File name: Pandora205s1_FortYatesND_20240824_L2Fit_fout2c3d20231113p1-8.txt File generation date: 20241127T223653.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mafany Ndiva Mongoh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 205 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora205_OF_v3d20210326.txt Instrument calibration file used: Pandora205s1_CF_v3d20231113.txt Level 1 file used: Pandora205s1_FortYatesND_20240824_L1_smca1c3d20231113p1-8.txt Full location name: Sitting Bull College Fort Yates ND Short location name: FortYatesND Country of location: United States Location latitude [deg]: 46.0857 Location longitude [deg]: -100.6760 Location altitude [m]: 533 Local noon date: 20240824 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 2 First and last pixel inside fitting window: 214 356 Nominal wavelengths inside fitting window [nm]: 305.0625 305.2030 305.3435 305.4840 305.6244 305.7649 305.9053 306.0457 306.1861 306.3266 306.4670 306.6074 306.7477 306.8881 307.0285 307.1689 307.3092 307.4496 307.5899 307.7302 307.8706 308.0109 308.1512 308.2915 308.4318 308.5720 308.7123 308.8526 308.9928 309.1331 309.2733 309.4135 309.5537 309.6940 309.8342 309.9743 310.1145 310.2547 310.3949 310.5350 310.6752 310.8153 310.9554 311.0956 311.2357 311.3758 311.5159 311.6560 311.7960 311.9361 312.0762 312.2162 312.3563 312.4963 312.6363 312.7763 312.9163 313.0563 313.1963 313.3363 313.4763 313.6162 313.7562 313.8961 314.0361 314.1760 314.3159 314.4558 314.5957 314.7356 314.8754 315.0153 315.1552 315.2950 315.4349 315.5747 315.7145 315.8543 315.9941 316.1339 316.2737 316.4135 316.5532 316.6930 316.8327 316.9725 317.1122 317.2519 317.3916 317.5313 317.6710 317.8107 317.9503 318.0900 318.2297 318.3693 318.5089 318.6485 318.7882 318.9278 319.0673 319.2069 319.3465 319.4861 319.6256 319.7651 319.9047 320.0442 320.1837 320.3232 320.4627 320.6022 320.7417 320.8811 321.0206 321.1600 321.2995 321.4389 321.5783 321.7177 321.8571 321.9965 322.1358 322.2752 322.4146 322.5539 322.6932 322.8326 322.9719 323.1112 323.2505 323.3897 323.5290 323.6683 323.8075 323.9468 324.0860 324.2252 324.3644 324.5036 324.6428 324.7820 324.9212 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240824T124806.3Z 9002.533406 216 1 47.64 2 81.69 83.01 39.42 230.43 0.00 1 0.00 1 0 25 4.137e-01 3.176e-02 3.380e-01 1.577e-02 7.321939e-01 1.101752e-02 8.659580e-03 -6.000000e+00 3.097834e-01 230.86 -2.00 3.62 -2.00 321.56 0.00e+00 -1.331010e-02 5.905112e-03 2.690742e-03 -6.000000e+00 1.593379e-02 283.31 -2.00 20.00 -2.00 321.00 0.00e+00 6.500 0.005 302.00 328.00 3 3.4387e+00 4.0331e-02 7.9363e-02 -6.0000e+00 7.8045e-01 4.8599e-01 5.1201e-02 6.0673e-02 -6.0000e+00 8.4426e-01 -6.6295e-01 4.0543e-02 2.1952e-02 -6.0000e+00 4.9441e-01 2.5803e-01 1.8423e-02 1.9221e-02 -6.0000e+00 1.9648e-01 1.8667e-05 -4.4972e-03 6.6600e-04 3.9067e-04 -6.0000e+00 1.9539e-02 1.0359e-01 -1.4276e-04 12 8 8 10 0 0 99.99 17.55 0.77 0.10359 0.06979 25 7 1 5 0 1905.020 21.48 15.00 17.55 27.26 13.0 976.85 900000 -42971 900000 -89455 -170185 -72817 -144295 900000 900000 900000 -150944 -39657 50687 81248 38789 -35921 900000 -123118 96481 900000 -19875 -21559 -4483 -14450 900000 -7658 2466 11038 47766 -44781 -27251 75357 112621 -41945 900000 -13887 119592 31358 -655 43818 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-504 -1016 -509 2610 1797 -1793 -3237 -3510 1146 -155 -5277 4291 -3385 -3500 1689 -2060 -2347 -694 -4058 -1110 1932 21 66 356 -1116 -3486 -2280 -4041 1033 1164 2991 5121 -1493 -367 2084 -595 3756 2327 840 -1878 -2737 -140 2189 6576 4337 -2696 658 1087 1762 908 -2603 2191 -714 -3293 2984 -3327 -2027 -2552 429 3613 -915 900000 SS 20240824T130225.5Z 9002.543351 221 1 12.66 2 79.22 85.55 41.30 234.72 0.00 1 0.00 1 0 25 3.523e-01 1.252e-02 2.489e-01 8.317e-03 6.195021e-01 5.471145e-03 7.283077e-03 -6.000000e+00 2.591606e-01 230.86 -2.00 3.62 -2.00 321.00 0.00e+00 6.644246e-05 2.597451e-03 1.756884e-03 -6.000000e+00 1.151234e-02 283.31 -2.00 20.00 -2.00 320.41 0.00e+00 5.149 0.003 302.00 328.00 3 2.9011e+00 1.8365e-02 6.0385e-02 -6.0000e+00 6.4691e-01 9.6278e-02 2.3392e-02 3.7777e-02 -6.0000e+00 6.9546e-01 -1.6588e-01 1.9599e-02 1.7612e-02 -6.0000e+00 4.1343e-01 6.3260e-02 9.1088e-03 5.3883e-03 -6.0000e+00 1.6541e-01 1.2288e-04 -2.7177e-03 3.5344e-04 1.0285e-04 -6.0000e+00 1.6444e-02 1.0354e-01 -1.9990e-04 12 9 9 12 1 1 99.97 17.55 0.47 0.10354 0.08311 12 13 1 5 0 972.650 21.48 14.99 17.55 27.37 13.0 977.94 -176369 56036 -167498 -53009 -103133 -76664 -103885 -121043 -78378 -120094 -78553 -45880 -93661 -246 -51522 -28528 -58648 15061 -22992 -8790 -15331 -13442 -36489 -23587 -81602 -43163 -3357 -15703 -9076 7899 -12746 3212 -11826 -19221 28297 -8589 21490 1270 1274 -7510 5098 -1842 7577 675 -1754 5845 -1124 10245 5141 10631 7819 6246 6368 3121 461 3976 6778 4514 -2813 6888 30749 4489 2385 3778 903 4437 235 775 4653 2357 2869 150 752 3615 -3808 3092 -3141 -3649 110 412 -3136 -394 -1546 -1507 -1010 -1963 -323 728 -973 -574 -1700 -1382 659 -51 4489 -1655 -699 -70 -416 -1192 -462 -1103 -1027 -859 -212 -1495 -236 -243 37 207 -78 -216 892 43 859 642 35 80 548 452 -93 38 -127 806 1440 757 -785 661 312 794 -121 -45 -255 -101 -69 -20 -424 -255 -276 509 -268 -206 900000 -3234 454 -3130 -430 -1059 -650 -1264 -1898 -910 -2316 -1173 -583 -2262 -3 -1168 -584 -1794 244 -568 -198 -384 -347 -1258 -761 -4838 -1838 -100 -545 -312 250 -543 133 -599 -1109 1099 -514 1110 92 106 -754 494 -204 795 78 -212 671 -143 1215 683 1446 1196 1061 1169 617 99 847 1430 982 -666 1558 5791 1158 677 1119 285 1386 79 278 1739 951 1210 66 323 1474 -1580 1145 -1234 -1519 48 201 -1783 -237 -1023 -1070 -758 -1528 -255 573 -784 -447 -1291 -1023 485 -40 3714 -1590 -720 -77 -475 -1364 -505 -1166 -1066 -903 -230 -1745 -285 -316 51 308 -120 -342 1398 66 1320 982 54 125 876 734 -151 61 -199 1220 2111 1105 -1186 1040 523 1411 -233 -90 -538 -224 -158 -48 -1013 -610 -663 1179 -605 -464 900000 SS 20240824T131025.0Z 9002.548901 227 1 47.46 2 77.84 86.97 42.40 236.99 0.00 1 0.00 1 0 25 2.366e-01 5.417e-03 7.940e-02 2.642e-03 5.682358e-01 1.728098e-03 6.630367e-03 -6.000000e+00 1.744454e-01 230.86 -2.00 3.62 -2.00 320.77 0.00e+00 1.156907e-03 7.713499e-04 1.331583e-03 -6.000000e+00 7.730299e-03 283.31 -2.00 20.00 -2.00 320.16 0.00e+00 4.608 0.002 302.00 328.00 3 2.5267e+00 5.6890e-03 5.3913e-02 -6.0000e+00 4.3548e-01 3.1838e-02 7.0866e-03 3.2634e-02 -6.0000e+00 4.6785e-01 -5.9991e-02 5.8257e-03 1.6316e-02 -6.0000e+00 2.7814e-01 1.6530e-02 2.7459e-03 4.6593e-03 -6.0000e+00 1.1155e-01 3.0453e-04 -3.8753e-05 1.1625e-04 1.1050e-04 -6.0000e+00 1.1043e-02 9.8000e-02 1.7292e-04 10 0 0 10 0 0 99.99 17.55 0.25 0.09800 0.09771 127 33 1 5 0 373.630 21.48 15.00 17.55 27.69 13.1 981.10 -102156 -61487 -86013 -73139 -95815 -92866 -71943 -73933 -51536 -72110 -60413 -51646 -15864 -6218 -43516 14637 -7469 -18617 -17205 -1617 -37113 3899 3531 -12881 -12443 -12494 -17224 -16124 -6158 -7789 -6219 -2948 -3685 -7070 -5240 -1364 -840 596 -682 4144 2210 392 3580 -1961 -4152 3162 700 1132 1650 3289 2091 2260 3221 2944 2540 680 1433 184 -1170 2943 1767 2428 1976 1916 1475 2814 456 56 2146 1811 808 457 -576 -405 -2532 -439 -1031 -924 11 -224 -770 -1352 -1319 -600 -948 -405 -279 311 -477 1153 -421 -247 498 434 418 617 -50 -265 -235 -486 -360 -354 -690 -260 86 -516 -469 -370 -267 173 8 196 418 233 184 422 259 134 163 -91 -199 -464 -154 342 866 208 270 354 120 346 124 -273 -130 67 -21 -254 -151 -268 -22 64 47 53 900000 -1124 -490 -906 -685 -1144 -1131 -775 -900 -555 -1064 -905 -834 -215 -92 -1090 233 -164 -497 -483 -41 -1399 102 98 -449 -455 -471 -694 -661 -241 -337 -296 -150 -204 -429 -330 -90 -63 51 -68 446 266 51 473 -282 -624 452 106 177 272 575 369 434 661 644 585 165 351 46 -301 749 481 707 620 634 505 969 166 22 880 801 380 219 -274 -184 -1110 -180 -422 -396 5 -118 -456 -889 -942 -456 -769 -342 -243 271 -413 951 -339 -193 390 359 379 619 -51 -292 -267 -548 -391 -370 -712 -271 93 -596 -576 -488 -380 262 12 319 672 367 283 642 400 212 265 -151 -329 -752 -242 518 1271 304 400 550 201 626 223 -524 -265 143 -47 -591 -357 -638 -51 146 104 116 900000 SS 20240824T131541.2Z 9002.552560 230 1 47.59 2 76.93 87.91 43.13 238.45 0.00 1 0.00 1 0 25 1.943e-01 5.343e-03 4.133e-02 1.808e-03 5.340710e-01 1.167588e-03 6.275029e-03 -6.000000e+00 1.432807e-01 230.86 -2.00 3.62 -2.00 320.47 0.00e+00 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