File name: Pandora238s1_Granada_20240203_L2Fit_fout2c14d20230901p1-8.txt File generation date: 20250305T233256.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20230901.txt Level 1 file used: Pandora238s1_Granada_20240203_L1_smca1c14d20230901p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20240203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 10 for SO2 First and last pixel inside fitting window: 202 343 Nominal wavelengths inside fitting window [nm]: 305.0915 305.2330 305.3745 305.5159 305.6574 305.7988 305.9402 306.0815 306.2229 306.3642 306.5055 306.6468 306.7881 306.9293 307.0705 307.2117 307.3529 307.4940 307.6352 307.7763 307.9174 308.0585 308.1995 308.3406 308.4816 308.6226 308.7636 308.9045 309.0455 309.1864 309.3273 309.4682 309.6090 309.7499 309.8907 310.0315 310.1723 310.3131 310.4538 310.5946 310.7353 310.8760 311.0167 311.1573 311.2980 311.4386 311.5792 311.7198 311.8604 312.0009 312.1415 312.2820 312.4225 312.5630 312.7035 312.8439 312.9844 313.1248 313.2652 313.4056 313.5460 313.6863 313.8267 313.9670 314.1073 314.2476 314.3879 314.5281 314.6684 314.8086 314.9488 315.0890 315.2292 315.3694 315.5095 315.6497 315.7898 315.9299 316.0700 316.2101 316.3501 316.4902 316.6302 316.7702 316.9102 317.0502 317.1902 317.3301 317.4701 317.6100 317.7499 317.8898 318.0297 318.1696 318.3094 318.4493 318.5891 318.7289 318.8687 319.0085 319.1483 319.2880 319.4278 319.5675 319.7072 319.8469 319.9866 320.1263 320.2659 320.4056 320.5452 320.6848 320.8244 320.9640 321.1036 321.2432 321.3827 321.5223 321.6618 321.8013 321.9408 322.0803 322.2198 322.3592 322.4987 322.6381 322.7775 322.9169 323.0563 323.1957 323.3351 323.4744 323.6138 323.7531 323.8924 324.0317 324.1710 324.3103 324.4495 324.5888 324.7280 324.8673 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240203T075426.5Z 8799.329474 287 1 54.44 2 83.81 116.33 61.68 205.12 0.00 1 0.00 1 0 25 7.231e-01 2.802e-02 4.983e-01 2.210e-02 1.080371e+00 1.376389e-02 1.184633e-02 -6.000000e+00 4.143825e-01 224.41 -2.00 3.42 -2.00 322.43 0.00e+00 2.005348e-02 7.531178e-03 1.826448e-03 -6.000000e+00 2.091695e-02 274.48 -2.00 20.00 -2.00 322.08 0.00e+00 8.355 0.009 302.00 328.00 3 6.3960e-01 5.2351e-02 9.9097e-02 -6.0000e+00 1.0355e+00 1.5336e+00 7.4984e-02 7.5658e-02 -6.0000e+00 1.1403e+00 -1.9438e+00 7.3910e-02 3.2168e-02 -6.0000e+00 6.6746e-01 7.7122e-01 3.4346e-02 2.1352e-02 -6.0000e+00 2.9540e-01 3.5979e-05 -1.1917e-03 5.2988e-04 2.1454e-04 -6.0000e+00 1.7691e-02 3.7486e-03 0.0000e+00 12 8 8 10 0 0 5.20 20.35 1.45 0.00375 -0.00521 63 7 1 5 0 863.648 24.50 15.00 20.35 12.60 4.5 864.42 900000 900000 -132426 -95706 -19352 900000 900000 125586 900000 -151299 -192686 900000 92792 900000 900000 900000 900000 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1358 900000 3373 900000 1018 2321 4650 3055 2805 6434 3714 3686 2711 3043 1999 2587 370 1757 4028 2919 3739 2476 2739 2904 3328 3869 6095 2557 -1413 -613 -962 3007 2721 1333 1079 1411 1236 4068 1865 2931 -1683 -3905 -236 -1314 1072 -1986 2530 923 -1175 -2155 2463 -5916 -4041 -2303 1322 -81 -1547 568 -3177 -1322 490 -3778 -2296 186 254 -1713 2220 -3459 466 -3863 -3246 250 908 3033 3785 3085 1618 4276 811 2440 -1044 1008 -1064 -1791 332 1697 790 1223 -848 563 -1466 5922 264 -793 -5320 -2623 567 SS 20240203T080448.6Z 8799.336674 290 1 54.04 2 81.97 118.01 62.61 207.60 0.00 1 0.00 1 0 17 7.396e-01 1.107e-02 3.953e-01 6.736e-03 9.370428e-01 3.797850e-03 9.828410e-03 -6.000000e+00 4.011063e-01 224.41 -2.00 3.42 -2.00 322.01 0.00e+00 1.244420e-02 2.027595e-03 5.518144e-03 -6.000000e+00 1.954478e-02 274.48 -2.00 20.00 -2.00 321.63 0.00e+00 6.711 0.005 302.00 328.00 3 6.4387e-01 1.3726e-02 8.9389e-02 -6.0000e+00 9.9686e-01 4.2576e-01 2.4817e-02 8.0889e-02 -6.0000e+00 1.0854e+00 -4.9816e-01 3.0377e-02 3.2681e-02 -6.0000e+00 6.4300e-01 1.9142e-01 1.3630e-02 1.7829e-02 -6.0000e+00 2.8817e-01 2.1230e-04 -1.0670e-03 1.5490e-04 1.0479e-04 -6.0000e+00 1.6761e-02 3.2252e-03 0.0000e+00 12 8 8 10 0 0 -18.38 20.35 1.16 0.00323 -0.00479 173 19 1 5 0 312.002 24.50 15.00 20.35 13.61 4.5 871.83 -156037 900000 -127595 900000 -390791 -316557 -313204 900000 -215526 900000 -284750 -182685 900000 -72148 -39766 -124349 20664 -18601 -81507 900000 900000 -97696 -155039 -70175 -93600 131580 900000 -48584 900000 900000 -36617 24314 -45638 88925 -55281 41802 -26309 -34365 -23669 20038 35650 29820 -19000 15596 17269 -23994 63409 66511 6119 11725 21031 16002 6194 8485 7703 2359 12073 20087 4909 987 2265 26363 5005 9574 9611 6792 9725 1939 2133 3159 1925 2835 4125 669 5582 7283 -405 -1178 1036 825 695 -1598 -1397 -492 -1106 -44 -91 1439 1566 2253 111 1106 -2899 -3106 -1754 -493 150 -327 -1179 82 -45 183 -60 437 -1135 -1621 -724 -646 -846 -870 12 -45 -396 205 351 -119 305 101 -268 5 560 1576 243 -686 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6.007214e-03 8.549812e-04 1.449624e-03 -6.000000e+00 1.484735e-02 274.48 -2.00 20.00 -2.00 321.13 0.00e+00 5.675 0.003 302.00 328.00 3 5.6428e-01 5.9895e-03 6.8501e-02 -6.0000e+00 8.5221e-01 1.9393e-01 9.7236e-03 4.7776e-02 -6.0000e+00 9.2914e-01 -1.8731e-01 1.1786e-02 2.6680e-02 -6.0000e+00 5.4967e-01 6.1888e-02 5.4861e-03 1.2977e-02 -6.0000e+00 2.4015e-01 6.5850e-04 -8.9748e-04 7.4266e-05 8.5929e-05 -6.0000e+00 1.3454e-02 3.5040e-03 0.0000e+00 11 8 0 10 0 0 -2.02 20.35 0.96 0.00350 -0.00324 329 36 1 5 0 164.031 24.50 15.00 20.35 14.65 4.6 879.05 -284368 -293529 -208560 -235769 -196410 900000 -189528 -226041 -130632 -153894 -198275 -4935 -49119 -142711 -91414 -35354 900000 -32185 -29335 -45531 -33326 -91290 8883 23942 -28348 -52723 -15351 -67754 -25219 -38935 -18085 -14916 -16715 -2005 4356 -27374 -6041 -17997 -4502 7624 404 -305 -4775 3082 873 5091 -2826 9173 -7052 4035 -1572 9838 4524 7500 6562 2404 1226 1983 -1727 -315 -369 2914 4474 2781 1286 -184 2172 1910 3056 1920 245 142 576 142 1375 52 -2616 -1230 181 -657 -1041 -1339 -1333 -962 -596 -659 -636 1205 1237 1177 837 456 255 -371 -1070 -491 613 356 339 -3 315 -547 -970 -279 -1576 -1548 -1021 -342 -225 -86 512 86 -465 466 196 177 291 173 -94 298 342 136 -1 30 524 391 698 541 -350 188 -316 -204 -513 307 276 -491 493 -89 -146 -606 333 252 -2018 -2658 -919 -1269 -625 900000 -649 -1272 -416 -571 -1156 -16 -156 -1173 -606 -169 900000 -196 -187 -362 -239 -1113 49 125 -262 -671 -138 -980 -241 -518 -267 -250 -358 -39 69 -633 -129 -521 -143 262 16 -13 -236 142 42 272 -171 531 -518 291 -142 886 474 854 787 312 167 257 -223 -40 -49 434 771 576 276 -38 473 428 794 595 82 49 187 43 360 12 -631 -309 55 -248 -458 -698 -735 -555 -371 -431 -434 816 832 740 481 254 140 -226 -786 -422 609 383 384 -3 315 -519 -827 -255 -1585 -1588 -1022 -372 -272 -122 808 143 -768 737 291 256 438 274 -159 508 544 206 -2 42 710 519 869 776 -600 358 -624 -425 -1135 721 696 -1302 1273 -241 -383 -1470 752 524 SS 20240203T082226.6Z 8799.348919 298 1 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