File name: Pandora144s1_Eureka-PEARL_20200810_L2Fit_fout2c4d20190120p1-8.txt File generation date: 20241125T231415.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v3d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20200810_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20200810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 217 359 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2448 305.3856 305.5264 305.6672 305.8079 305.9487 306.0895 306.2302 306.3709 306.5116 306.6524 306.7931 306.9337 307.0744 307.2151 307.3557 307.4964 307.6370 307.7776 307.9182 308.0588 308.1994 308.3399 308.4805 308.6211 308.7616 308.9021 309.0426 309.1831 309.3236 309.4641 309.6046 309.7450 309.8855 310.0259 310.1663 310.3067 310.4471 310.5875 310.7279 310.8683 311.0086 311.1490 311.2893 311.4296 311.5699 311.7102 311.8505 311.9908 312.1311 312.2713 312.4116 312.5518 312.6920 312.8322 312.9724 313.1126 313.2528 313.3929 313.5331 313.6732 313.8134 313.9535 314.0936 314.2337 314.3737 314.5138 314.6539 314.7939 314.9340 315.0740 315.2140 315.3540 315.4940 315.6340 315.7739 315.9139 316.0538 316.1938 316.3337 316.4736 316.6135 316.7534 316.8933 317.0331 317.1730 317.3128 317.4527 317.5925 317.7323 317.8721 318.0119 318.1516 318.2914 318.4312 318.5709 318.7106 318.8503 318.9900 319.1297 319.2694 319.4091 319.5487 319.6884 319.8280 319.9676 320.1073 320.2469 320.3864 320.5260 320.6656 320.8051 320.9447 321.0842 321.2237 321.3632 321.5027 321.6422 321.7817 321.9212 322.0606 322.2000 322.3395 322.4789 322.6183 322.7577 322.8971 323.0364 323.1758 323.3151 323.4545 323.5938 323.7331 323.8724 324.0117 324.1510 324.2902 324.4295 324.5687 324.7080 324.8472 324.9864 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200810T060338.2Z 7527.252526 4 1 50.47 2 84.53 3.05 78.96 110.41 0.00 1 0.00 1 0 25 4.636e-01 2.454e-02 3.993e-01 1.913e-02 8.818377e-01 1.113872e-02 1.453957e-02 -6.000000e+00 2.845292e-01 234.01 -2.00 5.57 -2.00 322.25 0.00e+00 1.490745e-02 5.591737e-03 5.533946e-03 -6.000000e+00 1.206783e-02 269.10 -2.00 20.00 -2.00 321.80 0.00e+00 9.175 0.025 302.00 328.00 3 9.8891e-02 3.8672e-02 1.2445e-01 -6.0000e+00 7.1954e-01 1.3204e+00 4.7872e-02 9.5667e-02 -6.0000e+00 7.8008e-01 -1.5704e+00 4.2114e-02 3.9952e-02 -6.0000e+00 4.5892e-01 6.1569e-01 2.0778e-02 1.5091e-02 -6.0000e+00 1.8567e-01 3.8614e-05 -2.1652e-03 5.7272e-04 1.8370e-04 -6.0000e+00 1.4852e-02 9.4332e-03 -6.5806e-05 12 8 8 10 0 0 -2.83 22.28 0.71 0.00943 -0.00684 66 13 1 8 0 764.584 25.39 15.01 22.28 35672 -2915 -52410 900000 -97543 7821 -74761 -15555 20640 -98174 60702 -118184 900000 -82053 174470 41291 111556 -7046 34161 -58048 192003 -27437 -54304 65545 10406 56796 -37743 268618 -4431 -22479 -77142 91444 21188 35396 60142 44456 38330 21035 62046 5023 13925 -8361 58503 -16453 64251 45318 6177 20642 306 45367 57667 54568 -6559 33155 2977 50262 11616 31079 39989 36689 48676 4426 27254 21326 44702 22158 23875 10313 11795 9560 2118 11320 3520 21359 11389 5098 -6320 9450 -8321 12013 -1275 1332 -5482 -1481 -1331 1253 -473 -1774 9693 -2139 557 -6262 -158 -7505 -911 -1160 -2671 1112 -2383 -1208 -2544 1492 -3994 1767 -5865 1366 -7964 -24 -781 -1375 -2068 250 232 108 -510 -1283 1570 -2233 962 -1255 2534 1665 1216 656 2550 2424 629 1991 -239 1350 161 916 155 -32 -541 1367 1041 -981 -854 -1209 1070 -1522 -309 665 -69 -1955 900000 -4299 146 -2154 -290 385 -3162 1132 -5609 900000 -4451 3253 910 2080 -287 927 -3837 3580 -1163 -2854 1222 265 1059 -1408 5009 -132 -922 -6015 1705 869 1254 1570 1326 1286 941 2082 328 883 -686 2509 -1503 2636 2282 472 1424 27 2792 3441 3663 -868 3091 383 4030 1343 2840 3206 3010 3721 586 3252 2982 5168 3223 3472 1827 2287 2103 533 2617 840 3903 2060 894 -1214 1674 -2064 2912 -414 477 -2290 -632 -600 580 -231 -890 4265 -1013 242 -2791 -67 -3736 -494 -751 -2067 946 -2048 -1020 -2230 1135 -2994 1259 -4757 1096 -7529 -23 -778 -1575 -2664 336 318 145 -671 -1687 2063 -3207 1400 -1896 3596 2509 1771 931 3448 3209 859 2941 -415 2407 323 1982 364 -82 -1460 3769 2939 -2837 -2416 -3259 2624 -3597 -781 SU 20200810T061628.2Z 7527.261437 7 1 50.33 2 84.48 6.16 78.42 113.52 0.00 1 0.00 1 0 25 4.789e-01 2.072e-02 4.469e-01 1.780e-02 8.678116e-01 1.075695e-02 1.398687e-02 -6.000000e+00 2.968561e-01 234.01 -2.00 5.57 -2.00 322.31 0.00e+00 7.688506e-03 5.821343e-03 7.065757e-03 -6.000000e+00 1.351621e-02 269.10 -2.00 20.00 -2.00 321.88 0.00e+00 9.121 0.025 302.00 328.00 3 2.2357e-01 3.8555e-02 1.2454e-01 -6.0000e+00 7.5328e-01 9.3526e-01 5.3347e-02 9.7062e-02 -6.0000e+00 8.1846e-01 -1.1701e+00 5.4588e-02 4.4081e-02 -6.0000e+00 4.8132e-01 4.6562e-01 2.5502e-02 1.3106e-02 -6.0000e+00 1.9580e-01 4.1227e-05 -8.7007e-04 5.6797e-04 1.8762e-04 -6.0000e+00 1.5540e-02 7.6032e-03 -9.8511e-06 12 8 8 10 0 0 22.17 22.29 0.70 0.00760 0.00107 71 14 1 8 0 708.780 25.39 15.00 22.29 900000 -54917 -134143 900000 32372 -14325 95902 -39802 -93680 900000 -98536 900000 -171159 900000 -82588 900000 -45190 900000 158730 66666 85840 1650 900000 223455 -52764 3628 25478 56846 900000 -143296 5550 -76104 -8861 -32159 167982 29915 30859 107623 13182 30246 33414 13055 -23684 46528 -11470 -9705 57218 52058 74175 63040 39393 29131 34859 41264 62029 9454 39701 13584 8200 13152 26464 25355 22329 35704 -4650 48073 -5294 18557 169 13195 -551 14311 12951 5641 -294 1513 10489 -1181 709 4382 1806 5098 1639 2902 -656 -754 -3772 551 843 3810 -5000 2281 -1364 3761 -841 1931 -2209 -3168 616 -2932 -2966 592 -1097 -1942 -2935 -2158 1151 -2959 168 -217 -523 -1870 -557 1643 897 15 -1850 178 -1696 -7 -24 1899 806 -712 2805 985 949 1193 146 827 1296 685 203 486 -857 -291 813 -348 85 -121 278 -349 -1348 900000 -952 -2747 900000 561 -248 1662 -690 -1623 900000 -1707 900000 -6740 900000 -2082 900000 -997 900000 2750 1155 1487 29 900000 3872 -1330 63 441 985 900000 -9932 115 -4220 -276 -1282 2911 622 695 1865 480 1048 1216 611 -1642 1612 -715 -605 1884 1894 2313 2403 2116 1918 2356 2789 3547 934 2889 1247 767 1162 2155 2329 2399 3712 -757 4665 -899 2669 33 2515 -129 2926 2581 1114 -55 257 1599 -219 151 1078 535 1661 605 1132 -282 -342 -1837 261 391 1644 -2227 909 -572 1642 -447 1184 -1657 -2728 497 -2429 -2518 440 -779 -1410 -2278 -1769 981 -2891 164 -242 -652 -2515 -751 2130 1139 19 -2459 244 -2480 -10 -34 2540 1155 -1004 3708 1297 1269 1744 226 1449 2511 1446 463 1187 -2265 -796 2249 -979 234 -317 674 -802 -3410 SU 20200810T062645.2Z 7527.268579 10 1 50.49 2 84.43 8.65 78.00 116.02 0.00 1 0.00 1 0 25 4.456e-01 2.134e-02 4.260e-01 1.800e-02 8.720004e-01 1.077336e-02 1.406844e-02 -6.000000e+00 2.783199e-01 234.01 -2.00 5.57 -2.00 322.26 0.00e+00 4.375874e-03 5.705599e-03 3.832544e-03 -6.000000e+00 1.239170e-02 269.10 -2.00 20.00 -2.00 321.83 0.00e+00 9.052 0.024 302.00 328.00 3 2.5816e-01 3.8394e-02 1.1826e-01 -6.0000e+00 7.0804e-01 1.0463e+00 5.0512e-02 8.1669e-02 -6.0000e+00 7.7030e-01 -1.2875e+00 4.9336e-02 4.0104e-02 -6.0000e+00 4.4975e-01 5.0925e-01 2.3432e-02 1.2239e-02 -6.0000e+00 1.8054e-01 4.1008e-05 -1.1063e-03 5.6902e-04 1.8372e-04 -6.0000e+00 1.4389e-02 8.4958e-03 -4.9936e-05 12 8 8 10 0 0 9.54 22.28 0.64 0.00850 0.00018 68 13 1 8 0 742.439 25.39 15.00 22.28 -40798 900000 -135545 -81699 -48415 -20821 -184646 900000 900000 -134536 -6310 -94142 900000 -96016 92296 35556 900000 -42652 900000 -13482 -23656 42470 112307 13909 35423 900000 -64137 66336 -8979 900000 -53123 51871 70184 37049 26093 -11936 236725 -37375 87996 59567 30488 -24650 57468 28444 77965 21861 23953 -697 16012 -2089 14851 81216 8707 26379 28532 80496 42894 33272 5175 3605 91 -1091 54329 12898 24855 1586 20155 3016 8783 4456 8692 13101 5081 9837 -5943 3215 -4672 9700 -5857 8977 -468 6265 2890 -579 587 1925 -4488 -3244 4854 -1202 4673 2576 4481 -871 3465 -3590 217 490 -106 -465 -3467 -1149 -3609 -4375 -3013 -2051 -3939 -1332 -3181 -3574 -298 -1179 38 -1445 -215 -670 1490 -2004 1156 -613 1433 830 4116 1616 3147 2072 119 1026 252 1868 -248 -7 742 465 -237 414 122 -221 149 -1549 577 -872 -754 -715 900000 -4536 -1432 -849 -365 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