File name: Pandora238s1_Granada_20231012_L2Fit_fout2c4d20221202p1-8.txt File generation date: 20231013T052149.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20231012_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20231012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2378 305.3788 305.5198 305.6608 305.8018 305.9428 306.0838 306.2247 306.3657 306.5066 306.6475 306.7884 306.9293 307.0702 307.2110 307.3519 307.4927 307.6335 307.7743 307.9151 308.0559 308.1967 308.3375 308.4782 308.6189 308.7597 308.9004 309.0411 309.1818 309.3224 309.4631 309.6037 309.7444 309.8850 310.0256 310.1662 310.3068 310.4473 310.5879 310.7284 310.8689 311.0095 311.1500 311.2905 311.4309 311.5714 311.7118 311.8523 311.9927 312.1331 312.2735 312.4139 312.5543 312.6947 312.8350 312.9753 313.1157 313.2560 313.3963 313.5366 313.6768 313.8171 313.9573 314.0976 314.2378 314.3780 314.5182 314.6584 314.7986 314.9387 315.0789 315.2190 315.3591 315.4992 315.6393 315.7794 315.9195 316.0595 316.1996 316.3396 316.4796 316.6196 316.7596 316.8996 317.0396 317.1796 317.3195 317.4594 317.5993 317.7393 317.8792 318.0190 318.1589 318.2988 318.4386 318.5784 318.7183 318.8581 318.9979 319.1376 319.2774 319.4172 319.5569 319.6966 319.8364 319.9761 320.1158 320.2554 320.3951 320.5348 320.6744 320.8140 320.9536 321.0933 321.2328 321.3724 321.5120 321.6516 321.7911 321.9306 322.0701 322.2097 322.3491 322.4886 322.6281 322.7676 322.9070 323.0464 323.1858 323.3253 323.4646 323.6040 323.7434 323.8828 324.0221 324.1614 324.3008 324.4401 324.5794 324.7186 324.8579 324.9972 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231012T065640.9Z 8685.289362 142 1 54.21 2 83.52 104.32 57.23 109.93 0.00 1 0.00 1 0 17 6.337e-01 1.673e-02 4.154e-01 1.482e-02 8.544690e-01 9.165145e-03 9.180590e-03 -6.000000e+00 3.703694e-01 226.43 -2.00 3.42 -2.00 322.12 0.00e+00 1.163010e-02 5.695866e-03 4.212113e-03 -6.000000e+00 3.151967e-02 283.52 -2.00 20.00 -2.00 321.71 0.00e+00 8.027 0.008 302.00 328.00 3 9.4003e-01 3.8375e-02 9.5418e-02 -6.0000e+00 9.3045e-01 1.2361e-01 7.0492e-02 7.9261e-02 -6.0000e+00 1.0225e+00 -1.8977e-01 8.2749e-02 3.1417e-02 -6.0000e+00 6.0868e-01 8.2523e-02 3.5961e-02 1.7829e-02 -6.0000e+00 2.9435e-01 6.0682e-05 -1.1992e-03 3.8573e-04 1.1867e-04 -6.0000e+00 1.5882e-02 9.2315e-03 4.8162e-06 12 8 8 10 0 0 -7.21 21.01 1.41 0.00923 0.00022 77 8 1 5 0 703.623 25.00 15.00 21.01 21.97 4.4 927.98 900000 900000 900000 900000 900000 900000 900000 -252378 900000 900000 900000 900000 900000 900000 900000 900000 900000 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578 844 -943 655 3500 1810 1634 -1149 -526 972 2059 -112 -273 1553 -798 489 411 1488 1323 226 89 -697 640 539 128 34 701 -680 -1344 2854 631 1450 97 -1811 668 -1094 28 472 222 3229 -609 476 106 -2206 2158 878 1479 1516 -652 -186 -918 -422 -100 -144 -115 1024 2076 -3749 -32 985 -3838 192 356 -1204 -1539 -1644 -899 1278 95 -1513 3919 -1072 -759 620 2738 853 548 1997 -524 -675 -649 -4210 3168 3028 644 348 -1262 2310 -1877 653 -1282 -208 -1452 309 341 900000 SS 20231012T070700.9Z 8685.296538 145 1 54.16 2 81.53 105.95 55.37 111.98 0.00 1 0.00 1 0 17 3.045e-01 6.776e-03 3.033e-01 4.737e-03 7.149383e-01 2.616599e-03 8.012388e-03 -6.000000e+00 1.667186e-01 226.43 -2.00 3.42 -2.00 321.42 0.00e+00 6.235282e-03 1.324159e-03 1.004869e-03 -6.000000e+00 8.686787e-03 283.52 -2.00 20.00 -2.00 320.92 0.00e+00 6.394 0.004 302.00 328.00 3 6.8872e-01 9.0447e-03 6.9715e-02 -6.0000e+00 4.1304e-01 1.1560e-01 1.4016e-02 3.9218e-02 -6.0000e+00 4.4936e-01 -1.0224e-01 1.6070e-02 2.4180e-02 -6.0000e+00 2.6665e-01 2.5813e-02 7.5146e-03 1.1963e-02 -6.0000e+00 1.2344e-01 3.5934e-04 -7.9129e-04 1.1371e-04 8.2195e-05 -6.0000e+00 6.8191e-03 9.5235e-03 -2.5306e-05 11 8 0 10 0 0 0.48 21.01 1.10 0.00952 0.00358 211 23 1 5 0 256.305 24.75 14.99 21.01 22.95 4.3 934.18 900000 900000 900000 900000 900000 -40823 900000 -179420 -116034 -26212 900000 -105258 900000 -125751 -64825 -25953 94480 -24122 -1 -49470 -54434 -51572 62880 2274 -48580 -18766 -57266 28501 -24632 30229 5165 54323 -7057 -35487 -39265 -18661 26123 -7821 19113 10508 2195 12438 -954 4561 12917 -6524 -3076 3 3709 -8182 278 -6347 1643 3277 -3904 2905 1002 -4788 -186 1442 -918 4082 1621 2679 412 3884 3793 779 2228 61 3096 -47 1168 -856 871 -969 -886 -1395 531 -2744 -1024 -1498 -60 -1012 258 -871 -30 618 2145 1028 920 -1413 602 -172 51 190 16 469 -39 116 551 -857 -932 -205 -2446 -1175 -1125 -454 -201 352 16 -260 185 710 417 904 -311 814 -453 -122 80 438 386 -498 873 387 449 226 205 68 -258 53 -483 306 -183 -701 802 -228 -165 -538 374 482 900000 900000 900000 900000 900000 900000 -188 900000 -955 -535 -121 900000 -485 900000 -1208 -448 -150 436 -176 0 -532 -628 -555 290 19 -713 -220 -1008 203 -300 253 74 547 -163 -1131 -1136 -469 482 -243 569 414 103 563 -53 243 655 -419 -197 0 277 -747 27 -741 194 425 -565 407 149 -729 -26 198 -138 668 316 603 96 822 850 183 601 20 1047 -17 396 -278 246 -247 -223 -365 166 -1075 -455 -785 -33 -587 161 -581 -21 432 1476 671 548 -827 335 -104 36 159 15 535 -43 133 586 -803 -792 -188 -2503 -1213 -1252 -546 -242 487 24 -418 290 1066 587 1228 -447 1216 -734 -204 126 658 567 -702 1170 512 556 318 337 124 -526 113 -1093 673 -436 -1758 1959 -590 -417 -1262 827 991 900000 SS 20231012T072105.5Z 8685.306314 150 1 54.07 2 78.85 108.22 52.88 114.91 0.00 1 0.00 1 0 25 1.530e-01 5.537e-03 1.428e-01 1.792e-03 5.796421e-01 9.139862e-04 6.488042e-03 -6.000000e+00 8.280735e-02 226.43 -2.00 3.42 -2.00 320.64 0.00e+00 2.122505e-03 3.696694e-04 4.240479e-04 -6.000000e+00 3.677968e-03 283.52 -2.00 20.00 -2.00 320.06 0.00e+00 4.992 0.002 302.00 328.00 3 5.2936e-01 2.8227e-03 5.4551e-02 -6.0000e+00 2.0554e-01 4.6910e-02 3.7954e-03 3.0011e-02 -6.0000e+00 2.2306e-01 -1.3173e-02 3.9509e-03 1.6117e-02 -6.0000e+00 1.3290e-01 -1.0512e-02 1.9758e-03 5.7929e-03 -6.0000e+00 5.8816e-02 1.6604e-03 -7.0911e-04 4.2138e-05 4.1457e-05 -6.0000e+00 3.2427e-03 9.2184e-03 -2.5345e-05 10 0 0 10 0 0 10.48 20.98 0.99 0.00922 0.00389 491 54 1 5 0 109.770 24.75 15.00 20.98 24.17 4.3 943.17 34215 -76425 -68890 -16094 -19948 -62335 -7079 -80732 9362 -58724 -31489 -23723 -20509 -11381 -3847 -18074 -10554 -22555 -7474 -5171 -7293 -20080 -9176 -5277 -3674 -12732 -11035 -14446 -13713 -13065 -11387 -3383 -5337 -590 -10684 -11123 -5062 -7257 -3188 -144 -3165 -2225 -1691 -298 2948 -609 -675 -2323 -288 779 3076 961 2540 444 1538 1150 606 -271 143 -427 166 1969 2195 2593 908 1111 1318 889 -358 1242 1015 -118 860 -408 510 -437 -828 -1238 -806 -744 -964 -1091 -1581 -1457 -485 -591 -333 517 659 958 1302 820 383 -56 182 -294 531 -18 76 -267 155 -248 -899 208 -1513 -1100 -912 -850 -125 389 577 642 -39 805 176 115 58 412 -283 -482 -249 217 170 -191 567 216 559 578 -144 5 -73 -186 -499 430 197 -474 404 -93 -212 -667 266 481 900000 60 -452 -417 -56 -64 -327 -24 -658 35 -479 -193 -159 -176 -111 -44 -284 -181 -494 -150 -108 -159 -478 -220 -134 -97 -398 -344 -434 -396 -425 -456 -140 -273 -30 -516 -578 -284 -498 -291 -14 -379 -279 -225 -39 382 -84 -94 -342 -43 123 549 191 540 107 379 294 162 -71 36 -108 44 579 733 982 347 390 478 324 -153 614 537 -66 452 -206 228 -174 -320 -483 -371 -408 -604 -793 -1212 -1066 -383 -496 -292 457 582 790 1068 643 286 -44 152 -281 576 -22 101 -338 182 -257 -862 216 -1746 -1289 -1145 -1145 -182 585 942 1077 -63 1240 276 174 90 621 -461 -819 -405 340 260 -278 857 321 768 884 -232 9 -142 -373 -1048 876 434 -1104 925 -225 -500 -1478 559 948 900000 SS 20231012T072619.1Z 8685.309944 153 1 54.06 2 77.87 109.08 51.97 116.04 0.00 1 0.00 1 0 25 1.380e-01 5.697e-03 5.533e-02 1.391e-03 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