File name: Pandora199s1_Fukuoka_20241204_L2Fit_fwvt1c70d20230726p1-8.txt File generation date: 20241204T152253.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c70p1-8 Local principal investigator: Hisahiro Takashima Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 199 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora199_OF_v3d20210122.txt Instrument calibration file used: Pandora199s1_CF_v70d20230726.txt Level 1 file used: Pandora199s1_Fukuoka_20241204_L1_smca1c70d20230726p1-8.txt Full location name: Fukuoka University Short location name: Fukuoka Country of location: Japan Location latitude [deg]: 33.5491 Location longitude [deg]: 130.3660 Location altitude [m]: 55 Local noon date: 20241204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial fieldcal after fiber replacement based on Session 7 First and last pixel inside fitting window: 1609 1758 Nominal wavelengths inside fitting window [nm]: 492.0478 492.1693 492.2908 492.4123 492.5338 492.6552 492.7767 492.8981 493.0195 493.1409 493.2622 493.3836 493.5049 493.6262 493.7475 493.8688 493.9901 494.1113 494.2326 494.3538 494.4750 494.5962 494.7173 494.8385 494.9596 495.0807 495.2018 495.3229 495.4440 495.5650 495.6861 495.8071 495.9281 496.0490 496.1700 496.2910 496.4119 496.5328 496.6537 496.7746 496.8954 497.0163 497.1371 497.2579 497.3787 497.4995 497.6202 497.7410 497.8617 497.9824 498.1031 498.2238 498.3444 498.4651 498.5857 498.7063 498.8269 498.9475 499.0680 499.1886 499.3091 499.4296 499.5501 499.6705 499.7910 499.9114 500.0318 500.1522 500.2726 500.3930 500.5133 500.6337 500.7540 500.8743 500.9946 501.1148 501.2351 501.3553 501.4755 501.5957 501.7159 501.8361 501.9562 502.0763 502.1964 502.3165 502.4366 502.5567 502.6767 502.7967 502.9167 503.0367 503.1567 503.2767 503.3966 503.5165 503.6364 503.7563 503.8762 503.9960 504.1159 504.2357 504.3555 504.4753 504.5950 504.7148 504.8345 504.9542 505.0739 505.1936 505.3132 505.4329 505.5525 505.6721 505.7917 505.9113 506.0309 506.1504 506.2699 506.3894 506.5089 506.6284 506.7478 506.8673 506.9867 507.1061 507.2255 507.3448 507.4642 507.5835 507.7028 507.8221 507.9414 508.0607 508.1799 508.2991 508.4184 508.5375 508.6567 508.7759 508.8950 509.0141 509.1332 509.2523 509.3714 509.4905 509.6095 509.7285 509.8475 509.9665 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241203T221500.0Z 9103.927084 29 1 16.89 2 89.39 117.49 119.77 105.68 0.00 1 0.00 1 0 22 1.306e-02 1.290e-02 1.275e-03 1.265e-03 1.113885e+04 8.950764e+01 6.748642e+02 -6.000000e+00 7.702898e+02 284.03 -2.00 20.00 -2.00 505.46 0.00e+00 6.219418e-03 3.636311e-05 3.453478e-04 -6.000000e+00 3.763926e-04 284.03 -2.00 20.00 -2.00 501.32 0.00e+00 8.762407e-01 2.458163e-02 1.090059e-01 -6.000000e+00 2.638422e-01 224.21 -2.00 3.34 -2.00 502.76 0.00e+00 19.518 0.109 489.00 513.00 1 4.7055e+00 1.8908e-03 3.4154e-02 -6.0000e+00 2.0334e-02 -4.9896e-02 4.6127e-04 2.8000e-03 -6.0000e+00 5.1445e-03 9.4084e-04 2.8337e-03 1.4194e-04 1.5432e-04 -6.0000e+00 1.5482e-03 4.8808e-03 -1.4468e-05 12 9 9 12 1 1 43.86 17.69 6.48 0.00488 0.02454 11 9 1 4 0 1406.890 21.06 15.00 17.69 14.96 15.8 907.70 -3153 -2258 -1317 120 509 1759 1746 2445 1966 1169 462 -21 -851 -1106 -1479 -1426 -693 -115 569 734 888 877 1300 1184 1635 1020 1076 118 -1039 -1784 -2377 -2292 -881 230 552 947 315 177 -50 26 -49 584 931 1506 1978 1936 1617 1236 426 -691 -1400 -2258 -2400 -1871 -657 284 836 842 1248 1118 1451 1120 1646 1065 728 480 -40 -570 -1127 -1461 -1600 -1309 -1028 -540 -704 -1034 -1694 -1852 -2078 -1952 -1862 -1599 -1217 -1135 -950 -907 -676 -753 -423 -274 339 567 1230 1071 1021 147 -218 -886 -1809 -2224 -2549 -1922 -1041 -164 26 -97 -871 -891 -652 -396 198 1257 1726 2212 2333 2675 2578 2340 1661 975 1024 549 1194 970 1488 1141 843 591 937 395 107 -675 -1329 -1475 -954 -564 -463 152 461 668 727 786 573 693 478 -176 -737 -1804 -2041 -1954 -2609 -1886 -1125 105 455 1591 1607 2253 1818 1080 424 -19 -772 -998 -1337 -1298 -636 -107 512 667 812 806 1196 1100 1523 959 1009 110 -964 -1633 -2167 -2106 -819 217 532 918 307 172 -49 25 -48 576 931 1449 1916 1886 1576 1198 409 -659 -1384 -2221 -2364 -1775 -633 279 834 849 1262 1138 1479 1154 1693 1101 749 490 -40 -574 -1132 -1462 -1599 -1310 -1037 -547 -717 -1049 -1706 -1849 -2067 -1938 -1852 -1597 -1222 -1150 -968 -928 -691 -769 -430 -280 348 561 1216 1055 1035 146 -213 -852 -1730 -2119 -2453 -1885 -1050 -162 26 -98 -889 -910 -669 -411 208 1327 1837 2367 2519 2785 2711 2477 1763 1030 1068 571 1235 1012 1557 1204 895 631 997 421 113 -715 -1407 -1569 -1022 -612 -511 170 521 730 802 872 640 773 532 -196 -810 -1982 -2240 -2162 SQ 20241203T221758.1Z 9103.929145 33 1 47.84 2 88.85 117.91 119.21 105.99 0.00 1 0.00 1 0 22 1.035e-02 1.026e-02 4.180e-04 4.145e-04 1.044145e+04 2.924607e+01 6.516556e+02 -6.000000e+00 6.107858e+02 284.03 -2.00 20.00 -2.00 505.48 0.00e+00 5.390684e-03 1.184661e-05 2.994452e-04 -6.000000e+00 2.984441e-04 284.03 -2.00 20.00 -2.00 501.32 0.00e+00 9.256375e-01 8.061619e-03 9.796971e-02 -6.000000e+00 2.091833e-01 224.21 -2.00 3.34 -2.00 502.77 0.00e+00 18.284 0.089 489.00 513.00 1 3.6450e+00 6.2071e-04 3.0988e-02 -6.0000e+00 1.6122e-02 -4.9635e-02 1.5043e-04 2.5841e-03 -6.0000e+00 4.0782e-03 3.2649e-03 2.5429e-03 4.6771e-05 1.3429e-04 -6.0000e+00 1.2276e-03 4.1025e-03 -2.8304e-06 12 8 8 10 0 0 84.76 17.69 4.98 0.00410 0.02174 116 30 1 4 0 411.970 21.06 14.99 17.69 14.99 15.8 907.79 -2229 -1677 -860 -43 810 1463 1765 1818 1449 1123 401 -64 -703 -888 -1201 -1093 -632 115 458 701 741 772 1020 1093 1167 929 713 66 -621 -1383 -1807 -1676 -721 -29 465 385 283 22 -238 -125 -74 286 692 1217 1462 1468 1220 844 153 -434 -1224 -1800 -1988 -1410 -690 36 491 679 744 878 1030 1073 1109 996 786 311 -129 -542 -847 -1075 -1184 -1171 -696 -428 -463 -858 -1297 -1526 -1619 -1421 -1463 -1383 -1195 -797 -820 -705 -732 -495 -464 -192 245 687 1030 1118 817 270 -158 -850 -1546 -2012 -2021 -1579 -658 -117 -51 -390 -785 -800 -546 -264 175 842 1364 1610 1853 2122 2072 1846 1444 1062 659 646 810 894 1035 905 611 690 673 365 124 -487 -1023 -1145 -670 -475 -181 141 417 512 563 666 640 558 370 -91 -786 -1298 -1660 -1482 -1914 -1459 -720 -37 711 1306 1599 1660 1327 1022 363 -58 -628 -788 -1068 -977 -572 105 428 662 704 737 977 1054 1133 906 694 64 -594 -1306 -1695 -1584 -692 -27 438 366 269 21 -225 -119 -71 275 674 1198 1452 1464 1216 836 151 -420 -1169 -1705 -1886 -1352 -674 36 499 695 766 907 1068 1119 1099 987 775 321 -132 -552 -857 -1083 -1191 -1183 -707 -438 -450 -877 -1315 -1534 -1620 -1419 -1465 -1392 -1213 -771 -800 -690 -718 -484 -454 -188 241 683 1026 1107 797 258 -156 -829 -1494 -1940 -1963 -1483 -635 -116 -52 -399 -804 -819 -561 -274 185 894 1458 1734 1911 2205 2174 1948 1523 1112 684 666 833 925 1077 948 644 728 710 385 130 -509 -1067 -1200 -707 -509 -197 155 465 578 642 763 737 644 425 -104 -892 -1463 -1871 -1682 SQ 20241203T222104.2Z 9103.931298 37 1 29.71 2 88.28 118.34 118.61 106.30 0.00 1 0.00 1 0 22 8.745e-03 8.673e-03 8.929e-04 8.872e-04 9.048579e+03 6.173357e+01 5.650130e+02 -6.000000e+00 5.159030e+02 284.03 -2.00 20.00 -2.00 505.44 0.00e+00 4.709109e-03 2.537621e-05 2.628606e-04 -6.000000e+00 2.520707e-04 284.03 -2.00 20.00 -2.00 501.22 0.00e+00 9.789406e-01 1.731153e-02 8.594984e-02 -6.000000e+00 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