File name: Pandora144s1_Eureka-PEARL_20230705_L2Fit_fout2c5d20210211p1-8.txt File generation date: 20241124T013950.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Xiaoyi Zhao Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v5d20180302.txt Instrument calibration file used: Pandora144s1_CF_v5d20210211.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20230705_L1_smca1c5d20210211p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20230705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 217 358 Nominal wavelengths inside fitting window [nm]: 305.1392 305.2800 305.4207 305.5615 305.7022 305.8430 305.9837 306.1244 306.2651 306.4057 306.5464 306.6871 306.8277 306.9684 307.1090 307.2496 307.3902 307.5308 307.6714 307.8119 307.9525 308.0930 308.2336 308.3741 308.5146 308.6551 308.7956 308.9361 309.0766 309.2170 309.3575 309.4979 309.6383 309.7787 309.9191 310.0595 310.1999 310.3403 310.4806 310.6210 310.7613 310.9016 311.0419 311.1822 311.3225 311.4628 311.6031 311.7433 311.8836 312.0238 312.1640 312.3042 312.4444 312.5846 312.7248 312.8649 313.0051 313.1452 313.2854 313.4255 313.5656 313.7057 313.8458 313.9859 314.1259 314.2660 314.4060 314.5460 314.6860 314.8261 314.9660 315.1060 315.2460 315.3860 315.5259 315.6659 315.8058 315.9457 316.0856 316.2255 316.3654 316.5052 316.6451 316.7849 316.9248 317.0646 317.2044 317.3442 317.4840 317.6238 317.7636 317.9033 318.0431 318.1828 318.3225 318.4622 318.6019 318.7416 318.8813 319.0209 319.1606 319.3002 319.4399 319.5795 319.7191 319.8587 319.9983 320.1379 320.2774 320.4170 320.5565 320.6960 320.8355 320.9750 321.1145 321.2540 321.3935 321.5330 321.6724 321.8118 321.9513 322.0907 322.2301 322.3695 322.5088 322.6482 322.7876 322.9269 323.0662 323.2056 323.3449 323.4842 323.6234 323.7627 323.9020 324.0412 324.1805 324.3197 324.4589 324.5981 324.7373 324.8765 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230705T153019.0Z 8586.646053 112 1 50.11 2 59.23 142.01 115.68 287.80 0.00 1 0.00 1 0 25 8.043e-03 6.125e-03 6.624e-04 2.072e-04 2.601899e-01 1.134135e-04 4.958003e-03 -6.000000e+00 5.057619e-03 236.58 -2.00 5.57 -2.00 317.45 0.00e+00 1.707504e-04 1.554293e-05 1.042156e-04 -6.000000e+00 2.055178e-04 269.05 -2.00 20.00 -2.00 316.94 0.00e+00 1.947 0.000 302.00 328.00 3 2.6458e-01 3.0441e-04 2.9399e-02 -6.0000e+00 1.2887e-02 -1.8524e-04 3.3680e-04 2.2287e-02 -6.0000e+00 1.3876e-02 -1.5130e-02 2.0278e-04 1.0747e-02 -6.0000e+00 8.1398e-03 9.2838e-03 9.7546e-05 2.9064e-03 -6.0000e+00 3.3475e-03 4.9067e-02 -3.2269e-04 6.7573e-06 3.8687e-05 -6.0000e+00 2.5564e-04 6.4899e-03 -8.4289e-05 10 0 0 10 0 0 9.21 20.51 0.32 0.00649 0.00407 2128 417 1 8 0 23.547 23.93 15.00 20.51 -794 -1917 -2878 -2476 -1259 -293 102 362 -776 -1131 -299 429 952 538 100 -492 63 286 454 362 402 866 663 239 -62 -844 -1377 -64 581 891 1056 656 -908 -1837 -647 -293 -80 209 -446 -1306 -1025 -919 -1044 -1004 -700 -1013 -723 -490 13 562 605 940 830 339 697 831 609 527 1117 1407 1645 1368 751 -356 107 432 501 1114 1114 128 -299 -331 -495 -340 -91 495 455 685 347 -438 -1079 -1561 -1433 -869 -763 -684 -312 -460 -174 -127 476 543 1130 1362 1096 802 168 -324 -693 -394 -419 125 600 -116 -1017 -619 -423 -291 -46 -219 -281 -378 -101 151 771 1029 896 285 -406 -711 -404 -168 -96 343 722 1024 1337 1117 245 195 9 179 311 131 -97 -153 151 -499 -458 -351 -118 -210 -88 -224 -331 -262 -124 -29 11 43 -99 -148 -40 61 151 97 20 -106 14 66 109 89 100 217 173 66 -18 -246 -390 -17 148 231 291 195 -285 -573 -195 -92 -28 87 -199 -656 -548 -510 -589 -568 -394 -565 -394 -261 7 305 348 573 533 228 479 581 429 368 771 985 1210 1085 637 -286 90 338 375 851 931 109 -272 -307 -451 -293 -78 384 330 498 273 -389 -979 -1543 -1502 -962 -902 -792 -375 -561 -207 -155 533 558 1093 1334 1160 940 202 -420 -919 -503 -499 151 719 -148 -1283 -819 -585 -422 -70 -328 -434 -576 -157 218 1027 1328 1182 399 -609 -1116 -636 -259 -143 486 969 1308 1808 1445 340 287 14 280 502 206 -161 -265 266 -896 -816 -606 -197 -341 SS 20230705T160151.9Z 8586.667961 118 1 50.13 2 58.48 150.47 116.78 295.51 0.00 1 0.00 1 0 25 7.988e-03 6.112e-03 6.096e-04 1.973e-04 2.563849e-01 1.082411e-04 4.870876e-03 -6.000000e+00 5.022706e-03 236.58 -2.00 5.57 -2.00 317.36 0.00e+00 1.722210e-04 1.448888e-05 9.339491e-05 -6.000000e+00 2.041158e-04 269.06 -2.00 20.00 -2.00 316.85 0.00e+00 1.905 0.000 302.00 328.00 3 2.2110e-01 2.8988e-04 2.8857e-02 -6.0000e+00 1.2798e-02 -3.2916e-03 3.2085e-04 2.1900e-02 -6.0000e+00 1.3780e-02 -1.4037e-02 1.9211e-04 1.0565e-02 -6.0000e+00 8.0838e-03 9.8161e-03 9.1895e-05 2.8618e-03 -6.0000e+00 3.3243e-03 5.3560e-02 -3.4557e-04 6.4554e-06 3.7082e-05 -6.0000e+00 2.5390e-04 6.7537e-03 -8.8472e-05 10 0 0 10 0 0 19.98 20.48 0.32 0.00675 0.00416 2241 440 1 8 0 22.357 24.04 15.00 20.48 -1060 -1968 -2857 -2463 -1143 94 52 478 -733 -1017 -217 405 980 281 102 -570 93 200 412 306 513 917 723 182 -39 -699 -1303 132 637 936 892 922 -854 -1774 -625 -292 -193 248 -418 -1282 -1071 -876 -1073 -1039 -606 -997 -683 -470 87 577 612 902 785 329 598 766 518 555 1058 1410 1668 1441 699 -381 100 411 511 1095 1157 82 -246 -355 -467 -335 -102 537 454 709 389 -370 -1031 -1473 -1452 -870 -757 -706 -353 -476 -186 -123 493 548 1169 1345 1113 808 208 -359 -710 -379 -431 101 540 -143 -994 -619 -467 -291 -37 -246 -325 -420 -129 132 820 1018 917 307 -357 -693 -355 -99 -53 319 703 1035 1333 1085 222 157 -26 142 325 148 -115 -165 156 -471 -458 -332 -108 -223 -123 -240 -342 -272 -117 10 6 59 -97 -138 -30 60 162 53 21 -127 21 48 102 78 132 237 194 52 -12 -210 -380 36 167 249 253 280 -274 -567 -193 -94 -70 96 -191 -658 -586 -496 -619 -602 -348 -568 -379 -256 47 319 359 560 514 225 418 545 371 394 743 1004 1248 1162 553 -311 85 326 388 847 980 71 -227 -334 -431 -292 -89 422 334 521 310 -333 -946 -1471 -1539 -974 -904 -827 -430 -587 -224 -140 558 568 1142 1330 1189 955 251 -470 -949 -487 -517 123 652 -169 -1264 -827 -652 -426 -54 -372 -504 -644 -186 191 1098 1321 1215 432 -539 -1015 -522 -154 -80 455 950 1329 1673 1410 309 232 -39 224 525 234 -192 -286 276 -848 -817 -575 -180 -363 SS 20230705T162536.8Z 8586.684453 124 1 50.11 2 58.02 156.88 117.57 301.37 0.00 1 0.00 1 0 25 8.183e-03 6.166e-03 5.959e-04 1.969e-04 2.542293e-01 1.081686e-04 4.842173e-03 -6.000000e+00 5.145348e-03 236.58 -2.00 5.57 -2.00 317.32 0.00e+00 1.876477e-04 1.429143e-05 9.753070e-05 -6.000000e+00 2.091107e-04 269.06 -2.00 20.00 -2.00 316.81 0.00e+00 1.881 0.000 302.00 328.00 3 2.3924e-01 2.8949e-04 2.8590e-02 -6.0000e+00 1.3110e-02 -3.2808e-04 3.2029e-04 2.1746e-02 -6.0000e+00 1.4117e-02 -1.4810e-02 1.9129e-04 1.0484e-02 -6.0000e+00 8.2812e-03 8.8282e-03 9.1189e-05 2.8346e-03 -6.0000e+00 3.4054e-03 5.3901e-02 -3.4364e-04 6.4401e-06 3.7555e-05 -6.0000e+00 2.6010e-04 6.8405e-03 -9.3112e-05 10 0 0 10 0 0 17.34 20.47 0.31 0.00684 0.00426 2260 443 1 8 0 22.169 23.93 15.00 20.47 -1016 -1833 -2910 -2816 -1041 -701 380 302 -468 -1378 135 307 1102 236 185 -568 90 392 275 424 489 1139 570 371 -47 -659 -1403 77 743 1008 1068 685 -770 -1945 -405 -330 67 175 -282 -1285 -1023 -921 -1104 -1000 -720 -1001 -800 -409 3 630 539 923 763 332 651 735 596 490 1132 1352 1709 1354 717 -410 89 443 565 1157 1081 118 -355 -346 -506 -310 -136 569 453 723 401 -463 -1065 -1552 -1424 -858 -713 -697 -298 -487 -140 -149 506 493 1142 1348 1091 843 172 -331 -731 -342 -426 124 612 -105 -1004 -638 -423 -309 -21 -239 -305 -408 -70 93 820 997 911 286 -388 -706 -413 -114 -78 339 714 1045 1308 1138 244 222 13 172 316 103 -114 -183 175 -476 -452 -345 -104 -220 -121 -229 -357 -320 -109 -74 43 38 -63 -192 19 46 185 45 39 -129 21 96 69 110 128 299 156 107 -14 -201 -416 21 197 271 306 211 -250 -630 -126 -108 25 69 -130 -667 -566 -528 -644 -585 -419 -576 -449 -224 1 351 318 577 503 229 458 527 430 350 800 970 1286 1099 570 -337 76 353 431 898 919 102 -328 -326 -468 -271 -119 448 334 532 320 -416 -978 -1552 -1510 -961 -852 -817 -362 -600 -169 -169 573 512 1115 1332 1164 995 208 -432 -976 -438 -510 151 737 -125 -1275 -851 -590 -451 -29 -360 -472 -623 -102 134 1095 1290 1204 402 -584 -1109 -606 -176 -116 481 962 1338 1637 1474 339 326 20 268 509 162 -189 -316 308 -854 -803 -596 -173 -357 SS 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