File name: Pandora238s1_Granada_20230522_L2Fit_fout2c4d20221202p1-8.txt File generation date: 20241022T150104.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20230522_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20230522 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2378 305.3788 305.5198 305.6608 305.8018 305.9428 306.0838 306.2247 306.3657 306.5066 306.6475 306.7884 306.9293 307.0702 307.2110 307.3519 307.4927 307.6335 307.7743 307.9151 308.0559 308.1967 308.3375 308.4782 308.6189 308.7597 308.9004 309.0411 309.1818 309.3224 309.4631 309.6037 309.7444 309.8850 310.0256 310.1662 310.3068 310.4473 310.5879 310.7284 310.8689 311.0095 311.1500 311.2905 311.4309 311.5714 311.7118 311.8523 311.9927 312.1331 312.2735 312.4139 312.5543 312.6947 312.8350 312.9753 313.1157 313.2560 313.3963 313.5366 313.6768 313.8171 313.9573 314.0976 314.2378 314.3780 314.5182 314.6584 314.7986 314.9387 315.0789 315.2190 315.3591 315.4992 315.6393 315.7794 315.9195 316.0595 316.1996 316.3396 316.4796 316.6196 316.7596 316.8996 317.0396 317.1796 317.3195 317.4594 317.5993 317.7393 317.8792 318.0190 318.1589 318.2988 318.4386 318.5784 318.7183 318.8581 318.9979 319.1376 319.2774 319.4172 319.5569 319.6966 319.8364 319.9761 320.1158 320.2554 320.3951 320.5348 320.6744 320.8140 320.9536 321.0933 321.2328 321.3724 321.5120 321.6516 321.7911 321.9306 322.0701 322.2097 322.3491 322.4886 322.6281 322.7676 322.9070 323.0464 323.1858 323.3253 323.4646 323.6040 323.7434 323.8828 324.0221 324.1614 324.3008 324.4401 324.5794 324.7186 324.8579 324.9972 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230522T064346.5Z 8542.280400 114 1 53.85 2 71.57 78.04 91.75 53.31 0.00 1 0.00 1 0 17 1.352e-01 6.506e-03 1.421e-01 3.931e-03 4.806207e-01 1.972277e-03 5.421992e-03 -6.000000e+00 7.452375e-02 231.12 -2.00 3.42 -2.00 319.77 0.00e+00 1.044275e-03 5.927730e-04 2.347152e-04 -6.000000e+00 3.244048e-03 283.00 -2.00 20.00 -2.00 319.12 0.00e+00 3.123 0.000 302.00 328.00 3 3.7172e+00 5.6601e-03 3.8204e-02 -6.0000e+00 1.8709e-01 6.3600e-02 6.8756e-03 2.4775e-02 -6.0000e+00 2.0229e-01 -1.3332e-02 6.1383e-03 1.2515e-02 -6.0000e+00 1.2003e-01 -9.3386e-03 3.2321e-03 3.8837e-03 -6.0000e+00 5.2591e-02 3.7686e-04 -3.2086e-04 9.2785e-05 2.8013e-05 -6.0000e+00 2.8538e-03 3.9940e-03 -7.6344e-06 11 8 0 10 0 0 99.68 20.43 1.02 0.00399 0.00158 73 8 1 5 0 737.249 24.50 15.00 20.43 20.65 4.2 932.54 -31948 56550 9341 70778 50608 62138 -19881 -62352 -32961 -46304 -8927 -2419 14154 -14167 -6996 -12892 11229 -4666 -12384 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168 -447 -440 619 987 -1383 1018 30 -609 605 -2342 -1089 -1349 -662 -422 425 1127 57 -99 1453 329 616 -137 428 -229 -528 -500 283 -128 -388 933 441 832 1556 164 -190 -611 -448 -905 1509 473 -1071 -307 398 -756 -1058 431 626 900000 SS 20230522T065406.2Z 8542.287572 117 1 54.61 2 69.55 79.46 90.15 54.81 0.00 1 0.00 1 0 17 3.057e-01 6.816e-03 1.611e-01 4.705e-03 4.384897e-01 2.359825e-03 5.033467e-03 -6.000000e+00 1.684214e-01 231.12 -2.00 3.42 -2.00 319.47 0.00e+00 8.654989e-05 6.362117e-04 2.160193e-04 -6.000000e+00 7.332652e-03 283.00 -2.00 20.00 -2.00 318.80 0.00e+00 2.833 0.000 302.00 328.00 3 4.3928e+00 6.6506e-03 3.4811e-02 -6.0000e+00 4.2282e-01 5.7063e-02 7.8865e-03 2.2647e-02 -6.0000e+00 4.5718e-01 -9.3052e-03 6.6322e-03 1.1231e-02 -6.0000e+00 2.7127e-01 -5.2676e-03 3.5370e-03 3.2096e-03 -6.0000e+00 1.1885e-01 2.6229e-04 -6.3446e-04 1.1174e-04 2.4426e-05 -6.0000e+00 6.4567e-03 3.9236e-03 -3.8636e-05 11 8 0 10 0 0 99.91 20.44 1.27 0.00392 -0.00084 45 5 1 5 0 1213.013 24.50 15.00 20.44 20.72 4.1 931.91 147423 -23535 26989 27761 3848 90816 301951 7916 -18579 11183 10495 2902 25016 8840 13710 8108 8337 -15192 -1361 12093 -16677 -7182 -8358 1991 -5315 -4653 -639 -5138 192 -543 1459 10167 -2159 -7408 3405 -1235 -4646 -6941 -4428 -3744 -1804 -581 -1342 1280 -172 -2731 101 1001 2922 755 13 1527 2207 -397 639 -459 789 1122 2504 2506 -114 433 2132 1290 -680 -771 826 737 1282 1476 22 4 1149 -165 96 514 146 -637 -13 -878 -863 -1137 -1383 -946 -832 -995 -318 538 566 -184 815 960 14 110 -661 115 536 -271 84 -296 -130 -1 -367 1006 -1051 -1253 -948 -1071 515 273 460 516 -168 396 -89 168 178 81 -504 -507 -626 -17 414 -165 1127 1190 714 314 -106 -136 362 436 -43 203 192 156 310 -228 -538 -736 -252 328 900000 676 -486 361 329 50 521 1385 133 -462 222 201 67 574 280 503 392 417 -1058 -86 706 -1328 -497 -645 151 -457 -423 -56 -428 14 -43 135 928 -263 -970 378 -152 -673 -1216 -945 -862 -481 -159 -390 358 -49 -812 29 285 823 225 4 549 839 -169 276 -206 363 500 1067 1056 -52 216 1163 787 -413 -420 445 388 764 1031 16 3 859 -120 62 291 78 -335 -8 -621 -685 -940 -1194 -850 -816 -1037 -345 589 621 -190 753 913 13 99 -620 120 629 -369 118 -395 -163 -1 -378 1115 -1312 -1593 -1280 -1534 770 455 750 852 -267 638 -132 237 260 123 -838 -814 -1067 -27 664 -251 1608 1649 915 438 -166 -228 600 737 -76 372 380 324 636 -494 -1147 -1482 -487 597 900000 SS 20230522T080813.2Z 8542.339042 172 1 52.88 2 54.86 89.98 77.81 64.77 0.00 1 0.00 1 0 25 8.098e-02 1.501e-02 5.871e-02 1.133e-02 2.930700e-01 5.629218e-03 3.513003e-03 -6.000000e+00 4.461852e-02 231.13 -2.00 3.42 -2.00 317.97 0.00e+00 -4.692478e-04 9.497539e-04 8.013016e-05 -6.000000e+00 1.942614e-03 283.01 -2.00 20.00 -2.00 317.24 0.00e+00 1.732 0.000 302.00 328.00 3 6.8892e+00 1.5125e-02 2.2279e-02 -6.0000e+00 1.1201e-01 1.1269e-01 1.7076e-02 1.5162e-02 -6.0000e+00 1.2112e-01 -1.5923e-02 1.1016e-02 7.4631e-03 -6.0000e+00 7.1866e-02 -7.3775e-03 5.7740e-03 2.1487e-03 -6.0000e+00 3.1485e-02 7.0333e-05 -8.2548e-04 2.6888e-04 1.7450e-05 -6.0000e+00 1.7105e-03 4.3197e-03 -2.8052e-05 12 8 8 10 0 0 99.94 20.47 2.30 0.00432 -0.00188 14 2 1 5 0 3776.849 24.50 15.00 20.47 21.31 4.2 936.68 -13821 -3168 -30749 33973 -21430 27794 49969 -10659 -15644 25390 -2450 -8468 20215 9086 753 5424 -8742 13220 32 6259 -10951 8171 9684 697 6265 2844 2945 7765 -4994 -2106 -5435 5215 -1282 2309 -2973 -9244 -83 -8013 5572 138 -1190 522 2433 -1710 -518 -39 -1754 1443 198 -627 -1090 2397 640 -2499 -2669 4336 -2978 924 -755 -1346 1374 400 3178 758 2475 1850 -1693 1721 1451 1507 49 419 244 -1853 1737 -4723 4919 356 -1044 -1263 -2253 1477 -1177 -3156 -2004 -73 -1319 586 2299 29 103 2021 -1016 -436 -1468 1630 -725 -511 1807 -444 132 1372 -1033 -1671 -630 84 -418 -485 1213 1308 355 264 538 201 -3122 778 -906 1365 282 -107 -2020 -1326 1289 -685 -371 1742 2216 -899 1277 -176 -911 65 718 1969 -646 637 -339 -7 336 -571 -1088 95 900000 -1116 -242 -3241 1646 -1530 1252 1954 -879 -1516 1871 -221 -858 1824 1029 108 819 -1522 1972 6 1072 -2269 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