 0 0 10 0 0 99.43 22.25 0.30 0.05928 0.06039 49 10 1 8 0 1014.889 25.39 15.00 22.25 1854 -2568 -2981 -2150 -195 -136 -5357 -89 -5945 3079 -999 -116 -213 203 -1135 790 1267 26 -460 406 270 162 2310 -749 1940 -716 -76 -467 -99 2049 176 1957 -1297 -1658 -1839 317 -1888 -305 -1177 -1473 -1264 -846 -700 -709 -386 -961 -475 -917 232 113 284 643 507 439 500 899 33 614 479 1644 1116 1493 871 629 152 556 664 1597 1010 345 -109 -474 -106 -270 334 354 482 434 185 -393 -1099 -1400 -1527 -816 -795 -534 -295 -91 109 -95 469 647 842 799 1461 612 581 -161 -266 -491 -647 -409 173 -316 -886 -831 -534 -204 -177 -33 -247 -176 -71 -194 390 728 714 238 -182 -601 -422 -217 131 413 672 876 949 982 396 168 14 102 505 159 115 -90 44 -204 -314 -386 -354 -299 900000 130 -201 -233 -156 -13 -9 -401 -7 -540 265 -92 -11 -23 25 -162 120 202 4 -81 73 49 30 433 -153 404 -156 -16 -94 -19 395 37 436 -315 -405 -439 76 -518 -97 -444 -632 -585 -407 -344 -351 -191 -474 -229 -438 110 55 146 352 294 266 313 573 22 394 305 1047 748 976 614 460 109 374 468 1133 713 271 -92 -414 -91 -221 251 266 335 300 138 -299 -940 -1311 -1525 -860 -895 -638 -368 -106 136 -113 515 651 798 762 1486 695 731 -202 -345 -621 -837 -495 204 -393 -1081 -1070 -719 -288 -265 -53 -406 -288 -110 -283 527 945 940 331 -271 -938 -664 -336 195 587 909 1230 1300 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