File name: Pandora238s1_Granada_20240722_L2Fit_fout2c14d20240721p1-8.txt File generation date: 20250305T233245.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20240721.txt Level 1 file used: Pandora238s1_Granada_20240722_L1_smca1c14d20240721p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20240722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on 11 to update SO2 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.1097 305.2506 305.3914 305.5322 305.6730 305.8138 305.9546 306.0954 306.2362 306.3769 306.5177 306.6584 306.7991 306.9398 307.0805 307.2212 307.3619 307.5025 307.6432 307.7838 307.9244 308.0651 308.2057 308.3463 308.4868 308.6274 308.7680 308.9085 309.0490 309.1896 309.3301 309.4706 309.6111 309.7516 309.8920 310.0325 310.1729 310.3134 310.4538 310.5942 310.7346 310.8750 311.0154 311.1557 311.2961 311.4364 311.5767 311.7171 311.8574 311.9977 312.1379 312.2782 312.4185 312.5587 312.6990 312.8392 312.9794 313.1196 313.2598 313.4000 313.5402 313.6803 313.8205 313.9606 314.1007 314.2408 314.3809 314.5210 314.6611 314.8012 314.9412 315.0813 315.2213 315.3613 315.5013 315.6413 315.7813 315.9213 316.0612 316.2012 316.3411 316.4811 316.6210 316.7609 316.9008 317.0407 317.1805 317.3204 317.4602 317.6001 317.7399 317.8797 318.0195 318.1593 318.2991 318.4388 318.5786 318.7183 318.8581 318.9978 319.1375 319.2772 319.4169 319.5566 319.6962 319.8359 319.9755 320.1151 320.2547 320.3944 320.5339 320.6735 320.8131 320.9527 321.0922 321.2317 321.3713 321.5108 321.6503 321.7898 321.9292 322.0687 322.2081 322.3476 322.4870 322.6264 322.7658 322.9052 323.0446 323.1840 323.3234 323.4627 323.6020 323.7414 323.8807 324.0200 324.1593 324.2985 324.4378 324.5771 324.7163 324.8555 324.9948 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240722T070824.8Z 8969.297510 5 1 54.09 2 68.78 80.25 102.71 251.96 0.00 1 0.00 1 0 17 2.652e-02 5.503e-03 4.225e-03 4.664e-04 3.833814e-01 2.328776e-04 4.436069e-03 -6.000000e+00 1.465216e-02 231.81 -2.00 3.42 -2.00 318.71 0.00e+00 6.007446e-04 5.069446e-05 1.428713e-04 -6.000000e+00 6.506075e-04 288.24 -2.00 20.00 -2.00 317.93 0.00e+00 2.737 0.000 302.00 328.00 3 3.2920e-01 6.3843e-04 3.2280e-02 -6.0000e+00 3.6781e-02 3.1201e-02 7.3517e-04 1.9777e-02 -6.0000e+00 3.9710e-02 -1.1744e-02 5.3496e-04 9.7078e-03 -6.0000e+00 2.3622e-02 -6.2124e-03 2.8887e-04 2.7712e-03 -6.0000e+00 1.0394e-02 1.8342e-02 -5.1266e-04 1.0936e-05 2.0712e-05 -6.0000e+00 5.6236e-04 5.3267e-03 0.0000e+00 11 1 0 11 4 0 -9.26 27.52 0.96 0.00533 0.00147 1635 180 1 5 0 32.728 30.00 14.92 27.52 29.91 6.0 986.87 -7445 -6205 -5239 -10948 -11991 -10126 -13156 -6075 -4980 -6232 -7937 -5158 -2514 -3339 -876 -1584 382 -163 278 1571 -792 -281 936 -394 -691 278 -1029 -1349 -1061 788 1244 1460 1736 -1082 -3427 -740 -1278 -1069 -546 -1080 -1462 -855 -744 -735 -190 -260 -546 -303 -714 486 1294 731 951 695 350 1344 728 335 816 197 1168 1299 1495 1264 -323 157 129 -339 989 975 750 -117 -89 -174 154 -76 261 -506 105 -720 -792 -1372 -1776 -1320 -547 -629 -609 97 464 203 801 725 692 604 448 278 654 98 -252 -355 17 -108 -624 227 -1242 -871 -911 -616 -210 196 267 294 -26 733 451 335 206 220 -136 -419 -422 158 164 -110 841 747 940 715 51 -4 -84 -105 -226 389 113 -458 296 -160 -141 -724 -52 228 900000 -227 -200 -194 -373 -360 -316 -463 -230 -210 -280 -344 -242 -141 -220 -68 -137 33 -16 28 162 -85 -32 114 -52 -96 41 -151 -181 -133 104 188 235 326 -209 -581 -131 -257 -254 -160 -377 -544 -329 -299 -292 -76 -105 -217 -120 -283 196 581 353 442 352 181 705 397 178 421 102 628 770 976 910 -228 99 81 -207 675 780 640 -96 -76 -144 115 -50 160 -331 71 -569 -701 -1275 -1717 -1329 -599 -731 -743 110 572 236 834 705 672 596 457 318 771 134 -356 -475 22 -131 -707 279 -1582 -1124 -1253 -893 -319 305 441 490 -41 1078 654 464 294 330 -206 -677 -666 243 247 -167 1210 1045 1206 990 73 -6 -140 -176 -391 656 207 -883 562 -302 -278 -1362 -95 391 900000 SS 20240722T071337.3Z 8969.301127 8 1 54.08 2 67.76 80.97 103.64 252.67 0.00 1 0.00 1 0 17 2.167e-02 5.600e-03 3.345e-03 4.264e-04 3.664022e-01 2.069528e-04 4.182293e-03 -6.000000e+00 1.176559e-02 231.81 -2.00 3.42 -2.00 318.62 0.00e+00 5.894143e-04 4.437185e-05 1.412976e-04 -6.000000e+00 5.286219e-04 288.24 -2.00 20.00 -2.00 317.80 0.00e+00 2.619 0.000 302.00 328.00 3 3.2010e-01 5.6778e-04 3.0790e-02 -6.0000e+00 2.9515e-02 2.6536e-02 6.5478e-04 1.8763e-02 -6.0000e+00 3.2072e-02 -9.3688e-03 4.5899e-04 9.1051e-03 -6.0000e+00 1.9087e-02 -6.3696e-03 2.4378e-04 2.5203e-03 -6.0000e+00 8.1605e-03 2.1292e-02 -4.1063e-04 9.9419e-06 1.8316e-05 -6.0000e+00 4.5727e-04 1.1071e-03 0.0000e+00 10 0 0 10 0 0 -7.89 25.17 0.93 0.00111 -0.00198 1728 190 1 5 0 30.944 28.00 14.97 25.17 31.37 5.5 991.93 -7171 -5265 -8261 -8298 -8984 -8473 -5601 -6711 -3129 -6597 -6075 -3775 -2690 -1662 -20 -1360 -683 181 781 1100 -267 549 1065 -14 -492 -42 -996 -1230 -1483 1195 1208 1528 1390 -1271 -2929 -817 -1775 -1164 -555 -1028 -1477 -1131 -644 -914 -148 -268 -457 -206 -684 326 1241 825 948 618 362 1283 662 355 915 313 1061 1320 1427 1220 -324 194 199 -238 922 916 745 -165 -187 -227 209 179 337 -633 143 -555 -875 -1376 -1845 -1213 -716 -817 -532 77 352 227 870 780 730 535 532 321 597 65 -253 -375 30 -178 -650 420 -1215 -904 -952 -648 -174 230 246 259 -27 752 441 327 263 361 -164 -406 -429 135 164 -147 766 778 1036 651 122 -14 -83 -83 -245 441 126 -411 253 -226 -200 -744 -46 176 17 -258 -216 -371 -326 -308 -304 -213 -298 -151 -347 -300 -201 -173 -122 -2 -133 -68 19 87 128 -32 69 145 -2 -76 -7 -163 -183 -207 172 200 267 285 -268 -537 -156 -389 -298 -175 -351 -539 -426 -253 -392 -58 -116 -194 -87 -289 139 589 382 465 330 197 707 380 199 496 170 600 820 975 918 -240 127 129 -150 648 757 656 -140 -153 -195 161 122 214 -389 99 -449 -792 -1304 -1824 -1244 -801 -898 -611 89 411 270 927 776 663 491 547 370 710 89 -361 -505 38 -218 -746 521 -1566 -1180 -1324 -949 -248 360 408 433 -44 1109 640 452 375 500 -249 -655 -679 207 248 -210 1105 1092 1330 898 174 -21 -136 -137 -392 732 228 -733 476 -422 -368 -1389 -83 301 28 SS 20240722T071846.2Z 8969.304702 11 1 54.07 2 66.75 81.68 104.57 253.36 0.00 1 0.00 1 0 17 2.127e-02 5.711e-03 2.722e-03 3.951e-04 3.525959e-01 1.917301e-04 4.034100e-03 -6.000000e+00 1.154733e-02 231.81 -2.00 3.42 -2.00 318.48 0.00e+00 5.452570e-04 3.903497e-05 1.367790e-04 -6.000000e+00 5.188075e-04 288.24 -2.00 20.00 -2.00 317.65 0.00e+00 2.513 0.000 302.00 328.00 3 2.9524e-01 5.2384e-04 2.9579e-02 -6.0000e+00 2.8968e-02 2.6985e-02 6.0229e-04 1.8046e-02 -6.0000e+00 3.1477e-02 -9.2875e-03 4.1164e-04 8.7434e-03 -6.0000e+00 1.8733e-02 -6.3623e-03 2.1741e-04 2.4117e-03 -6.0000e+00 8.0092e-03 2.4477e-02 -3.3522e-04 9.2748e-06 1.8028e-05 -6.0000e+00 4.4873e-04 9.7109e-04 0.0000e+00 10 0 0 10 0 0 -3.66 23.61 0.93 0.00097 -0.00155 1890 208 1 5 0 28.256 26.75 14.99 23.61 32.34 5.3 996.02 -6445 -5478 -5630 -9641 -10046 -7478 -6319 -5255 -3381 -5971 -5923 -4281 -3386 -2076 209 -1793 238 530 845 1322 -419 722 689 -49 -398 674 -358 -975 -748 1621 1022 1907 1302 -1069 -2850 -993 -1534 -1092 -525 -969 -1561 -1060 -622 -908 -164 -141 -451 -198 -740 391 1338 758 968 814 354 1204 695 353 677 334 1306 1126 1266 1127 -451 99 283 -230 1001 976 705 -97 -185 -243 204 -28 447 -667 168 -700 -936 -1357 -1776 -1162 -674 -868 -636 96 366 201 746 823 701 540 596 251 635 75 -264 -401 58 -125 -579 453 -1185 -937 -1012 -702 -191 251 262 289 1 777 440 304 237 337 -118 -404 -466 158 161 -144 858 809 997 747 106 -1 -125 -84 -288 425 99 -482 253 -200 -164 -714 -75 146 31 -267 -262 -285 -442 -401 -305 -278 -264 -187 -357 -333 -260 -248 -173 20 -197 26 63 104 170 -56 100 104 -8 -68 120 -64 -159 -113 254 184 360 288 -243 -563 -205 -360 -300 -178 -354 -609 -427 -261 -377 -68 -59 -204 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