File name: Pandora238s1_Granada_20230215_L2Fit_fout2c4d20221202p1-8.txt File generation date: 20241022T132145.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Perez Ramirez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora238_OF_v1d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20230215_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20230215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2378 305.3788 305.5198 305.6608 305.8018 305.9428 306.0838 306.2247 306.3657 306.5066 306.6475 306.7884 306.9293 307.0702 307.2110 307.3519 307.4927 307.6335 307.7743 307.9151 308.0559 308.1967 308.3375 308.4782 308.6189 308.7597 308.9004 309.0411 309.1818 309.3224 309.4631 309.6037 309.7444 309.8850 310.0256 310.1662 310.3068 310.4473 310.5879 310.7284 310.8689 311.0095 311.1500 311.2905 311.4309 311.5714 311.7118 311.8523 311.9927 312.1331 312.2735 312.4139 312.5543 312.6947 312.8350 312.9753 313.1157 313.2560 313.3963 313.5366 313.6768 313.8171 313.9573 314.0976 314.2378 314.3780 314.5182 314.6584 314.7986 314.9387 315.0789 315.2190 315.3591 315.4992 315.6393 315.7794 315.9195 316.0595 316.1996 316.3396 316.4796 316.6196 316.7596 316.8996 317.0396 317.1796 317.3195 317.4594 317.5993 317.7393 317.8792 318.0190 318.1589 318.2988 318.4386 318.5784 318.7183 318.8581 318.9979 319.1376 319.2774 319.4172 319.5569 319.6966 319.8364 319.9761 320.1158 320.2554 320.3951 320.5348 320.6744 320.8140 320.9536 321.0933 321.2328 321.3724 321.5120 321.6516 321.7911 321.9306 322.0701 322.2097 322.3491 322.4886 322.6281 322.7676 322.9070 323.0464 323.1858 323.3253 323.4646 323.6040 323.7434 323.8828 324.0221 324.1614 324.3008 324.4401 324.5794 324.7186 324.8579 324.9972 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230215T084942.7Z 8446.367855 255 1 54.53 2 71.57 122.93 66.35 197.05 0.00 1 0.00 1 0 17 2.375e-01 1.926e-02 2.173e-01 1.445e-02 4.422017e-01 7.042536e-03 5.180648e-03 -6.000000e+00 1.276686e-01 224.81 -2.00 3.42 -2.00 319.48 0.00e+00 3.002927e-03 1.850427e-03 4.769087e-04 -6.000000e+00 5.495682e-03 274.45 -2.00 20.00 -2.00 318.97 0.00e+00 3.124 0.000 302.00 328.00 3 5.8321e+00 1.9381e-02 3.6247e-02 -6.0000e+00 3.1670e-01 2.0102e-01 2.2731e-02 2.2089e-02 -6.0000e+00 3.4461e-01 -1.7743e-01 1.8773e-02 1.1588e-02 -6.0000e+00 2.0451e-01 7.6993e-02 1.0130e-02 4.3261e-03 -6.0000e+00 9.0163e-02 4.7246e-05 -1.3493e-03 3.4033e-04 3.0567e-05 -6.0000e+00 5.0347e-03 6.4044e-03 -1.2824e-04 12 9 8 11 8 0 99.88 20.09 0.73 0.00640 -0.00374 15 2 1 5 0 3635.038 24.25 15.00 20.09 16.28 4.1 905.98 -35755 69264 -47854 -95661 -79895 39822 94473 -66546 10176 -21086 91970 -45641 55920 -37231 91792 16948 40603 32654 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-1177 -1238 1 -2458 -1610 2891 762 -1713 -578 -869 -533 -1529 -1174 -5148 580 945 -3239 71 -40 1877 141 333 2083 -1933 -2077 2616 242 -1360 -727 435 -190 -2669 1660 2 -324 -119 -3274 436 -2550 -1483 -805 183 2580 2044 1956 1144 -1062 1202 -2799 -769 -370 1942 551 1649 -1224 1586 2423 -667 -1557 1568 560 -381 3223 -637 439 2211 -1318 807 1104 -1410 -2055 -2132 -1541 1336 900000 SS 20230215T091113.5Z 8446.382795 265 1 33.78 2 68.06 127.09 67.76 201.87 0.00 1 0.00 1 0 17 2.360e-02 6.162e-03 2.097e-02 2.746e-03 3.801531e-01 1.331987e-03 4.470156e-03 -6.000000e+00 1.269657e-02 224.81 -2.00 3.42 -2.00 318.40 0.00e+00 5.529245e-04 2.593073e-04 1.682955e-04 -6.000000e+00 5.462604e-04 274.45 -2.00 20.00 -2.00 317.87 0.00e+00 2.653 0.000 302.00 328.00 3 3.6542e+00 3.5606e-03 3.0935e-02 -6.0000e+00 3.1496e-02 7.1594e-02 4.0565e-03 1.9009e-02 -6.0000e+00 3.4266e-02 -2.4186e-02 2.9425e-03 9.5316e-03 -6.0000e+00 2.0335e-02 -2.1850e-03 1.6038e-03 2.8391e-03 -6.0000e+00 8.9693e-03 7.1668e-04 -4.3387e-04 6.3700e-05 2.1801e-05 -6.0000e+00 4.9841e-04 4.6397e-03 -4.6016e-05 12 1 1 12 1 1 92.70 20.15 1.07 0.00464 0.00138 36 7 1 5 0 864.361 24.25 15.00 20.15 16.71 4.1 909.60 5660 -3423 -6691 7290 -10010 -10287 2739 -10211 -580 -6168 -332 -8619 5174 1979 -2605 1932 2678 -2037 -2868 -256 -1264 1153 446 2279 -1359 894 -1247 -877 -388 865 -1438 966 3511 -2416 -2540 -2500 -2289 -3176 -1174 -1161 -1205 -1136 -1377 -1326 -453 136 -201 -161 -875 739 1209 1363 1706 602 675 1164 818 1780 1240 860 999 150 741 883 101 819 -41 -14 947 684 690 -338 -58 -563 257 473 -208 -1067 -174 -282 -443 -1772 -1947 -1115 -703 -1126 -465 219 787 238 1038 967 431 -144 522 -71 376 -111 43 10 266 -51 -551 819 -783 -834 -575 -791 -354 -9 70 60 -296 528 155 318 414 448 -226 -205 -223 193 65 -220 705 838 845 804 141 -62 119 -427 -429 896 294 -459 483 -225 -47 -971 -189 78 900000 207 -147 -314 263 -368 -396 101 -492 -29 -341 -16 -506 325 149 -246 196 276 -240 -353 -35 -163 152 65 348 -225 153 -217 -138 -57 132 -260 181 750 -552 -496 -517 -534 -879 -394 -420 -464 -454 -578 -548 -187 56 -82 -72 -393 334 554 666 881 341 389 681 496 1037 705 487 593 99 536 703 78 560 -28 -9 707 549 589 -303 -49 -466 207 333 -138 -690 -127 -240 -386 -1780 -2029 -1204 -762 -1301 -558 267 952 271 1145 997 409 -140 565 -80 471 -150 60 14 350 -60 -605 974 -1041 -1128 -767 -1116 -525 -14 114 99 -459 812 217 425 571 648 -356 -320 -364 306 101 -322 972 1120 1117 1067 209 -98 189 -692 -714 1543 514 -848 877 -432 -89 -1745 -326 137 900000 SS 20230215T091616.3Z 8446.386300 268 1 55.45 2 67.26 128.10 68.14 202.98 0.00 1 0.00 1 0 17 1.396e-01 1.148e-02 9.193e-02 7.138e-03 3.677734e-01 3.472635e-03 4.309382e-03 -6.000000e+00 7.510980e-02 224.81 -2.00 3.42 -2.00 318.68 0.00e+00 3.872538e-04 7.265962e-04 1.691956e-04 -6.000000e+00 3.231434e-03 274.45 -2.00 20.00 -2.00 318.15 0.00e+00 2.567 0.000 302.00 328.00 3 5.6545e+00 9.3468e-03 2.9918e-02 -6.0000e+00 1.8632e-01 1.0369e-01 1.0692e-02 1.8355e-02 -6.0000e+00 2.0271e-01 -3.6810e-02 8.0031e-03 9.2435e-03 -6.0000e+00 1.2029e-01 5.5947e-03 4.3496e-03 2.7334e-03 -6.0000e+00 5.3062e-02 1.0506e-04 -4.6260e-04 1.6808e-04 2.2166e-05 -6.0000e+00 2.9478e-03 4.2955e-03 -4.9510e-05 12 9 8 11 8 0 97.55 20.18 0.98 0.00430 0.00082 14 2 1 5 0 3959.850 24.25 15.00 20.18 16.81 4.1 910.41 -6151 43145 -26283 -47563 119033 63497 -5828 -10630 17955 -25720 -19823 23155 -5204 19869 -5092 -4745 1548 2094 -6798 12790 5013 4907 6102 -3177 4182 5521 -2154 4863 111 4744 -5426 -1832 2408 3452 -3220 -4994 -3794 -1100 -1822 1450 -1001 -2936 1683 1885 605 -3103 1448 -1808 3090 -67 -2507 -1912 284 1836 924 -2121 1490 -3020 4393 148 2130 3690 333 4284 -1072 -1307 924 -2282 -456 2484 684 292 1679 1473 129 -1685 -2122 -297 -1967 -2128 -1304 -428 -1877 -1715 -1010 -1014 -2047 232 1163 651 1278 752 -485 -29 593 1252 -128 1407 1104 293 886 -1050 -1200 -195 -1867 -1640 -1060 -892 536 568 172 182 394 267 189 437 -744 116 -340 -289 -736 582 1821 -1031 790 167 2208 1229 347 -1419 -295 340 -928 726 173 128 442 15 -639 -1070 222 299 900000 -235 1076 -1387 -2731 1105 1068 -213 -469 666 -1566 -1069 886 -323 1207 -474 -492 154 224 -822 1327 571 531 710 -436 556 765 -320 609 14 582 -848 -292 428 673 -571 -952 -808 -267 -552 457 -343 -1063 669 736 240 -1287 561 -720 1166 -27 -1141 -922 142 976 504 -1216 851 -1749 2293 80 1182 2217 227 3089 -786 -853 585 -1442 -320 1979 589 239 1431 1204 96 -1121 -1328 -175 -1340 -1686 -1142 -384 -1765 -1681 -1073 -1142 -2439 275 1368 719 1265 768 -458 -28 572 1341 -155 1925 1563 395 1111 -1196 -1275 -225 -2411 -2147 -1467 -1301 810 949 280 298 610 420 270 595 -1057 171 -547 -492 -1226 937 2828 -1546 1105 229 2712 1642 518 -2285 -465 539 -1527 1232 317 247 841 31 -1269 -2013 400 510 900000 SS 20230215T092517.8Z 8446.392567 274 1 53.82 2 65.86 129.95 68.86 204.93 0.00 1 0.00 1 0 17 3.170e-02 6.716e-03 2.993e-02 4.172e-03 3.481871e-01 2.007901e-03 4.089272e-03 -6.000000e+00 1.705337e-02 224.81 -2.00 3.42 -2.00 318.40 0.00e+00 2.709113e-04 3.908601e-04 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