File name: Pandora199s1_Fukuoka_20241213_L2Fit_fwvt1c70d20230726p1-8.txt File generation date: 20241214T000637.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c70p1-8 Local principal investigator: Hisahiro Takashima Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 199 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora199_OF_v3d20210122.txt Instrument calibration file used: Pandora199s1_CF_v70d20230726.txt Level 1 file used: Pandora199s1_Fukuoka_20241213_L1_smca1c70d20230726p1-8.txt Full location name: Fukuoka University Short location name: Fukuoka Country of location: Japan Location latitude [deg]: 33.5491 Location longitude [deg]: 130.3660 Location altitude [m]: 55 Local noon date: 20241213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial fieldcal after fiber replacement based on Session 7 First and last pixel inside fitting window: 1609 1758 Nominal wavelengths inside fitting window [nm]: 492.0478 492.1693 492.2908 492.4123 492.5338 492.6552 492.7767 492.8981 493.0195 493.1409 493.2622 493.3836 493.5049 493.6262 493.7475 493.8688 493.9901 494.1113 494.2326 494.3538 494.4750 494.5962 494.7173 494.8385 494.9596 495.0807 495.2018 495.3229 495.4440 495.5650 495.6861 495.8071 495.9281 496.0490 496.1700 496.2910 496.4119 496.5328 496.6537 496.7746 496.8954 497.0163 497.1371 497.2579 497.3787 497.4995 497.6202 497.7410 497.8617 497.9824 498.1031 498.2238 498.3444 498.4651 498.5857 498.7063 498.8269 498.9475 499.0680 499.1886 499.3091 499.4296 499.5501 499.6705 499.7910 499.9114 500.0318 500.1522 500.2726 500.3930 500.5133 500.6337 500.7540 500.8743 500.9946 501.1148 501.2351 501.3553 501.4755 501.5957 501.7159 501.8361 501.9562 502.0763 502.1964 502.3165 502.4366 502.5567 502.6767 502.7967 502.9167 503.0367 503.1567 503.2767 503.3966 503.5165 503.6364 503.7563 503.8762 503.9960 504.1159 504.2357 504.3555 504.4753 504.5950 504.7148 504.8345 504.9542 505.0739 505.1936 505.3132 505.4329 505.5525 505.6721 505.7917 505.9113 506.0309 506.1504 506.2699 506.3894 506.5089 506.6284 506.7478 506.8673 506.9867 507.1061 507.2255 507.3448 507.4642 507.5835 507.7028 507.8221 507.9414 508.0607 508.1799 508.2991 508.4184 508.5375 508.6567 508.7759 508.8950 509.0141 509.1332 509.2523 509.3714 509.4905 509.6095 509.7285 509.8475 509.9665 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241212T222417.9Z 9112.933541 184 1 32.84 2 88.96 118.95 116.43 322.00 0.00 1 0.00 1 0 29 1.365e-02 1.349e-02 1.420e-03 1.408e-03 5.904883e+03 9.271285e+01 3.185479e+02 -6.000000e+00 8.025365e+02 283.20 -2.00 20.00 -2.00 505.46 0.00e+00 3.899012e-03 4.041167e-05 2.113488e-04 -6.000000e+00 3.926185e-04 283.20 -2.00 20.00 -2.00 501.34 0.00e+00 8.869782e-01 2.735039e-02 7.322786e-02 -6.000000e+00 2.758681e-01 224.02 -2.00 3.34 -2.00 502.80 0.00e+00 18.576 0.094 489.00 513.00 1 5.5024e+00 2.1054e-03 3.0720e-02 -6.0000e+00 2.1255e-02 -3.9856e-02 5.1543e-04 2.1184e-03 -6.0000e+00 5.3790e-03 5.0501e-04 4.3626e-03 1.6313e-04 8.9351e-05 -6.0000e+00 1.6178e-03 -3.3306e-02 1.6975e-04 12 9 9 12 1 1 23.18 16.98 8.09 -0.03331 -0.00305 11 4 1 4 0 2735.590 20.35 14.97 16.98 8.19 15.5 862.79 -3548 -2729 -1665 -483 267 1939 1689 2089 1681 874 405 -79 -1141 -1194 -1549 -1238 -490 294 634 835 1098 856 1402 1182 1500 1124 939 -274 -1012 -1635 -2294 -2184 -578 357 947 769 512 399 -402 223 -32 809 1244 1780 2427 2298 1712 1090 266 -757 -1201 -2648 -2372 -1801 -774 252 1155 922 1140 1236 1460 1384 1800 1358 1126 818 -205 -408 -1414 -1154 -1444 -1141 -1001 -280 -918 -1209 -2035 -2104 -2231 -2117 -1940 -1677 -1312 -1036 -938 -762 -590 -722 -879 -369 540 588 1031 1147 1156 80 -567 -1115 -1847 -2033 -2347 -1757 -778 -61 158 -97 -986 -1131 -841 -240 299 1189 1862 2392 2662 2972 2666 2244 1805 1140 708 594 1161 1144 1454 922 677 455 742 270 54 -802 -1524 -1440 -872 -522 -257 184 372 706 369 915 583 665 397 -213 -1171 -1963 -2217 -2023 -3051 -2372 -1477 -438 231 1696 1507 1872 1511 785 361 -70 -1008 -1049 -1363 -1094 -437 267 585 779 1028 807 1322 1126 1432 1079 899 -263 -956 -1524 -2131 -2046 -547 345 928 761 507 393 -397 219 -32 805 1177 1698 2325 2211 1650 1045 253 -713 -1182 -2605 -2327 -1681 -735 244 1128 911 1131 1230 1456 1390 1807 1367 1127 812 -203 -401 -1390 -1124 -1408 -1115 -988 -277 -918 -1202 -2015 -2064 -2183 -2071 -1902 -1653 -1302 -1036 -945 -771 -598 -733 -896 -377 554 610 1073 1189 1183 81 -566 -1098 -1804 -1974 -2303 -1756 -796 -64 158 -98 -995 -1141 -851 -245 309 1236 1949 2517 2820 3166 2865 2424 1945 1222 754 630 1227 1217 1552 993 732 494 803 292 58 -863 -1639 -1551 -945 -573 -286 208 403 771 407 1012 651 742 442 -237 -1291 -2153 -2428 -2231 SQ 20241212T222724.9Z 9112.935705 188 1 46.48 2 88.39 119.39 116.80 322.66 0.00 1 0.00 1 0 29 9.809e-03 9.696e-03 5.107e-04 5.074e-04 6.585573e+03 3.408222e+01 4.007488e+02 -6.000000e+00 5.768506e+02 283.20 -2.00 20.00 -2.00 505.46 0.00e+00 3.707489e-03 1.451315e-05 2.065193e-04 -6.000000e+00 2.821955e-04 283.20 -2.00 20.00 -2.00 501.25 0.00e+00 9.430409e-01 9.867001e-03 6.919213e-02 -6.000000e+00 1.982792e-01 224.02 -2.00 3.34 -2.00 502.72 0.00e+00 17.115 0.073 489.00 513.00 1 4.2165e+00 7.5632e-04 2.7629e-02 -6.0000e+00 1.5277e-02 -4.5604e-02 1.8645e-04 1.9973e-03 -6.0000e+00 3.8661e-03 2.2405e-03 2.7777e-03 5.8224e-05 9.0619e-05 -6.0000e+00 1.1629e-03 -7.1171e-03 4.1479e-05 12 9 9 12 1 1 36.82 16.98 5.11 -0.00712 0.01215 65 17 1 4 0 704.040 20.35 15.02 16.98 8.33 15.5 863.68 -2304 -1727 -890 -134 594 1267 1429 1550 1465 962 392 -220 -701 -1013 -1092 -1046 -435 -38 503 699 701 739 978 951 1106 1046 631 19 -694 -1335 -1729 -1512 -598 209 405 381 305 46 -139 -133 45 362 791 1185 1434 1356 1166 753 175 -564 -1146 -1795 -1873 -1455 -602 48 466 578 658 888 926 1033 1138 1008 674 476 -153 -440 -939 -972 -1124 -1092 -704 -388 -350 -760 -1203 -1530 -1466 -1457 -1403 -1413 -1031 -868 -709 -716 -587 -565 -423 -307 160 633 907 971 758 258 -280 -806 -1429 -1789 -1917 -1360 -636 -91 -81 -258 -654 -797 -567 -226 218 768 1273 1535 1791 1941 1962 1698 1453 898 532 542 767 767 975 835 641 557 602 346 -39 -509 -1049 -1052 -685 -395 -170 159 300 443 465 695 538 531 386 -162 -763 -1339 -1560 -1438 -1933 -1465 -772 -120 540 1174 1344 1470 1390 910 368 -205 -650 -935 -1007 -971 -408 -35 461 648 655 693 920 901 1053 998 603 18 -650 -1233 -1586 -1395 -560 200 396 375 300 45 -136 -130 44 358 790 1196 1458 1385 1189 762 175 -558 -1115 -1732 -1805 -1418 -598 46 455 570 652 881 922 1033 1141 1010 673 471 -151 -429 -912 -938 -1083 -1057 -686 -381 -345 -746 -1171 -1479 -1409 -1401 -1354 -1373 -1008 -857 -705 -716 -589 -566 -424 -310 163 648 933 995 767 257 -274 -778 -1366 -1703 -1840 -1329 -638 -94 -85 -271 -688 -838 -567 -228 223 793 1326 1612 1892 2066 2102 1826 1558 956 562 569 805 810 1034 890 686 597 645 370 -41 -540 -1110 -1115 -732 -428 -187 178 323 482 510 766 597 590 428 -179 -834 -1452 -1687 -1566 SQ 20241212T223036.1Z 9112.937917 192 1 47.92 2 87.82 119.84 117.17 323.34 0.00 1 0.00 1 0 22 8.184e-03 8.117e-03 3.999e-04 3.974e-04 6.031348e+03 2.636297e+01 3.739910e+02 -6.000000e+00 4.812846e+02 283.20 -2.00 20.00 -2.00 505.45 0.00e+00 3.734637e-03 1.135148e-05 2.087868e-04 -6.000000e+00 2.354260e-04 283.20 -2.00 20.00 -2.00 501.23 0.00e+00 9.530231e-01 7.755918e-03 6.426169e-02 -6.000000e+00 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