File name: Pandora174s1_FairbanksAK_20241228_L2Fit_fwvt1c4d20230117p1-8.txt File generation date: 20241229T095919.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Jingqiu Mao Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 174 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora174_OF_v4d20200215.txt Instrument calibration file used: Pandora174s1_CF_v4d20230117.txt Level 1 file used: Pandora174s1_FairbanksAK_20241228_L1_smca1c4d20230117p1-8.txt Full location name: University of Alaska Fairbanks campus Short location name: FairbanksAK Country of location: USA Location latitude [deg]: 64.8594 Location longitude [deg]: -147.8499 Location altitude [m]: 227 Local noon date: 20241228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 3 latest vp for new VP from 20230117 or 20230614 First and last pixel inside fitting window: 1650 1799 Nominal wavelengths inside fitting window [nm]: 492.0795 492.2006 492.3217 492.4428 492.5639 492.6849 492.8059 492.9270 493.0480 493.1689 493.2899 493.4109 493.5318 493.6527 493.7736 493.8945 494.0154 494.1362 494.2571 494.3779 494.4987 494.6195 494.7403 494.8610 494.9817 495.1025 495.2232 495.3439 495.4645 495.5852 495.7058 495.8264 495.9470 496.0676 496.1882 496.3088 496.4293 496.5498 496.6703 496.7908 496.9113 497.0317 497.1522 497.2726 497.3930 497.5134 497.6338 497.7541 497.8744 497.9948 498.1151 498.2354 498.3556 498.4759 498.5961 498.7163 498.8365 498.9567 499.0769 499.1971 499.3172 499.4373 499.5574 499.6775 499.7976 499.9176 500.0377 500.1577 500.2777 500.3977 500.5176 500.6376 500.7575 500.8774 500.9973 501.1172 501.2371 501.3570 501.4768 501.5966 501.7164 501.8362 501.9560 502.0757 502.1954 502.3152 502.4349 502.5545 502.6742 502.7939 502.9135 503.0331 503.1527 503.2723 503.3919 503.5114 503.6309 503.7505 503.8700 503.9894 504.1089 504.2283 504.3478 504.4672 504.5866 504.7060 504.8253 504.9447 505.0640 505.1833 505.3026 505.4219 505.5412 505.6604 505.7796 505.8988 506.0180 506.1372 506.2564 506.3755 506.4946 506.6137 506.7328 506.8519 506.9710 507.0900 507.2090 507.3280 507.4470 507.5660 507.6850 507.8039 507.9228 508.0417 508.1606 508.2795 508.3984 508.5172 508.6360 508.7548 508.8736 508.9924 509.1111 509.2299 509.3486 509.4673 509.5860 509.7046 509.8233 509.9419 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241228T231156.9Z 9128.966630 388 1 49.11 2 89.37 197.99 99.60 220.09 0.00 1 0.00 1 0 22 9.309e-03 9.170e-03 8.663e-04 8.627e-04 3.575075e+03 4.514477e+01 2.882458e+02 -6.000000e+00 4.459918e+02 257.56 -2.00 20.00 -2.00 505.40 0.00e+00 1.414771e-03 2.211214e-05 7.491209e-05 -6.000000e+00 2.417706e-04 257.56 -2.00 20.00 -2.00 501.12 0.00e+00 1.857595e+00 1.617671e-02 3.503310e-02 -6.000000e+00 1.807534e-01 216.29 -2.00 4.56 -2.00 502.61 0.00e+00 19.985 0.224 489.00 513.00 1 4.8908e+00 1.2250e-03 4.1789e-02 -6.0000e+00 1.3724e-02 -4.4761e-02 3.1726e-04 2.4045e-03 -6.0000e+00 3.6301e-03 8.0206e-04 1.1273e-03 7.2311e-05 5.9468e-05 -6.0000e+00 8.0256e-04 3.6084e-02 -2.2886e-04 12 8 8 10 0 0 15.42 21.75 3.59 0.03608 0.04390 18 4 1 4 0 2728.100 25.07 20.01 21.75 9.95 26.1 994.00 -2484 -1616 -723 199 367 1010 1587 1622 1302 863 354 -44 -446 -991 -1143 -648 -540 6 718 745 549 749 276 877 1231 1294 1131 476 -969 -1287 -1640 -1198 -729 397 635 592 609 -348 -499 -368 -142 -21 436 879 1035 1002 1074 513 105 -674 -1353 -2076 -2228 -1978 -425 -180 412 640 269 535 541 668 1085 1108 684 618 29 -241 -737 -1133 -1021 -454 -80 174 -115 -156 -812 -859 -1118 -1414 -1201 -974 -850 -914 -236 -416 -488 -588 -93 -454 122 917 1184 1195 1022 844 243 -805 -1593 -1772 -1988 -1319 -438 47 220 165 -520 -1146 -835 -311 -194 299 809 953 1268 1512 1730 1330 1084 610 189 8 273 471 530 532 886 744 642 710 265 -205 -644 -1147 -1078 -605 -165 89 818 681 591 539 401 787 564 431 -680 -1387 -1601 -1512 -2169 -1435 -644 183 336 940 1501 1549 1243 817 333 -41 -411 -911 -1052 -599 -510 6 691 724 536 732 272 866 1190 1252 1094 458 -943 -1214 -1540 -1133 -707 388 637 596 606 -346 -492 -362 -140 -21 428 872 1037 1007 1071 509 103 -664 -1302 -1970 -2107 -1900 -418 -178 414 647 273 539 548 665 1081 1103 678 620 29 -238 -722 -1100 -986 -441 -78 173 -113 -156 -799 -834 -1080 -1371 -1173 -961 -843 -895 -233 -415 -488 -588 -92 -456 124 915 1201 1210 1021 849 241 -784 -1564 -1718 -1942 -1279 -439 48 224 168 -538 -1173 -849 -320 -199 311 849 1008 1314 1577 1822 1412 1143 636 195 8 286 486 552 556 926 778 674 748 278 -211 -662 -1177 -1111 -636 -174 96 884 747 639 587 441 870 626 475 -741 -1481 -1733 -1609 SQ 20241228T231650.2Z 9128.970026 393 1 48.85 2 89.54 199.10 99.93 221.09 0.00 1 0.00 1 0 15 9.610e-03 9.509e-03 8.447e-04 8.408e-04 3.674127e+03 4.415644e+01 2.929816e+02 -6.000000e+00 4.605872e+02 257.56 -2.00 20.00 -2.00 505.41 0.00e+00 1.502260e-03 2.159719e-05 8.001283e-05 -6.000000e+00 2.495923e-04 257.56 -2.00 20.00 -2.00 501.16 0.00e+00 1.787401e+00 1.576750e-02 3.659922e-02 -6.000000e+00 1.864848e-01 216.29 -2.00 4.56 -2.00 502.65 0.00e+00 20.325 0.236 489.00 513.00 1 4.7905e+00 1.1937e-03 4.3326e-02 -6.0000e+00 1.4161e-02 -4.7621e-02 3.0861e-04 2.4909e-03 -6.0000e+00 3.7410e-03 8.4986e-04 4.5085e-04 7.0538e-05 6.0706e-05 -6.0000e+00 8.2828e-04 -1.5377e-02 1.5254e-04 12 8 8 10 0 0 5.26 21.75 4.10 -0.01538 -0.01225 20 4 1 4 0 2442.480 25.07 20.00 21.75 10.03 25.8 991.45 -2415 -1709 -704 103 523 1124 1726 1514 1321 588 201 -57 -359 -787 -1175 -851 -612 49 627 676 839 600 529 943 1159 1216 1090 454 -925 -1508 -1716 -1418 -684 278 754 815 406 -84 -474 -506 -190 187 530 956 1054 1080 1037 718 172 -711 -1587 -1995 -2275 -1912 -532 -115 661 722 302 621 648 693 1066 1061 771 674 103 -74 -857 -1157 -883 -521 -257 -153 -77 -371 -735 -896 -1223 -1642 -1040 -981 -896 -744 -467 -309 -480 -664 -273 -231 279 939 963 1061 1110 898 173 -541 -1754 -1914 -2015 -1386 -697 116 614 257 -659 -1103 -1060 -392 -268 519 901 1021 1308 1637 1793 1577 925 590 246 -86 157 633 501 634 783 713 716 556 187 -344 -641 -1275 -1224 -716 -127 168 772 839 668 604 557 765 583 254 -614 -1469 -1581 -1454 -2126 -1486 -632 93 481 1054 1643 1417 1236 547 185 -53 -335 -728 -1091 -796 -566 47 609 645 800 576 510 913 1129 1187 1064 441 -883 -1440 -1629 -1357 -650 274 742 804 398 -82 -460 -489 -184 183 524 957 1067 1096 1046 718 170 -691 -1550 -1915 -2179 -1859 -515 -115 653 718 301 616 646 698 1076 1070 773 666 101 -72 -831 -1140 -865 -513 -250 -151 -77 -367 -715 -883 -1202 -1578 -1004 -957 -880 -739 -470 -305 -475 -658 -270 -229 279 953 994 1093 1124 895 170 -533 -1709 -1841 -1951 -1368 -696 117 632 264 -675 -1118 -1072 -400 -279 534 937 1071 1378 1735 1920 1659 970 627 258 -90 163 665 531 674 814 741 747 584 195 -362 -670 -1334 -1287 -751 -137 179 831 915 735 670 610 842 644 279 -664 -1598 -1702 -1576 SQ 20241228T232007.4Z 9128.972308 397 1 50.90 2 89.65 199.84 100.15 221.77 0.00 1 0.00 1 0 15 1.025e-02 1.011e-02 9.004e-04 8.957e-04 3.675202e+03 4.701634e+01 2.895963e+02 -6.000000e+00 4.911994e+02 257.56 -2.00 20.00 -2.00 505.42 0.00e+00 1.594766e-03 2.303735e-05 8.448569e-05 -6.000000e+00 2.662125e-04 257.56 -2.00 20.00 -2.00 501.20 0.00e+00 1.773734e+00 1.677063e-02 3.783575e-02 -6.000000e+00 1.989631e-01 216.29 -2.00 4.56 -2.00 502.68 0.00e+00 20.540 0.244 489.00 513.00 1 4.9171e+00 1.2702e-03 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