File name: Pandora144s1_Eureka-PEARL_20230509_L2Fit_fout2c5d20210211p1-8.txt File generation date: 20241124T012106.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Xiaoyi Zhao Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v5d20180302.txt Instrument calibration file used: Pandora144s1_CF_v5d20210211.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20230509_L1_smca1c5d20210211p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20230509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 217 358 Nominal wavelengths inside fitting window [nm]: 305.1392 305.2800 305.4207 305.5615 305.7022 305.8430 305.9837 306.1244 306.2651 306.4057 306.5464 306.6871 306.8277 306.9684 307.1090 307.2496 307.3902 307.5308 307.6714 307.8119 307.9525 308.0930 308.2336 308.3741 308.5146 308.6551 308.7956 308.9361 309.0766 309.2170 309.3575 309.4979 309.6383 309.7787 309.9191 310.0595 310.1999 310.3403 310.4806 310.6210 310.7613 310.9016 311.0419 311.1822 311.3225 311.4628 311.6031 311.7433 311.8836 312.0238 312.1640 312.3042 312.4444 312.5846 312.7248 312.8649 313.0051 313.1452 313.2854 313.4255 313.5656 313.7057 313.8458 313.9859 314.1259 314.2660 314.4060 314.5460 314.6860 314.8261 314.9660 315.1060 315.2460 315.3860 315.5259 315.6659 315.8058 315.9457 316.0856 316.2255 316.3654 316.5052 316.6451 316.7849 316.9248 317.0646 317.2044 317.3442 317.4840 317.6238 317.7636 317.9033 318.0431 318.1828 318.3225 318.4622 318.6019 318.7416 318.8813 319.0209 319.1606 319.3002 319.4399 319.5795 319.7191 319.8587 319.9983 320.1379 320.2774 320.4170 320.5565 320.6960 320.8355 320.9750 321.1145 321.2540 321.3935 321.5330 321.6724 321.8118 321.9513 322.0907 322.2301 322.3695 322.5088 322.6482 322.7876 322.9269 323.0662 323.2056 323.3449 323.4842 323.6234 323.7627 323.9020 324.0412 324.1805 324.3197 324.4589 324.5981 324.7373 324.8765 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230509T141847.7Z 8529.596385 6 1 50.31 2 66.52 126.22 115.90 250.77 0.00 1 0.00 1 0 25 8.493e-02 6.385e-03 5.584e-02 4.011e-03 4.748252e-01 2.174746e-03 8.705038e-03 -6.000000e+00 5.249996e-02 231.85 -2.00 5.57 -2.00 319.62 0.00e+00 2.016838e-03 5.400556e-04 4.577884e-04 -6.000000e+00 2.077122e-03 257.97 -2.00 20.00 -2.00 319.34 0.00e+00 2.491 0.000 302.00 328.00 3 4.7799e+00 5.9998e-03 4.7251e-02 -6.0000e+00 1.3262e-01 1.1654e-01 6.9087e-03 3.9803e-02 -6.0000e+00 1.4357e-01 -6.5160e-02 5.8433e-03 2.0283e-02 -6.0000e+00 8.4053e-02 2.6048e-02 3.1289e-03 6.3712e-03 -6.0000e+00 3.4626e-02 2.2045e-04 -4.7999e-04 1.2881e-04 7.4094e-05 -6.0000e+00 2.6941e-03 2.8625e-03 -7.6082e-05 10 0 0 10 0 0 -30.49 19.27 0.28 0.00286 -0.00074 14 3 1 8 0 3593.308 23.01 15.00 19.27 34629 -25501 -39742 -17937 -31227 -25938 -20295 4154 -28558 -11763 -41625 -6505 -22773 -3399 -17127 2587 3409 5044 -4180 -1941 5364 3980 2450 -1894 -1855 1198 -2319 -5361 1714 3109 561 3188 -3190 3069 -3215 879 -5414 -1990 -2810 -901 -2552 450 2035 -877 265 -472 1480 -1228 1569 703 3490 -739 3263 -330 -1253 885 1416 1890 368 1647 692 2448 1748 -402 -1618 2473 733 348 52 902 729 590 984 -718 -338 -1911 -569 -1677 276 -1318 -69 -1737 -1679 -385 -548 85 -131 164 456 85 739 995 144 -288 581 402 1122 -102 -80 -396 -492 -665 -262 -1029 -941 -1145 147 160 -291 467 -94 281 -460 254 421 -14 113 -317 282 -625 107 57 378 -44 521 1042 1021 158 10 520 20 210 -132 66 -429 217 384 -233 -187 34 -227 -587 447 -589 -1060 -400 -757 -609 -492 88 -905 -331 -1693 -214 -1060 -157 -962 133 189 294 -281 -132 378 290 190 -163 -152 107 -210 -489 147 283 59 368 -420 382 -420 116 -862 -364 -556 -198 -619 111 509 -229 69 -124 422 -332 468 204 1070 -256 1164 -128 -511 362 579 759 148 663 298 1133 889 -219 -886 1250 372 186 31 585 503 414 667 -463 -198 -1040 -292 -899 162 -896 -52 -1469 -1517 -364 -553 90 -145 182 492 88 698 875 124 -260 575 449 1397 -140 -103 -541 -622 -779 -297 -1224 -1186 -1523 203 215 -426 732 -156 467 -743 383 599 -22 159 -472 438 -1004 169 87 557 -68 763 1455 1415 233 16 825 34 368 -241 128 -876 455 819 -502 -396 69 -439 -1094 SS 20230509T142439.1Z 8529.600453 9 1 50.47 2 66.32 127.73 116.12 252.12 0.00 1 0.00 1 0 25 6.654e-02 6.561e-03 5.699e-02 3.966e-03 4.767435e-01 2.167794e-03 8.800718e-03 -6.000000e+00 4.112715e-02 231.85 -2.00 5.57 -2.00 319.61 0.00e+00 1.174827e-03 5.388086e-04 3.758716e-04 -6.000000e+00 1.627454e-03 257.98 -2.00 20.00 -2.00 319.32 0.00e+00 2.471 0.000 302.00 328.00 3 4.7763e+00 6.0302e-03 4.7457e-02 -6.0000e+00 1.0389e-01 1.2252e-01 6.9292e-03 4.0064e-02 -6.0000e+00 1.1248e-01 -6.4404e-02 5.8640e-03 2.0493e-02 -6.0000e+00 6.5847e-02 2.2174e-02 3.1317e-03 6.2513e-03 -6.0000e+00 2.7122e-02 2.2464e-04 -4.5885e-04 1.2883e-04 7.8353e-05 -6.0000e+00 2.1108e-03 3.5707e-03 -8.3070e-05 11 9 0 11 8 0 -17.36 19.27 0.34 0.00357 0.00012 14 3 1 8 0 3543.418 23.01 15.00 19.27 5672 -22097 -17355 -22992 -29274 -16621 -29467 435 -21013 -13180 -15056 19910 -17651 -15255 -3642 7302 -11132 -3489 7051 -2131 4046 991 690 -7842 2436 4244 -5206 -6032 1840 -12563 -3698 351 2517 -2129 4108 -8543 -4036 2578 -2036 66 2005 -3590 192 -3088 -832 2570 -1451 -181 1096 -231 1455 393 3713 1296 2191 576 648 935 1554 -438 2118 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-489 -281 -362 106 SS 20230509T143813.7Z 8529.609881 12 1 48.81 2 65.86 131.24 116.65 255.25 0.00 1 0.00 1 0 25 7.583e-02 6.413e-03 5.350e-02 3.883e-03 4.607049e-01 2.116398e-03 8.563711e-03 -6.000000e+00 4.686267e-02 231.85 -2.00 5.57 -2.00 319.53 0.00e+00 1.041565e-03 5.148522e-04 3.481421e-04 -6.000000e+00 1.855169e-03 257.98 -2.00 20.00 -2.00 319.24 0.00e+00 2.428 0.000 302.00 328.00 3 4.8058e+00 5.8731e-03 4.6101e-02 -6.0000e+00 1.1838e-01 8.9995e-02 6.7380e-03 3.8793e-02 -6.0000e+00 1.2817e-01 -4.5678e-02 5.6255e-03 1.9745e-02 -6.0000e+00 7.5034e-02 1.7665e-02 3.0036e-03 5.9353e-03 -6.0000e+00 3.0899e-02 2.3475e-04 -5.7293e-04 1.2639e-04 7.5299e-05 -6.0000e+00 2.4059e-03 3.6636e-03 -1.4165e-04 11 8 0 10 0 0 61.13 19.28 0.47 0.00366 -0.00064 14 3 1 8 0 3485.924 23.01 15.00 19.28 -31493 -509 -41247 -31506 -9143 -29186 23172 -30424 -230 -7340 -26417 2935 14037 1228 -770 2747 -5630 -2333 9536 5383 -999 3150 -3546 -7920 -10153 -3963 -7413 3875 -659 -3922 9254 -6445 -598 -1942 -2649 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