File name: Pandora238s1_Granada_20230902_L2Fit_fout2c4d20221202p1-8.txt File generation date: 20230903T181348.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20230902_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20230902 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2378 305.3788 305.5198 305.6608 305.8018 305.9428 306.0838 306.2247 306.3657 306.5066 306.6475 306.7884 306.9293 307.0702 307.2110 307.3519 307.4927 307.6335 307.7743 307.9151 308.0559 308.1967 308.3375 308.4782 308.6189 308.7597 308.9004 309.0411 309.1818 309.3224 309.4631 309.6037 309.7444 309.8850 310.0256 310.1662 310.3068 310.4473 310.5879 310.7284 310.8689 311.0095 311.1500 311.2905 311.4309 311.5714 311.7118 311.8523 311.9927 312.1331 312.2735 312.4139 312.5543 312.6947 312.8350 312.9753 313.1157 313.2560 313.3963 313.5366 313.6768 313.8171 313.9573 314.0976 314.2378 314.3780 314.5182 314.6584 314.7986 314.9387 315.0789 315.2190 315.3591 315.4992 315.6393 315.7794 315.9195 316.0595 316.1996 316.3396 316.4796 316.6196 316.7596 316.8996 317.0396 317.1796 317.3195 317.4594 317.5993 317.7393 317.8792 318.0190 318.1589 318.2988 318.4386 318.5784 318.7183 318.8581 318.9979 319.1376 319.2774 319.4172 319.5569 319.6966 319.8364 319.9761 320.1158 320.2554 320.3951 320.5348 320.6744 320.8140 320.9536 321.0933 321.2328 321.3724 321.5120 321.6516 321.7911 321.9306 322.0701 322.2097 322.3491 322.4886 322.6281 322.7676 322.9070 323.0464 323.1858 323.3253 323.4646 323.6040 323.7434 323.8828 324.0221 324.1614 324.3008 324.4401 324.5794 324.7186 324.8579 324.9972 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230902T080201.1Z 8645.334736 316 1 50.10 2 63.82 100.31 86.71 270.88 0.00 1 0.00 1 0 17 1.526e-02 6.085e-03 1.936e-03 3.604e-04 3.358894e-01 1.769267e-04 3.935582e-03 -6.000000e+00 8.371258e-03 229.84 -2.00 3.42 -2.00 317.92 0.00e+00 3.688966e-04 3.099707e-05 9.214642e-05 -6.000000e+00 3.731276e-04 287.47 -2.00 20.00 -2.00 317.13 0.00e+00 2.253 0.000 302.00 328.00 3 5.1770e-01 4.7387e-04 2.7102e-02 -6.0000e+00 2.0918e-02 2.8196e-02 5.3777e-04 1.7112e-02 -6.0000e+00 2.2624e-02 -7.4521e-03 3.5589e-04 8.4005e-03 -6.0000e+00 1.3474e-02 -5.0503e-03 1.8976e-04 2.3741e-03 -6.0000e+00 5.9429e-03 2.5094e-02 -3.0742e-04 8.3512e-06 1.7662e-05 -6.0000e+00 3.2243e-04 5.4264e-03 -8.3822e-06 12 1 1 12 1 1 98.45 21.43 0.94 0.00543 0.00312 1575 187 1 5 0 31.435 25.25 14.99 21.43 28.34 4.2 973.41 -4526 -2562 -4583 -4184 -6042 -5878 -6033 -4588 -1908 -2775 -4037 -2709 -2306 -2264 -429 -802 415 224 922 1399 835 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-1658 -1219 -1340 -947 -305 482 479 404 -16 1111 455 496 247 427 -129 -631 -802 249 189 -239 1296 1031 1181 1332 403 188 120 -13 -497 970 209 -870 582 -375 -542 -1490 -247 3 900000 SS 20230902T080722.5Z 8645.338455 319 1 54.08 2 62.77 101.22 87.73 271.68 0.00 1 0.00 1 0 17 1.439e-02 6.091e-03 1.600e-03 3.101e-04 3.257768e-01 1.526065e-04 3.844926e-03 -6.000000e+00 7.895125e-03 229.84 -2.00 3.42 -2.00 317.89 0.00e+00 3.597734e-04 2.649613e-05 9.129909e-05 -6.000000e+00 3.519291e-04 287.47 -2.00 20.00 -2.00 317.11 0.00e+00 2.174 0.000 302.00 328.00 3 3.0957e-01 4.0836e-04 2.6253e-02 -6.0000e+00 1.9729e-02 2.7443e-02 4.6222e-04 1.6668e-02 -6.0000e+00 2.1337e-02 -6.1837e-03 3.0328e-04 8.1799e-03 -6.0000e+00 1.2708e-02 -5.7763e-03 1.6145e-04 2.3052e-03 -6.0000e+00 5.6047e-03 3.3693e-02 -3.6055e-04 7.2179e-06 1.8132e-05 -6.0000e+00 3.0426e-04 5.4962e-03 -2.1212e-05 10 0 0 10 0 0 -9.24 21.45 0.90 0.00550 0.00279 2525 277 1 5 0 21.066 25.25 15.00 21.45 29.05 4.3 979.49 -3962 -3831 -3668 -4672 -5589 -4990 -4982 -3593 -1341 -2719 -3962 -3489 -2234 -1737 -274 -914 96 649 1166 1372 563 814 807 255 -197 581 307 60 -517 1127 644 1254 991 -493 -2329 -1738 -2145 -1923 -1284 -1248 -1478 -1016 -386 -787 -125 93 -304 -162 -546 275 913 647 803 628 461 1248 938 604 977 265 1138 1033 1284 1082 -151 374 276 -343 601 674 569 -181 -11 -89 374 223 454 -548 73 -823 -980 -1505 -1846 -1306 -763 -939 -662 88 395 269 878 753 621 490 515 311 631 42 -226 -380 102 -220 -654 456 -1248 -907 -985 -661 -204 353 339 265 -10 691 342 352 143 332 -102 -381 -517 189 144 -161 952 733 931 952 241 115 15 -24 -312 618 200 -485 304 -151 -282 -885 -129 -17 900000 -247 -253 -255 -288 -298 -275 -298 -244 -100 -217 -299 -283 -216 -191 -35 -131 14 100 184 249 105 144 155 53 -43 132 69 12 -98 220 144 292 267 -135 -555 -436 -611 -640 -525 -547 -688 -487 -192 -388 -62 46 -147 -77 -258 131 481 363 475 402 300 820 638 401 630 171 765 762 1035 874 -119 281 205 -246 483 580 521 -174 -10 -79 326 171 324 -376 56 -678 -898 -1570 -1993 -1355 -861 -1128 -831 112 503 320 938 811 607 483 567 353 795 57 -314 -497 135 -261 -729 554 -1698 -1251 -1341 -945 -304 536 543 425 -15 1035 466 458 192 468 -158 -585 -779 298 221 -234 1296 969 1213 1236 346 174 23 -37 -494 1014 333 -854 528 -277 -510 -1525 -215 -29 900000 SS 20230902T081230.0Z 8645.342014 322 1 54.08 2 61.77 102.11 88.70 272.44 0.00 1 0.00 1 0 17 1.358e-02 6.095e-03 1.382e-03 2.946e-04 3.148289e-01 1.454100e-04 3.706474e-03 -6.000000e+00 7.449596e-03 229.84 -2.00 3.42 -2.00 317.74 0.00e+00 3.828950e-04 2.407262e-05 8.092757e-05 -6.000000e+00 3.320658e-04 287.47 -2.00 20.00 -2.00 316.95 0.00e+00 2.104 0.000 302.00 328.00 3 3.0624e-01 3.8779e-04 2.5366e-02 -6.0000e+00 1.8615e-02 2.5562e-02 4.3824e-04 1.6059e-02 -6.0000e+00 2.0133e-02 -5.8473e-03 2.8321e-04 7.9011e-03 -6.0000e+00 1.1990e-02 -5.4799e-03 1.4987e-04 2.2472e-03 -6.0000e+00 5.2885e-03 3.6651e-02 -3.2727e-04 6.8560e-06 1.7511e-05 -6.0000e+00 2.8707e-04 5.4156e-03 -2.1442e-05 10 0 0 10 0 0 -6.49 21.45 0.92 0.00542 0.00296 2614 287 1 5 0 20.336 25.25 14.99 21.45 29.96 4.2 986.07 -4213 -2177 -3269 -3656 -5186 -5295 -5128 -3689 -1527 -2366 -3679 -2415 -1513 -1898 -36 -548 362 486 1110 1228 513 1084 927 313 -92 649 72 -194 -521 1033 681 1258 1071 -404 -2751 -1375 -1987 -1800 -1299 -1330 -1477 -993 -463 -585 -138 48 -263 -192 -476 264 991 663 678 718 379 1296 1023 594 1000 334 1098 960 1244 1047 -170 388 139 -309 638 756 589 -179 -32 -109 355 209 414 -542 37 -781 -943 -1517 -1845 -1302 -814 -921 -735 86 354 205 861 775 699 528 499 303 652 67 -285 -362 91 -225 -646 461 -1240 -874 -983 -715 -170 288 323 234 -35 660 299 353 206 332 -78 -406 -477 145 139 -141 941 755 985 952 252 132 34 4 -300 627 172 -484 297 -197 -274 -863 -136 -50 900000 -296 -159 -254 -250 -307 -326 -342 -279 -127 -209 -307 -214 -160 -229 -5 -85 56 81 191 220 94 207 192 70 -21 158 17 -43 -107 217 162 311 307 -118 -698 -365 -599 -634 -511 -617 -726 -502 -243 -303 -72 25 -133 -96 -235 132 544 388 418 477 256 884 722 409 670 224 767 736 953 875 -137 301 106 -228 482 668 553 -177 -30 -100 292 165 303 -381 29 -656 -881 -1613 -1874 -1376 -938 -1127 -942 104 426 249 938 849 695 529 515 348 831 91 -399 -478 112 -269 -729 567 -1587 -1133 -1355 -1035 -256 442 522 377 -53 994 410 462 278 470 -112 -626 -722 215 202 -206 1289 1004 1290 1242 364 200 53 7 -473 1029 286 -851 515 -362 -496 -1486 -227 -79 900000 SS 20230902T081749.4Z 8645.345711 325 1 54.07 2 60.74 103.04 89.71 273.24 0.00 1 0.00 1 0 17 1.206e-02 6.110e-03 1.218e-03 2.802e-04 3.060267e-01 1.382098e-04 3.616017e-03 -6.000000e+00 6.613609e-03 229.84 -2.00 3.42 -2.00 317.61 0.00e+00 3.197704e-04 2.215065e-05 7.641519e-05 -6.000000e+00 2.948094e-04 287.47 -2.00 20.00 -2.00 316.82 0.00e+00 2.037 0.000 302.00 328.00 3 2.9411e-01 3.6760e-04 2.4611e-02 -6.0000e+00 1.6526e-02 2.4837e-02 4.1450e-04 1.5628e-02 -6.0000e+00 1.7874e-02 -5.7217e-03 2.6482e-04 7.6745e-03 -6.0000e+00 1.0645e-02 -5.1018e-03 1.3970e-04 2.1665e-03 -6.0000e+00 4.6950e-03 3.9973e-02 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