File name: Pandora238s1_Granada_20240713_L2Fit_fout2c12d20240517p1-8.txt File generation date: 20250305T233341.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v12d20240517.txt Level 1 file used: Pandora238s1_Granada_20240713_L1_smca1c12d20240517p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20240713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20240517 First and last pixel inside fitting window: 202 343 Nominal wavelengths inside fitting window [nm]: 305.1033 305.2443 305.3853 305.5262 305.6672 305.8082 305.9491 306.0901 306.2310 306.3719 306.5128 306.6537 306.7946 306.9354 307.0763 307.2171 307.3579 307.4987 307.6395 307.7803 307.9211 308.0619 308.2026 308.3434 308.4841 308.6248 308.7655 308.9062 309.0469 309.1875 309.3282 309.4688 309.6094 309.7500 309.8906 310.0312 310.1718 310.3124 310.4529 310.5934 310.7340 310.8745 311.0150 311.1555 311.2959 311.4364 311.5769 311.7173 311.8577 311.9981 312.1385 312.2789 312.4193 312.5597 312.7000 312.8404 312.9807 313.1210 313.2613 313.4016 313.5419 313.6821 313.8224 313.9626 314.1028 314.2431 314.3833 314.5234 314.6636 314.8038 314.9439 315.0841 315.2242 315.3643 315.5044 315.6445 315.7846 315.9247 316.0647 316.2047 316.3448 316.4848 316.6248 316.7648 316.9048 317.0447 317.1847 317.3246 317.4646 317.6045 317.7444 317.8843 318.0242 318.1640 318.3039 318.4437 318.5835 318.7234 318.8632 319.0030 319.1427 319.2825 319.4223 319.5620 319.7017 319.8415 319.9812 320.1209 320.2606 320.4002 320.5399 320.6795 320.8192 320.9588 321.0984 321.2380 321.3776 321.5171 321.6567 321.7962 321.9358 322.0753 322.2148 322.3543 322.4938 322.6333 322.7727 322.9122 323.0516 323.1910 323.3304 323.4698 323.6092 323.7486 323.8880 324.0273 324.1667 324.3060 324.4453 324.5846 324.7239 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240713T054428.3Z 8960.239217 75 1 54.29 2 83.76 67.37 148.91 3.29 0.00 1 0.00 1 0 17 5.637e-01 1.835e-02 4.541e-01 1.537e-02 9.301808e-01 9.563859e-03 9.981876e-03 -6.000000e+00 3.322018e-01 232.06 -2.00 3.42 -2.00 322.28 0.00e+00 -2.838221e-04 6.146876e-03 2.494561e-03 -6.000000e+00 1.831914e-02 287.96 -2.00 20.00 -2.00 321.86 0.00e+00 8.278 0.009 302.00 328.00 3 4.5512e-01 4.2229e-02 9.2885e-02 -6.0000e+00 8.4354e-01 6.3096e-01 7.0399e-02 5.6017e-02 -6.0000e+00 9.2389e-01 -9.1632e-01 7.4379e-02 3.2050e-02 -6.0000e+00 5.4394e-01 3.7016e-01 3.2175e-02 1.0355e-02 -6.0000e+00 2.4305e-01 6.8424e-05 -6.1083e-04 3.8576e-04 9.5438e-05 -6.0000e+00 1.3531e-02 8.3653e-04 0.0000e+00 12 8 8 10 0 0 3.47 21.50 1.32 0.00084 -0.00375 88 10 1 5 0 616.505 25.25 15.00 21.50 26.26 4.9 954.02 900000 900000 900000 900000 -37006 900000 900000 -192413 900000 -284695 -107211 900000 900000 900000 -107009 900000 900000 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900000 1491 1766 1213 559 2163 1619 2737 1011 1191 1402 1988 2012 1050 2317 947 -183 2878 2006 888 777 4097 1390 2856 1377 -308 -2537 1519 -412 2180 432 1332 -830 88 477 -888 2571 -794 -2594 1234 -2557 672 586 -25 -2445 425 -83 65 657 -1245 -2317 123 -284 489 -554 -4563 922 893 -3063 1428 -628 -1630 190 -859 -1431 2492 1203 -1861 -205 -425 893 2073 1118 292 1738 -426 716 1722 330 298 -2372 1008 3117 -406 -3261 1726 588 -3168 3290 1401 -867 -2033 -1816 1071 SS 20240713T055453.6Z 8960.246454 78 1 54.06 2 81.84 68.85 148.75 8.09 0.00 1 0.00 1 0 17 5.468e-01 8.492e-03 3.591e-01 5.200e-03 8.059493e-01 2.933331e-03 8.865228e-03 -6.000000e+00 3.036660e-01 232.06 -2.00 3.42 -2.00 321.70 0.00e+00 4.446701e-03 1.621899e-03 8.589015e-04 -6.000000e+00 1.470750e-02 287.96 -2.00 20.00 -2.00 321.19 0.00e+00 6.601 0.005 302.00 328.00 3 3.3048e-01 1.0984e-02 7.4891e-02 -6.0000e+00 7.6199e-01 2.0754e-01 1.7682e-02 4.5483e-02 -6.0000e+00 8.2292e-01 -2.4127e-01 1.9742e-02 2.6029e-02 -6.0000e+00 4.8926e-01 8.6546e-02 8.9636e-03 1.1317e-02 -6.0000e+00 2.1755e-01 3.7621e-04 -5.5988e-04 1.2080e-04 8.0856e-05 -6.0000e+00 1.2055e-02 4.7177e-04 0.0000e+00 11 8 0 10 0 0 -4.44 21.50 1.14 0.00047 -0.00374 222 24 1 5 0 243.146 25.25 15.00 21.50 27.10 4.9 959.26 -171083 900000 -309771 900000 900000 -50295 -40428 -66947 -296964 -95624 -228325 900000 900000 -158412 -60663 -125325 -18772 65913 -99474 -30700 -87724 -2084 70882 -44110 -63568 43259 -33682 -79644 -7378 -20879 -25323 103049 37564 -8950 -11718 -18667 -9321 2555 -29350 17903 27725 16339 -8138 10969 1436 -4775 3899 16066 -7480 -3054 2096 2954 2904 7228 6537 3698 14869 -253 1490 -64 10026 -450 5391 1502 -764 3771 217 5279 5232 4749 413 128 1060 -48 2981 3131 -3685 43 2892 584 336 1113 -3219 -666 -863 12 28 -1907 935 2431 765 -17 1822 -1413 -1900 -1350 -387 477 -82 -324 -753 650 -773 -4 -1151 -1134 -1827 -201 -703 515 436 809 5 291 344 -204 90 155 110 -263 -211 257 230 -274 931 829 853 345 -8 -197 -296 154 51 236 -49 -339 382 -83 -158 -622 149 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0.00e+00 4.995 0.002 302.00 328.00 3 2.6886e-01 3.0228e-03 5.6880e-02 -6.0000e+00 4.1363e-01 7.7384e-02 4.1749e-03 3.3593e-02 -6.0000e+00 4.4656e-01 -4.9884e-02 4.3266e-03 1.8664e-02 -6.0000e+00 2.6553e-01 4.4840e-03 2.1203e-03 7.0233e-03 -6.0000e+00 1.1661e-01 1.9454e-03 -3.9559e-04 4.1394e-05 5.1513e-05 -6.0000e+00 6.2938e-03 2.7065e-04 0.0000e+00 10 0 0 10 0 0 -4.73 21.47 0.93 0.00027 -0.00270 529 58 1 5 0 101.902 25.25 15.00 21.47 28.53 4.9 969.28 -83119 -120538 -98405 -114944 -70777 -59853 -132590 -60324 -79927 -100952 -89110 -90461 -50413 -40286 -38627 -28603 -37773 -24339 -7873 2947 -20549 -36269 -22476 -4049 -4073 -14732 -13797 -13418 -3596 -14794 -18815 -14653 -408 -4630 -13393 -7239 -8875 -8589 -4887 -2815 -5460 -3187 -1874 -2452 -3479 1262 -413 184 455 1180 1967 675 2359 1010 3309 225 1178 1415 107 614 1497 1731 2144 2822 2025 1715 1096 770 344 1473 1308 478 521 180 908 -171 -454 -726 -406 -1142 -721 -990 -2160 -1235 -353 -658 -380 657 812 804 767 566 236 -453 -227 -223 622 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