File name: Pandora238s1_Granada_20230818_L2Fit_fout2c4d20221202p1-8.txt File generation date: 20230819T181917.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20230818_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20230818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2378 305.3788 305.5198 305.6608 305.8018 305.9428 306.0838 306.2247 306.3657 306.5066 306.6475 306.7884 306.9293 307.0702 307.2110 307.3519 307.4927 307.6335 307.7743 307.9151 308.0559 308.1967 308.3375 308.4782 308.6189 308.7597 308.9004 309.0411 309.1818 309.3224 309.4631 309.6037 309.7444 309.8850 310.0256 310.1662 310.3068 310.4473 310.5879 310.7284 310.8689 311.0095 311.1500 311.2905 311.4309 311.5714 311.7118 311.8523 311.9927 312.1331 312.2735 312.4139 312.5543 312.6947 312.8350 312.9753 313.1157 313.2560 313.3963 313.5366 313.6768 313.8171 313.9573 314.0976 314.2378 314.3780 314.5182 314.6584 314.7986 314.9387 315.0789 315.2190 315.3591 315.4992 315.6393 315.7794 315.9195 316.0595 316.1996 316.3396 316.4796 316.6196 316.7596 316.8996 317.0396 317.1796 317.3195 317.4594 317.5993 317.7393 317.8792 318.0190 318.1589 318.2988 318.4386 318.5784 318.7183 318.8581 318.9979 319.1376 319.2774 319.4172 319.5569 319.6966 319.8364 319.9761 320.1158 320.2554 320.3951 320.5348 320.6744 320.8140 320.9536 321.0933 321.2328 321.3724 321.5120 321.6516 321.7911 321.9306 322.0701 322.2097 322.3491 322.4886 322.6281 322.7676 322.9070 323.0464 323.1858 323.3253 323.4646 323.6040 323.7434 323.8828 324.0221 324.1614 324.3008 324.4401 324.5794 324.7186 324.8579 324.9972 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230818T061958.9Z 8630.263876 73 1 54.04 2 81.79 79.68 101.11 70.56 0.00 1 0.00 1 0 17 5.674e-01 8.341e-03 3.518e-01 4.882e-03 7.930982e-01 2.733967e-03 8.916367e-03 -6.000000e+00 3.140407e-01 230.89 -2.00 3.42 -2.00 321.65 0.00e+00 6.275101e-03 1.500028e-03 1.861847e-03 -6.000000e+00 1.497572e-02 288.50 -2.00 20.00 -2.00 321.13 0.00e+00 6.567 0.005 302.00 328.00 3 3.8782e-01 1.0162e-02 7.3887e-02 -6.0000e+00 7.8753e-01 1.8927e-01 1.6359e-02 4.4010e-02 -6.0000e+00 8.5120e-01 -1.9019e-01 1.8198e-02 2.7124e-02 -6.0000e+00 5.1040e-01 6.1539e-02 8.2757e-03 1.2169e-02 -6.0000e+00 2.3130e-01 3.6999e-04 -8.1781e-04 1.1343e-04 9.1907e-05 -6.0000e+00 1.2489e-02 4.7351e-03 -2.5550e-06 11 8 0 10 0 0 -11.12 21.71 1.04 0.00474 -0.00141 238 26 1 5 0 226.703 25.50 14.99 21.71 27.40 4.2 967.92 900000 900000 900000 900000 -232408 -254932 -176585 -149837 -191540 -153031 -93697 -214847 -200547 15542 -11367 900000 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553 1237 -19 -240 28 28 363 -674 307 -413 -588 -303 -652 -395 589 -377 117 1310 389 1060 596 -357 -875 -325 -217 -846 -328 -803 -241 -223 -557 -157 -1901 -1291 -1286 -961 158 386 582 519 399 886 363 167 258 324 316 -61 142 729 800 -1050 429 521 999 293 7 -158 69 -252 -143 854 -541 -880 1599 -573 -631 -1682 986 356 900000 SS 20230818T063509.7Z 8630.274418 78 1 54.09 2 78.81 81.89 98.36 72.98 0.00 1 0.00 1 0 25 2.764e-01 5.451e-03 1.521e-01 1.654e-03 6.262020e-01 8.705723e-04 7.009686e-03 -6.000000e+00 1.522256e-01 230.89 -2.00 3.42 -2.00 320.79 0.00e+00 2.555173e-03 3.707185e-04 5.855248e-04 -6.000000e+00 6.788274e-03 288.50 -2.00 20.00 -2.00 320.16 0.00e+00 4.972 0.002 302.00 328.00 3 2.8097e-01 2.7724e-03 5.6271e-02 -6.0000e+00 3.8122e-01 7.2471e-02 3.8035e-03 3.2869e-02 -6.0000e+00 4.1189e-01 -3.9734e-02 3.9155e-03 1.7725e-02 -6.0000e+00 2.4524e-01 1.3992e-03 1.9274e-03 6.5612e-03 -6.0000e+00 1.0803e-01 1.9899e-03 -6.3864e-04 3.8689e-05 4.6653e-05 -6.0000e+00 5.8380e-03 4.7409e-03 -1.1252e-05 10 0 0 10 0 0 -0.93 21.68 0.94 0.00474 -0.00006 589 65 1 5 0 91.472 25.50 15.00 21.68 29.25 4.2 981.53 -61070 82313 92918 -77084 -119303 -96459 -117811 -90978 -97898 -28691 -75314 -78755 -63868 -40779 5041 -17088 5399 -6122 -20396 -27574 -3605 -15014 -17206 1013 -13801 -6939 -9389 -15533 -17488 -24038 -9934 -1419 -1821 -1600 -13297 -12949 -10664 -5784 -7187 -3773 -5634 -1523 -1774 -599 -738 59 -313 -1050 -910 -1560 594 1804 1809 2156 906 1401 521 410 308 292 1925 1460 2742 2553 1278 783 503 1089 578 1764 1743 135 479 298 80 752 -447 -698 -699 -581 -935 -852 -1562 -1190 -968 -381 -478 672 654 476 627 613 155 -295 -62 -320 504 295 96 -153 -219 -394 -623 195 -1754 -922 -750 -647 -290 154 479 355 94 749 419 424 -81 186 -348 -189 -378 250 476 -264 467 365 828 587 -8 -101 -167 -186 -329 387 -26 -457 493 -128 -133 -599 189 363 900000 -197 133 150 -363 -754 -519 -871 -599 -789 -127 -526 -677 -635 -406 41 -207 57 -90 -368 -570 -60 -271 -356 19 -324 -164 -231 -380 -426 -712 -325 -48 -76 -69 -562 -579 -536 -332 -580 -325 -594 -163 -203 -68 -86 7 -38 -134 -121 -223 97 319 348 459 203 324 127 97 71 66 454 391 828 886 451 256 172 371 228 815 863 70 239 141 34 278 -162 -256 -305 -303 -560 -594 -1157 -838 -742 -308 -405 573 557 382 501 467 113 -228 -51 -302 540 371 128 -193 -258 -408 -590 198 -2003 -1063 -927 -860 -417 231 784 602 155 1172 610 595 -119 285 -578 -325 -623 394 734 -388 712 545 1143 828 -12 -181 -331 -354 -657 813 -59 -1098 1160 -319 -323 -1365 407 732 900000 SS 20230818T064023.0Z 8630.278045 81 1 54.10 2 77.78 82.65 97.40 73.80 0.00 1 0.00 1 0 25 2.157e-01 5.761e-03 5.415e-02 1.276e-03 5.818080e-01 6.616030e-04 6.587336e-03 -6.000000e+00 1.188185e-01 230.89 -2.00 3.42 -2.00 320.51 0.00e+00 2.132849e-03 2.577105e-04 4.718245e-04 -6.000000e+00 5.298169e-03 288.50 -2.00 20.00 -2.00 319.84 0.00e+00 4.585 0.002 302.00 328.00 3 2.4931e-01 2.0428e-03 5.2027e-02 -6.0000e+00 2.9756e-01 6.8330e-02 2.6808e-03 3.0359e-02 -6.0000e+00 3.2149e-01 -3.6568e-02 2.6290e-03 1.5834e-02 -6.0000e+00 1.9142e-01 8.1813e-04 1.3236e-03 5.5109e-03 -6.0000e+00 8.4327e-02 3.0281e-03 -5.6832e-04 2.9761e-05 4.1060e-05 -6.0000e+00 4.5547e-03 4.5157e-03 -5.6965e-06 10 0 0 10 0 0 -5.26 21.71 0.87 0.00452 0.00025 741 81 1 5 0 72.648 25.50 15.00 21.71 29.91 4.2 986.11 -89764 -59179 -71343 -74121 -91470 -82444 -39695 -77160 -36834 -44413 -79510 -46929 -43806 -31848 -20436 -16445 -19426 -14187 -9207 -5447 -4748 -16900 -12646 -11897 -9493 -12871 -11409 -11675 -17454 -7147 -4258 -4723 -2312 -4402 -6627 -1980 -8109 -6921 -3518 -3499 -1876 -903 -1203 36 428 398 217 -243 600 1043 2617 1897 1652 731 373 1553 1533 542 194 784 1300 2606 1618 1853 938 1418 1271 182 825 994 1000 240 -41 -304 113 7 -336 -1299 -547 -1419 -814 -1111 -1645 -1417 -901 -642 -423 719 1057 926 1122 827 275 -75 75 -78 551 -24 -142 -274 102 -370 -1010 140 -1488 -898 -1119 -647 -281 448 395 432 162 670 397 249 269 283 -268 -435 -385 149 359 -252 613 499 763 610 -20 34 -85 -182 -387 424 22 -546 346 -29 -248 -617 186 368 900000 -636 -374 -562 -546 -702 -616 -214 -704 -256 -364 -907 -453 -541 -433 -342 -314 -411 -323 -211 -128 -114 -440 -352 -362 -299 -450 -399 -380 -583 -242 -175 -217 -126 -254 -373 -113 -564 -568 -351 -422 -242 -122 -173 5 62 59 33 -38 96 176 503 402 380 188 100 424 436 151 53 209 365 811 577 751 382 528 489 70 366 520 560 141 -23 -163 54 3 -136 -533 -263 -820 -532 -768 -1203 -1084 -748 -564 -388 665 975 802 879 617 215 -61 64 -78 618 -32 -181 -360 125 -401 -1008 150 -1783 -1088 -1457 -900 -386 694 665 749 272 1067 586 353 397 438 -449 -761 -646 242 566 -378 873 695 1071 869 -32 60 -154 -342 -763 878 49 -1201 806 -65 -553 -1392 397 738 900000 SS 20230818T064531.9Z 8630.281620 84 1 54.07 2 76.76 83.40 96.46 74.60 0.00 1 0.00 1 0 25 1.545e-01 5.522e-03 3.445e-02 1.031e-03 5.433992e-01 5.277183e-04 6.189024e-03 -6.000000e+00 8.509221e-02 230.89 -2.00 3.42 -2.00 320.22 0.00e+00 2.117410e-03 1.892914e-04 2.565894e-04 -6.000000e+00 3.794330e-03 288.50 -2.00 20.00 -2.00 319.54 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