File name: Pandora238s1_Granada_20240825_L2Fit_fout2c4d20221202p1-8.txt File generation date: 20240826T002139.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20240825_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20240825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2378 305.3788 305.5198 305.6608 305.8018 305.9428 306.0838 306.2247 306.3657 306.5066 306.6475 306.7884 306.9293 307.0702 307.2110 307.3519 307.4927 307.6335 307.7743 307.9151 308.0559 308.1967 308.3375 308.4782 308.6189 308.7597 308.9004 309.0411 309.1818 309.3224 309.4631 309.6037 309.7444 309.8850 310.0256 310.1662 310.3068 310.4473 310.5879 310.7284 310.8689 311.0095 311.1500 311.2905 311.4309 311.5714 311.7118 311.8523 311.9927 312.1331 312.2735 312.4139 312.5543 312.6947 312.8350 312.9753 313.1157 313.2560 313.3963 313.5366 313.6768 313.8171 313.9573 314.0976 314.2378 314.3780 314.5182 314.6584 314.7986 314.9387 315.0789 315.2190 315.3591 315.4992 315.6393 315.7794 315.9195 316.0595 316.1996 316.3396 316.4796 316.6196 316.7596 316.8996 317.0396 317.1796 317.3195 317.4594 317.5993 317.7393 317.8792 318.0190 318.1589 318.2988 318.4386 318.5784 318.7183 318.8581 318.9979 319.1376 319.2774 319.4172 319.5569 319.6966 319.8364 319.9761 320.1158 320.2554 320.3951 320.5348 320.6744 320.8140 320.9536 321.0933 321.2328 321.3724 321.5120 321.6516 321.7911 321.9306 322.0701 322.2097 322.3491 322.4886 322.6281 322.7676 322.9070 323.0464 323.1858 323.3253 323.4646 323.6040 323.7434 323.8828 324.0221 324.1614 324.3008 324.4401 324.5794 324.7186 324.8579 324.9972 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240825T064104.3Z 9003.278522 260 1 55.33 2 78.78 85.18 28.48 240.78 0.00 1 0.00 1 0 25 4.724e-01 1.539e-02 3.228e-01 1.067e-02 6.370187e-01 5.613926e-03 6.990652e-03 -6.000000e+00 2.586393e-01 230.33 -2.00 3.42 -2.00 321.07 0.00e+00 1.560148e-03 2.641449e-03 4.805770e-04 -6.000000e+00 1.288192e-02 287.95 -2.00 20.00 -2.00 320.41 0.00e+00 4.961 0.002 302.00 328.00 3 3.5577e+00 1.8822e-02 5.6356e-02 -6.0000e+00 6.4895e-01 1.4046e-01 2.5932e-02 3.3069e-02 -6.0000e+00 7.0784e-01 -1.6003e-01 2.5918e-02 1.6772e-02 -6.0000e+00 4.1728e-01 5.9687e-02 1.2480e-02 5.2015e-03 -6.0000e+00 1.8106e-01 7.5524e-05 -4.0326e-04 2.5657e-04 4.0754e-05 -6.0000e+00 1.0490e-02 4.6113e-04 1.2127e-04 12 8 8 10 0 0 -3.06 22.02 1.05 0.00046 -0.00257 21 2 1 5 0 2634.041 25.50 15.00 22.02 32.20 4.9 987.40 900000 -177578 -86840 900000 -196928 900000 -144002 900000 -231606 900000 -31874 900000 51897 900000 900000 -114196 53830 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1003 -290 601 -110 354 -1421 942 2031 44 2152 -1162 276 399 -296 -2186 -721 -445 -2193 -957 -1982 275 555 422 1248 1628 128 1540 -770 506 1460 1532 963 -973 -48 -1872 -1867 -3008 -102 -1586 -1614 -2702 -1984 -1429 392 86 520 -241 2129 1708 -965 943 -1215 -45 253 1340 1570 -915 386 1062 -358 2612 2087 1047 -157 681 1667 2250 -721 -14 -750 -654 -2655 -274 -2733 1294 810 -220 SS 20240825T064622.2Z 9003.282202 263 1 54.26 2 77.73 85.97 29.38 242.47 0.00 1 0.00 1 0 17 4.263e-01 9.857e-03 2.619e-01 6.450e-03 5.982047e-01 3.296288e-03 6.570349e-03 -6.000000e+00 2.303183e-01 230.33 -2.00 3.42 -2.00 320.80 0.00e+00 2.838750e-03 1.414733e-03 3.556835e-04 -6.000000e+00 1.063031e-02 287.95 -2.00 20.00 -2.00 320.12 0.00e+00 4.568 0.001 302.00 328.00 3 3.1968e+00 1.0759e-02 5.2309e-02 -6.0000e+00 5.7565e-01 1.2187e-01 1.4332e-02 3.1203e-02 -6.0000e+00 6.2640e-01 -1.0257e-01 1.3947e-02 1.5556e-02 -6.0000e+00 3.7359e-01 2.7495e-02 6.8381e-03 5.9568e-03 -6.0000e+00 1.6208e-01 1.5803e-04 -5.5856e-04 1.5341e-04 4.0640e-05 -6.0000e+00 8.9749e-03 -2.2054e-04 1.7383e-05 12 8 8 10 0 0 35.39 22.03 0.95 -0.00022 -0.00442 37 4 1 5 0 1466.046 25.75 15.00 22.03 32.41 4.9 988.84 900000 -86681 900000 -130718 -122699 -158243 -138461 -155754 -122578 -13304 -70510 -55461 267182 49450 56291 -78720 54331 20492 301 105131 46297 -35757 -43354 23165 -42412 -10194 31177 -27780 -3521 37055 51735 -5078 -5542 15648 -8600 -10880 534 -5507 2022 -597 1218 -2582 529 6235 775 -2095 1695 4063 7124 340 -878 7780 5161 5492 -3464 -4983 -619 1665 1515 2120 3248 2569 5045 1073 231 -563 1001 1232 5798 1216 -296 1909 1219 460 -2358 1833 384 2080 -2454 -716 -2852 -2274 -387 -1580 -2446 -524 -394 959 1056 1660 974 1130 1219 -452 -266 -98 1249 -417 19 -830 -787 -359 159 -1164 -1778 -962 -1552 -103 336 247 339 546 606 198 -52 -80 -129 -420 -183 -406 194 425 -157 142 -467 377 1277 1483 -231 622 -216 -361 129 381 118 -656 601 88 638 -1025 25 -189 -461 900000 -671 900000 -1581 -1187 -2296 -1959 -3020 -1927 -84 -702 -552 1680 311 383 -2475 484 290 6 781 635 -1063 -1537 463 -1721 -321 659 -985 -95 741 1124 -218 -288 689 -418 -566 28 -368 157 -58 126 -292 62 757 92 -288 227 549 972 52 -158 1409 1035 1216 -869 -1307 -162 414 364 500 796 712 1551 392 85 -193 348 426 2187 569 -151 989 609 219 -1032 676 138 738 -1069 -367 -1706 -1567 -276 -1194 -2033 -454 -324 793 961 1411 755 830 846 -334 -226 -96 1254 -497 24 -1000 -884 -353 156 -1131 -1923 -1049 -1824 -128 450 376 564 939 1009 316 -77 -114 -190 -649 -304 -704 322 678 -246 210 -666 521 1620 2066 -376 1096 -389 -673 251 779 262 -1542 1380 213 1507 -2299 54 -377 -893 SS 20240825T065135.7Z 9003.285830 266 1 54.41 2 76.69 86.74 30.28 244.06 0.00 1 0.00 1 0 17 1.973e-01 7.054e-03 2.192e-01 4.271e-03 5.598639e-01 2.125801e-03 6.148964e-03 -6.000000e+00 1.065868e-01 230.33 -2.00 3.42 -2.00 320.49 0.00e+00 1.407116e-03 8.289371e-04 4.833897e-04 -6.000000e+00 4.805839e-03 287.95 -2.00 20.00 -2.00 319.78 0.00e+00 4.236 0.001 302.00 328.00 3 2.9035e+00 6.5724e-03 4.8484e-02 -6.0000e+00 2.6645e-01 6.8104e-02 8.5246e-03 2.8647e-02 -6.0000e+00 2.8989e-01 -3.8969e-02 8.1512e-03 1.4381e-02 -6.0000e+00 1.7271e-01 2.1555e-03 4.1053e-03 4.3513e-03 -6.0000e+00 7.3984e-02 3.0000e-04 -7.0461e-04 9.9951e-05 3.2633e-05 -6.0000e+00 4.1420e-03 1.2069e-05 -1.5261e-06 11 8 0 10 0 0 51.06 22.04 1.00 0.00001 -0.00528 60 7 1 5 0 906.380 25.75 15.00 22.04 32.68 4.9 990.86 36817 -77536 -64444 -135104 81069 68382 -6155 -40559 -27567 934 3749 -42938 11524 1442 -14501 -6862 -20272 -11223 -52111 -7840 6332 13034 -34446 -2574 -16783 -18026 -23861 19149 -9010 8558 11177 12509 10561 2977 -6823 -9030 -6243 -6241 -3045 -3446 -4030 -365 -1268 -2335 2678 7630 -63 -1600 -1970 1534 -2699 108 -122 824 1588 3722 1314 2013 -488 -1306 1442 2095 1522 3712 2908 -385 1545 -751 1067 1334 2683 162 -251 -559 -2095 60 -53 -961 -1071 277 -660 -1050 -1392 -1244 -1170 -350 476 200 60 948 977 485 40 442 500 270 119 187 -826 -176 342 -112 -754 -29 -2132 -1005 -727 -708 240 543 -368 120 161 649 300 71 327 410 -770 192 -363 116 354 113 331 936 1123 592 -46 -193 -20 -261 -259 564 377 -388 -86 -38 -144 -527 21 391 -255 153 -696 -557 -2345 338 285 -30 -324 -220 6 23 -492 100 17 -252 -131 -514 -293 -2170 -223 161 296 -1396 -84 -667 -778 -1111 537 -321 282 444 545 564 179 -393 -557 -430 -510 -334 -418 -589 -54 -201 -374 414 1150 -10 -273 -350 276 -582 25 -30 224 444 1051 397 588 -141 -377 425 686 567 1535 1214 -151 611 -302 480 710 1511 98 -146 -309 -1052 26 -22 -399 -519 158 -432 -797 -1120 -949 -974 -307 433 186 56 825 847 400 31 356 421 261 131 240 -1126 -227 410 -119 -736 -30 -2520 -1193 -922 -960 347 812 -604 202 261 997 465 105 503 605 -1241 321 -588 180 537 163 495 1362 1508 874 -72 -326 -37 -503 -520 1184 793 -864 -190 -87 -326 -1123 42 744 -512 SS 20240825T065647.2Z 9003.289435 269 1 53.77 2 75.66 87.52 31.18 245.57 0.00 1 0.00 1 0 25 1.331e-01 5.847e-03 1.443e-01 3.214e-03 5.255913e-01 1.602724e-03 5.824899e-03 -6.000000e+00 7.187223e-02 230.33 -2.00 3.42 -2.00 320.23 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