File name: Pandora238s1_Granada_20230519_L2Fit_fout2c4d20221202p1-8.txt File generation date: 20241022T150611.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20230519_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20230519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2378 305.3788 305.5198 305.6608 305.8018 305.9428 306.0838 306.2247 306.3657 306.5066 306.6475 306.7884 306.9293 307.0702 307.2110 307.3519 307.4927 307.6335 307.7743 307.9151 308.0559 308.1967 308.3375 308.4782 308.6189 308.7597 308.9004 309.0411 309.1818 309.3224 309.4631 309.6037 309.7444 309.8850 310.0256 310.1662 310.3068 310.4473 310.5879 310.7284 310.8689 311.0095 311.1500 311.2905 311.4309 311.5714 311.7118 311.8523 311.9927 312.1331 312.2735 312.4139 312.5543 312.6947 312.8350 312.9753 313.1157 313.2560 313.3963 313.5366 313.6768 313.8171 313.9573 314.0976 314.2378 314.3780 314.5182 314.6584 314.7986 314.9387 315.0789 315.2190 315.3591 315.4992 315.6393 315.7794 315.9195 316.0595 316.1996 316.3396 316.4796 316.6196 316.7596 316.8996 317.0396 317.1796 317.3195 317.4594 317.5993 317.7393 317.8792 318.0190 318.1589 318.2988 318.4386 318.5784 318.7183 318.8581 318.9979 319.1376 319.2774 319.4172 319.5569 319.6966 319.8364 319.9761 320.1158 320.2554 320.3951 320.5348 320.6744 320.8140 320.9536 321.0933 321.2328 321.3724 321.5120 321.6516 321.7911 321.9306 322.0701 322.2097 322.3491 322.4886 322.6281 322.7676 322.9070 323.0464 323.1858 323.3253 323.4646 323.6040 323.7434 323.8828 324.0221 324.1614 324.3008 324.4401 324.5794 324.7186 324.8579 324.9972 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230519T063356.7Z 8539.273573 102 1 54.57 2 73.79 77.25 70.24 79.66 0.00 1 0.00 1 0 25 2.202e-01 8.732e-03 2.027e-01 6.288e-03 5.454380e-01 3.235704e-03 6.170193e-03 -6.000000e+00 1.212847e-01 230.98 -2.00 3.42 -2.00 320.25 0.00e+00 1.084248e-03 1.131202e-03 8.044513e-04 -6.000000e+00 5.325691e-03 282.70 -2.00 20.00 -2.00 319.65 0.00e+00 3.524 0.001 302.00 328.00 3 4.1622e+00 9.6521e-03 4.3368e-02 -6.0000e+00 3.0443e-01 8.6127e-02 1.2145e-02 2.8464e-02 -6.0000e+00 3.2920e-01 -4.5734e-02 1.1611e-02 1.4460e-02 -6.0000e+00 1.9555e-01 2.4025e-03 5.9468e-03 4.3169e-03 -6.0000e+00 8.6195e-02 1.5615e-04 -4.8279e-04 1.4903e-04 3.7052e-05 -6.0000e+00 4.6537e-03 4.7186e-03 -2.6124e-05 11 8 0 10 0 0 99.85 20.72 0.86 0.00472 0.00109 28 3 1 5 0 1948.397 24.50 14.99 20.72 20.08 4.2 929.52 -116189 900000 -66638 -49773 -58017 -33766 16857 -87397 -93702 34950 -77720 -81193 31657 -30994 -32567 -137 -18278 -32038 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-1085 -715 -2213 -773 -1196 -717 146 678 771 1160 622 283 3 -273 -385 -22 41 337 -549 1073 -283 -2105 112 -2329 -1154 -918 -1196 863 2507 30 946 -224 790 -787 384 309 630 184 -895 -136 1207 767 -174 280 453 588 -821 -74 -361 -511 -527 -5 1379 139 -207 708 -399 -178 -1803 284 480 900000 SS 20230519T063938.4Z 8539.277528 106 1 25.76 2 72.68 78.04 69.15 80.40 0.00 1 0.00 1 0 25 3.182e-01 1.613e-02 2.230e-01 9.660e-03 5.106120e-01 4.763663e-03 5.702351e-03 -6.000000e+00 1.728250e-01 230.98 -2.00 3.42 -2.00 319.56 0.00e+00 1.757208e-04 1.349829e-03 5.742292e-04 -6.000000e+00 7.601112e-03 282.70 -2.00 20.00 -2.00 318.88 0.00e+00 3.311 0.001 302.00 328.00 3 4.6338e+00 1.3516e-02 4.0392e-02 -6.0000e+00 4.3422e-01 7.1428e-02 1.6155e-02 2.6071e-02 -6.0000e+00 4.7295e-01 -5.9843e-02 1.3521e-02 1.2782e-02 -6.0000e+00 2.7967e-01 2.3422e-02 7.1151e-03 3.5336e-03 -6.0000e+00 1.1872e-01 1.2494e-04 -7.4176e-05 2.2280e-04 2.6806e-05 -6.0000e+00 6.7423e-03 4.5303e-03 8.3969e-05 12 9 9 12 1 1 77.58 20.72 1.00 0.00453 0.00397 4 2 1 5 0 3671.565 24.50 15.00 20.72 20.36 4.2 930.45 -48004 200868 -26417 10575 -138589 -19178 -49765 900000 157292 109398 23084 -131494 -6630 50349 -30412 -8532 80 62306 -21264 -21125 -27437 -3945 24891 12738 4252 953 -6455 28994 -26260 -6806 -5836 43971 -4926 6196 47685 -3927 9331 -3328 6848 10480 -1697 2072 -4024 8492 69 4080 -209 -188 -4842 7995 1430 2253 788 -1563 4722 3155 1067 -1080 74 4301 729 4899 5858 1585 -1574 -647 867 -127 4621 -181 -552 -305 3394 -808 4469 -4566 -759 -4200 -724 261 -2353 -1704 -894 -2093 -1794 -922 -1667 300 903 56 -341 1896 -1926 -1566 2419 -665 -145 -827 189 -188 -18 693 -1590 -86 -1110 -1596 -345 -907 543 615 341 830 -739 626 1274 472 296 -446 494 -1625 1249 -279 1144 -549 979 1294 83 1504 1089 -258 -33 25 -481 679 396 -300 -58 -523 -407 -870 -15 -229 105 -829 1892 -435 108 -5439 -263 -1023 900000 1481 1030 316 -9570 -176 905 -1510 -394 4 1654 -1366 -1429 -2020 -220 1151 731 308 76 -559 1611 -2399 -558 -572 2858 -622 718 3144 -459 1090 -523 1219 2162 -427 525 -1141 2103 19 1084 -58 -53 -1455 2206 481 815 282 -629 1840 1286 461 -463 30 1668 308 2206 2929 928 -937 -346 464 -68 2686 -130 -390 -223 2502 -591 2774 -2725 -415 -2345 -453 191 -1830 -1515 -824 -2046 -1761 -951 -1812 326 974 57 -342 1753 -1727 -1449 2457 -730 -179 -1108 261 -247 -22 802 -1734 -100 -1444 -1970 -449 -1264 798 947 568 1404 -1219 960 1910 684 445 -659 781 -2748 1979 -436 1719 -791 1419 1820 109 2133 1634 -423 -56 43 -861 1266 751 -601 -114 -1090 -828 -1666 -28 -418 186 SS 20230519T064354.6Z 8539.280492 109 1 44.70 2 71.85 78.63 68.32 80.96 0.00 1 0.00 1 0 17 7.850e-02 5.689e-03 3.582e-02 1.563e-03 5.006224e-01 7.880531e-04 5.676437e-03 -6.000000e+00 4.323356e-02 230.98 -2.00 3.42 -2.00 319.65 0.00e+00 1.305263e-03 2.288719e-04 2.169017e-04 -6.000000e+00 1.880848e-03 282.70 -2.00 20.00 -2.00 319.02 0.00e+00 3.169 0.000 302.00 328.00 3 1.9863e+00 2.2359e-03 3.9235e-02 -6.0000e+00 1.0851e-01 5.7635e-02 2.6988e-03 2.5832e-02 -6.0000e+00 1.1735e-01 -2.5782e-02 2.3922e-03 1.3007e-02 -6.0000e+00 6.9625e-02 -3.2758e-03 1.2664e-03 4.1374e-03 -6.0000e+00 3.0506e-02 2.0027e-03 -4.1735e-04 3.6387e-05 2.8949e-05 -6.0000e+00 1.6576e-03 4.2645e-03 -1.8976e-05 12 1 1 12 1 1 99.94 20.72 0.90 0.00426 0.00113 255 35 1 5 0 170.292 24.50 15.00 20.72 20.43 4.2 931.28 -4868 -22137 -13891 -12819 -39750 -23582 -45550 -24821 -26817 -27034 -9844 -22942 -5264 -9059 -5665 -9078 -2884 3790 -5089 -5409 1000 2142 -4023 -7020 -5668 -4579 -3350 -1976 -2235 -53 -907 -2461 980 -20 -4024 -1354 -3654 -1502 -2777 -620 -2626 -604 -6 -1028 -466 59 -66 -1008 40 477 1498 564 646 1109 1165 1000 105 187 835 629 1103 1029 1368 1450 300 751 478 166 668 847 970 28 525 -15 375 244 79 -930 145 -824 -1101 -1411 -1873 -1338 -798 -773 -526 336 733 643 811 756 679 355 462 245 567 -51 -40 -184 27 -10 -753 139 -1533 -877 -860 -592 -267 255 377 303 -166 680 446 162 209 220 -346 -197 -312 48 161 -294 680 714 887 682 -26 22 -41 -92 -509 671 66 -508 403 -53 -308 -736 69 256 900000 -46 -275 -173 -142 -500 -291 -770 -395 -494 -539 -160 -483 -119 -256 -191 -368 -116 159 -245 -276 49 99 -219 -430 -396 -338 -246 -132 -142 -4 -75 -227 104 -2 -397 -138 -434 -207 -485 -127 -592 -140 -1 -250 -114 15 -16 -257 10 128 453 186 229 429 463 409 45 78 334 249 459 477 708 841 173 390 253 87 397 538 656 20 356 -10 238 136 42 -493 89 -543 -821 -1214 -1691 -1257 -814 -835 -544 351 762 684 778 683 573 310 461 278 665 -70 -57 -248 34 -11 -849 156 -1913 -1105 -1157 -845 -406 399 636 521 -274 1053 635 241 321 327 -558 -333 -509 76 247 -429 1014 1037 1187 1001 -40 37 -75 -159 -914 1256 133 -1015 847 -110 -626 -1508 134 470 900000 SS 20230519T064854.2Z 8539.283961 112 1 46.69 2 70.87 79.32 67.36 81.61 0.00 1 0.00 1 0 17 6.115e-02 5.681e-03 2.242e-02 1.196e-03 4.766511e-01 5.997889e-04 5.442904e-03 -6.000000e+00 3.367775e-02 230.98 -2.00 3.42 -2.00 319.44 0.00e+00 1.266283e-03 1.632896e-04 1.908650e-04 -6.000000e+00 1.464944e-03 282.70 -2.00 20.00 -2.00 318.79 0.00e+00 3.016 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