File name: Pandora199s1_Fukuoka_20250612_L2Fit_fout2c70d20230726p1-8.txt File generation date: 20250612T153140.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c70p1-8 Local principal investigator: Hisahiro Takashima Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 199 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora199_OF_v3d20210122.txt Instrument calibration file used: Pandora199s1_CF_v70d20230726.txt Level 1 file used: Pandora199s1_Fukuoka_20250612_L1_smca1c70d20230726p1-8.txt Full location name: Fukuoka University Short location name: Fukuoka Country of location: Japan Location latitude [deg]: 33.5491 Location longitude [deg]: 130.3660 Location altitude [m]: 55 Local noon date: 20250612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial fieldcal after fiber replacement based on Session 7 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1265 305.2675 305.4085 305.5495 305.6905 305.8315 305.9725 306.1135 306.2544 306.3954 306.5363 306.6772 306.8181 306.9591 307.0999 307.2408 307.3817 307.5226 307.6634 307.8042 307.9451 308.0859 308.2267 308.3675 308.5083 308.6490 308.7898 308.9306 309.0713 309.2120 309.3528 309.4935 309.6342 309.7748 309.9155 310.0562 310.1968 310.3375 310.4781 310.6187 310.7593 310.8999 311.0405 311.1811 311.3217 311.4622 311.6028 311.7433 311.8838 312.0243 312.1648 312.3053 312.4458 312.5863 312.7267 312.8672 313.0076 313.1480 313.2884 313.4288 313.5692 313.7096 313.8500 313.9903 314.1307 314.2710 314.4113 314.5517 314.6920 314.8323 314.9725 315.1128 315.2531 315.3933 315.5335 315.6738 315.8140 315.9542 316.0944 316.2346 316.3747 316.5149 316.6550 316.7952 316.9353 317.0754 317.2155 317.3556 317.4957 317.6358 317.7758 317.9159 318.0559 318.1959 318.3359 318.4759 318.6159 318.7559 318.8959 319.0358 319.1758 319.3157 319.4556 319.5956 319.7355 319.8754 320.0152 320.1551 320.2950 320.4348 320.5746 320.7145 320.8543 320.9941 321.1339 321.2736 321.4134 321.5532 321.6929 321.8327 321.9724 322.1121 322.2518 322.3915 322.5312 322.6708 322.8105 322.9501 323.0898 323.2294 323.3690 323.5086 323.6482 323.7878 323.9273 324.0669 324.2064 324.3459 324.4855 324.6250 324.7645 324.9040 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250612T015138.8Z 9294.077532 382 1 7.74 2 21.67 113.02 153.41 272.56 0.00 1 0.00 1 0 17 1.101e-02 8.816e-03 3.063e-03 2.183e-03 1.423150e-01 1.178387e-03 1.613832e-03 -6.000000e+00 6.657472e-03 232.13 -2.00 3.34 -2.00 314.75 0.00e+00 4.974602e-04 9.908497e-05 7.828083e-05 -6.000000e+00 2.997409e-04 290.23 -2.00 20.00 -2.00 314.08 0.00e+00 1.076 0.000 302.00 328.00 3 4.8198e+00 3.0377e-03 1.2810e-02 -6.0000e+00 1.6662e-02 2.9771e-02 3.3481e-03 6.9775e-03 -6.0000e+00 1.7963e-02 -4.5999e-03 1.9143e-03 3.3532e-03 -6.0000e+00 1.0711e-02 -4.5492e-03 8.3712e-04 9.1920e-04 -6.0000e+00 4.5397e-03 1.3137e-03 -1.2896e-04 6.6957e-05 1.3614e-05 -6.0000e+00 3.3037e-04 4.6042e-03 0.0000e+00 12 9 1 12 1 1 99.27 18.26 0.86 0.00460 0.00364 6 11 1 5 0 1104.700 21.69 15.00 18.26 28.16 19.0 1049.35 775 673 -1276 -1423 -2952 -1629 -1029 268 -84 -2588 -1478 -1399 259 394 1255 -380 1419 1439 1313 1245 1122 1625 1676 447 1444 660 79 -695 -741 463 573 1148 -982 -2067 -4105 -2662 -2567 -683 -289 -531 -451 -252 147 -425 113 -589 -651 -1249 -278 -315 1184 861 1048 1036 623 734 700 -31 367 441 1160 1782 1705 1110 -253 -463 -1086 -270 451 1588 1085 1129 649 385 -589 -1534 -2442 -2371 -2022 -1802 -1598 -1873 -1404 -1029 -506 2 914 857 756 731 281 -549 -909 143 -354 536 693 784 566 -175 -1374 -992 -944 -353 -920 -615 -746 -52 754 964 942 616 360 -427 -249 -771 292 19 645 412 821 688 752 619 588 -381 -265 -639 -187 -398 -673 -665 -155 -114 -54 233 636 396 116 98 -486 -796 284 254 -473 -480 -923 -545 -334 94 -32 -1001 -558 -546 109 183 626 -201 748 774 663 642 579 908 876 246 812 375 43 -389 -390 238 305 638 -572 -1181 -2288 -1502 -1488 -456 -206 -422 -378 -217 128 -370 97 -498 -530 -983 -211 -241 935 716 906 920 565 673 643 -29 331 405 1109 1679 1693 1117 -243 -437 -965 -240 436 1548 1128 1196 678 383 -584 -1380 -2033 -2102 -1766 -1740 -1568 -1976 -1551 -1199 -587 3 1157 1100 951 867 327 -582 -900 151 -373 613 808 974 711 -212 -1564 -1141 -1094 -405 -1135 -794 -1004 -68 1018 1352 1339 852 465 -543 -293 -946 363 23 855 537 1079 888 997 781 704 -468 -317 -790 -226 -505 -875 -876 -209 -160 -75 335 934 591 172 142 -686 -1101 SS 20250612T020949.8Z 9294.090159 392 1 46.73 2 18.28 120.21 157.00 275.53 0.00 1 0.00 1 0 33 1.288e-02 1.001e-02 4.644e-03 2.679e-03 1.451353e-01 1.422654e-03 1.631657e-03 -6.000000e+00 7.783034e-03 232.13 -2.00 3.34 -2.00 315.72 0.00e+00 7.363823e-04 1.448616e-04 1.593834e-04 -6.000000e+00 3.504226e-04 290.23 -2.00 20.00 -2.00 314.95 0.00e+00 1.053 0.000 302.00 328.00 3 6.2485e+00 3.7027e-03 1.2676e-02 -6.0000e+00 1.9479e-02 4.7229e-02 4.1116e-03 7.0471e-03 -6.0000e+00 2.1000e-02 -8.4039e-03 2.3514e-03 3.3828e-03 -6.0000e+00 1.2523e-02 -3.7117e-03 1.0542e-03 9.3486e-04 -6.0000e+00 5.3072e-03 3.1793e-04 -1.8800e-05 8.1920e-05 1.2702e-05 -6.0000e+00 3.8623e-04 4.6948e-03 0.0000e+00 12 9 9 12 1 1 99.99 18.26 0.89 0.00469 0.00455 15 4 1 5 0 2920.090 21.69 15.00 18.26 28.38 19.0 1052.05 2020 1249 -231 -1781 -1141 -3126 -276 13 -2273 -2495 -2456 -2118 -256 322 405 622 1211 2721 691 1662 3 2459 1838 1867 317 -755 -639 -1077 566 -507 -218 -726 -367 -3231 -2963 -3780 -2311 -1380 863 -461 376 -142 410 -182 -13 221 -894 -980 -742 -119 34 885 1137 1382 626 1411 466 131 -208 -60 872 2213 2290 1040 27 -1501 -1651 -857 902 1266 1493 1532 1022 325 -558 -2003 -2881 -3149 -2584 -2155 -1329 -1918 -1258 -927 -188 646 1040 1362 822 1042 98 -1080 -1687 -1016 -678 -132 757 771 547 20 -991 -1655 -1172 -441 -944 -211 -408 -29 774 1309 1482 835 410 -373 -568 -748 -488 360 391 747 886 729 554 723 -143 -380 -472 -381 -686 -505 -974 -720 -18 -169 69 220 746 755 576 157 -270 -1200 537 345 -62 -443 -257 -707 -65 3 -638 -704 -683 -609 -79 110 149 239 470 1061 281 682 1 998 766 807 144 -346 -308 -486 236 -211 -94 -331 -171 -1504 -1314 -1736 -1173 -815 579 -316 270 -105 306 -136 -10 160 -692 -729 -537 -86 26 699 931 1160 537 1216 406 113 -179 -52 791 2116 2094 970 27 -1354 -1395 -725 820 1262 1574 1494 1082 329 -522 -1705 -2271 -2450 -2142 -1971 -1322 -2058 -1409 -996 -214 778 1300 1716 1019 1213 115 -1164 -1704 -1022 -727 -154 957 945 678 24 -1218 -1938 -1377 -548 -1261 -266 -538 -39 1097 1920 2196 1208 555 -513 -723 -927 -619 481 561 1018 1217 983 721 983 -186 -469 -569 -473 -900 -693 -1371 -1023 -26 -256 100 331 1142 1171 888 237 -396 -1911 SS 20250612T021454.6Z 9294.093688 395 1 7.67 2 17.38 122.62 158.00 276.46 0.00 1 0.00 1 0 17 1.079e-02 8.790e-03 2.708e-03 1.943e-03 1.382772e-01 1.045350e-03 1.572975e-03 -6.000000e+00 6.521560e-03 232.13 -2.00 3.34 -2.00 314.72 0.00e+00 5.076120e-04 8.742671e-05 6.698750e-05 -6.000000e+00 2.936470e-04 290.23 -2.00 20.00 -2.00 314.05 0.00e+00 1.048 0.000 302.00 328.00 3 4.6536e+00 2.6938e-03 1.2477e-02 -6.0000e+00 1.6322e-02 2.5140e-02 2.9711e-03 6.8071e-03 -6.0000e+00 1.7597e-02 -6.4226e-03 1.6987e-03 3.2697e-03 -6.0000e+00 1.0493e-02 -4.3360e-03 7.4128e-04 9.0011e-04 -6.0000e+00 4.4467e-03 1.6131e-03 -2.3177e-04 5.9234e-05 1.3278e-05 -6.0000e+00 3.2365e-04 5.1935e-03 0.0000e+00 12 9 1 12 1 1 98.77 18.26 0.87 0.00519 0.00345 8 14 1 5 0 851.430 21.69 15.00 18.26 28.54 19.1 1053.90 577 -603 -387 -2819 -1604 -1032 -431 -258 -309 -2142 -1852 -1529 106 339 1786 446 1282 942 1653 1496 445 1627 1184 2017 1089 1109 6 -669 -659 -270 -2 818 -482 -2631 -3259 -3184 -2316 -1038 -390 -531 -189 -373 -92 -550 -100 -302 -719 -561 -342 65 475 499 1210 1462 666 1216 355 253 84 715 938 2222 1698 1277 174 -533 -801 -310 500 1263 664 493 788 477 -520 -1437 -2298 -2446 -1642 -1587 -1890 -2195 -1429 -1417 -239 163 757 822 933 533 149 -451 -909 -579 -487 808 726 1246 500 -136 -1084 -1316 -661 -637 -820 -644 -296 -127 830 972 954 483 203 -226 -303 -543 -146 137 552 213 862 856 757 378 230 -174 -217 -295 -39 -527 -811 -414 -421 119 368 154 643 368 256 -89 -548 -1063 218 -237 -146 -990 -507 -320 -142 -94 -119 -844 -716 -610 45 160 901 237 688 474 844 780 235 844 630 1106 622 634 3 -379 -351 -141 -1 459 -282 -1522 -1812 -1816 -1346 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