File name: Pandora238s1_Granada_20241101_L2Fit_fout2c14d20240721p1-8.txt File generation date: 20250305T233201.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20240721.txt Level 1 file used: Pandora238s1_Granada_20241101_L1_smca1c14d20240721p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20241101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on 11 to update SO2 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.1097 305.2506 305.3914 305.5322 305.6730 305.8138 305.9546 306.0954 306.2362 306.3769 306.5177 306.6584 306.7991 306.9398 307.0805 307.2212 307.3619 307.5025 307.6432 307.7838 307.9244 308.0651 308.2057 308.3463 308.4868 308.6274 308.7680 308.9085 309.0490 309.1896 309.3301 309.4706 309.6111 309.7516 309.8920 310.0325 310.1729 310.3134 310.4538 310.5942 310.7346 310.8750 311.0154 311.1557 311.2961 311.4364 311.5767 311.7171 311.8574 311.9977 312.1379 312.2782 312.4185 312.5587 312.6990 312.8392 312.9794 313.1196 313.2598 313.4000 313.5402 313.6803 313.8205 313.9606 314.1007 314.2408 314.3809 314.5210 314.6611 314.8012 314.9412 315.0813 315.2213 315.3613 315.5013 315.6413 315.7813 315.9213 316.0612 316.2012 316.3411 316.4811 316.6210 316.7609 316.9008 317.0407 317.1805 317.3204 317.4602 317.6001 317.7399 317.8797 318.0195 318.1593 318.2991 318.4388 318.5786 318.7183 318.8581 318.9978 319.1375 319.2772 319.4169 319.5566 319.6962 319.8359 319.9755 320.1151 320.2547 320.3944 320.5339 320.6735 320.8131 320.9527 321.0922 321.2317 321.3713 321.5108 321.6503 321.7898 321.9292 322.0687 322.2081 322.3476 322.4870 322.6264 322.7658 322.9052 323.0446 323.1840 323.3234 323.4627 323.6020 323.7414 323.8807 324.0200 324.1593 324.2985 324.4378 324.5771 324.7163 324.8555 324.9948 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241101T071724.2Z 9071.303753 72 1 53.87 2 83.72 113.70 83.32 117.11 0.00 1 0.00 1 0 17 7.437e-01 2.603e-02 4.572e-01 1.802e-02 9.196370e-01 1.031841e-02 9.843440e-03 -6.000000e+00 4.129282e-01 224.72 -2.00 3.42 -2.00 322.26 0.00e+00 1.085785e-02 6.172119e-03 1.233048e-03 -6.000000e+00 2.129828e-02 281.02 -2.00 20.00 -2.00 321.82 0.00e+00 8.246 0.009 302.00 328.00 3 6.6050e-01 4.1303e-02 9.1226e-02 -6.0000e+00 1.0336e+00 1.0466e+00 5.8903e-02 5.6845e-02 -6.0000e+00 1.1463e+00 -1.3787e+00 5.6994e-02 2.5389e-02 -6.0000e+00 6.6936e-01 5.5644e-01 2.5867e-02 1.3390e-02 -6.0000e+00 2.8357e-01 5.2713e-05 -1.1995e-03 4.2973e-04 1.1699e-04 -6.0000e+00 1.7860e-02 2.6526e-03 0.0000e+00 12 8 8 10 0 0 -6.53 20.25 1.14 0.00265 -0.00636 63 7 1 5 0 854.651 24.25 15.00 20.25 18.11 5.1 890.50 900000 -73031 -177102 -120590 -120509 -96303 900000 10916 900000 -183424 -169164 900000 900000 900000 56075 900000 -86079 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609 1828 5069 2256 898 1899 3070 2555 1936 2650 2390 -2057 3254 2277 673 1513 4359 2332 3202 4282 751 -2352 5021 3553 2539 2308 4144 2911 -432 -89 -3605 -1680 -845 730 -111 3720 491 2235 -1018 486 -1267 4217 -1200 -429 -4402 -870 -324 -3179 -1570 326 1249 -2761 1902 58 -4499 -3218 -172 2768 -3660 -2258 -2221 -652 -362 -2110 -3006 -1831 -15 2728 -1508 -210 -142 -1474 732 2455 1661 2435 3149 1717 505 262 4568 1571 -1291 869 992 2589 -1918 1904 1066 -4034 2422 -314 -924 -300 -473 1432 -4290 SS 20241101T072748.5Z 9071.310978 75 1 54.19 2 81.84 115.38 81.57 118.81 0.00 1 0.00 1 0 25 5.642e-01 7.711e-03 3.577e-01 5.665e-03 7.892396e-01 3.072459e-03 8.482072e-03 -6.000000e+00 3.003296e-01 224.72 -2.00 3.42 -2.00 321.75 0.00e+00 7.705415e-03 1.680628e-03 9.188117e-04 -6.000000e+00 1.455989e-02 281.02 -2.00 20.00 -2.00 321.24 0.00e+00 6.608 0.005 302.00 328.00 3 6.3636e-01 1.1005e-02 7.3451e-02 -6.0000e+00 7.4343e-01 1.6596e-01 1.8218e-02 4.4120e-02 -6.0000e+00 8.1443e-01 -1.6055e-01 2.1434e-02 2.4592e-02 -6.0000e+00 4.8650e-01 4.9190e-02 9.7225e-03 1.3028e-02 -6.0000e+00 2.1706e-01 2.9313e-04 -4.3357e-04 1.3171e-04 8.7678e-05 -6.0000e+00 1.2510e-02 3.0207e-03 0.0000e+00 11 8 0 10 0 0 -14.41 20.25 1.13 0.00302 -0.00024 170 19 1 5 0 318.373 24.25 15.00 20.25 18.93 5.2 896.51 900000 900000 900000 900000 -254464 -193863 -210834 900000 -284306 -198184 -151403 -41297 -4448 900000 900000 117358 -119067 -107568 221362 7891 -60296 45483 900000 900000 -50158 8449 -30167 -8735 -68903 -5705 -994 -52302 28499 447 -24275 -25394 1493 1363 28902 -18315 31680 -15085 40804 -5117 -6744 6771 11255 -3263 3152 7700 15293 4095 -4738 -250 11746 15276 -4842 3420 -2173 -3107 2615 -1362 6749 3807 -1695 3418 -2535 1193 5734 3847 795 1179 619 -2537 -3007 -4110 -1732 -1036 -499 741 -1175 -1648 -949 -353 -672 -270 618 1926 1687 1609 209 1175 -1358 -791 -340 -975 561 -721 148 -469 707 -214 -298 221 -1701 -1383 -987 -563 -475 322 -272 758 -71 723 43 660 476 498 -564 -438 -122 479 219 170 562 -69 466 568 -103 -16 7 -102 -368 472 143 -795 449 -6 -387 -522 408 616 -198 900000 900000 900000 900000 -1403 -1069 -1163 900000 -2895 -1093 -835 -228 -25 900000 900000 647 -1313 -1236 1221 44 -499 251 900000 900000 -503 51 -272 -61 -898 -49 -11 -1127 343 7 -450 -509 26 29 580 -716 826 -673 1125 -226 -314 289 480 -191 186 476 1037 346 -481 -27 1179 1533 -617 387 -250 -358 304 -190 1020 699 -336 613 -516 240 1284 1039 237 362 181 -712 -748 -913 -374 -234 -137 247 -464 -771 -469 -182 -377 -159 378 1180 1034 928 111 598 -694 -438 -224 -760 503 -779 168 -514 710 -187 -233 185 -1590 -1314 -1009 -626 -586 419 -399 1160 -108 1058 59 878 662 728 -890 -707 -184 688 307 228 723 -87 554 765 -165 -29 15 -217 -836 1132 341 -2007 1103 -16 -979 -1221 892 1359 -426 SS 20241101T074413.8Z 9071.322381 80 1 54.10 2 78.92 118.11 78.85 121.56 0.00 1 0.00 1 0 29 1.974e-01 5.449e-03 1.690e-01 1.907e-03 6.299228e-01 9.518929e-04 6.810489e-03 -6.000000e+00 1.043513e-01 224.72 -2.00 3.42 -2.00 320.89 0.00e+00 2.780848e-03 4.141894e-04 6.880736e-04 -6.000000e+00 4.668667e-03 281.02 -2.00 20.00 -2.00 320.32 0.00e+00 5.021 0.002 302.00 328.00 3 4.5071e-01 3.0116e-03 5.5809e-02 -6.0000e+00 2.5806e-01 8.0239e-02 4.1661e-03 3.1917e-02 -6.0000e+00 2.8230e-01 -4.7848e-02 4.4743e-03 1.7375e-02 -6.0000e+00 1.6827e-01 3.2827e-03 2.1909e-03 6.5622e-03 -6.0000e+00 7.2569e-02 1.6591e-03 -3.4076e-04 4.4053e-05 4.7252e-05 -6.0000e+00 4.1661e-03 3.2914e-03 0.0000e+00 10 0 0 10 0 0 -12.14 20.22 0.94 0.00329 0.00073 449 49 1 5 0 120.141 24.25 15.00 20.22 20.25 5.2 906.11 -68514 -56938 -8641 -13672 -109083 -66363 -94054 1284 -6471 22623 -81692 -60185 -6633 -61777 -24746 -17926 -16559 -9327 -20408 -15307 -2994 -11575 -9635 -26956 -18457 -8821 -11408 -13774 -25403 -8175 -3556 -6679 6187 -6645 -13057 -5128 -1652 -7531 -6064 -2986 -3764 -4709 -212 -3048 1275 1161 -634 279 -394 -479 1182 1791 2307 1490 298 1537 1232 -127 665 -1070 735 2041 1867 3128 1414 1219 686 108 940 1851 1243 614 -395 91 -366 132 -63 -729 -193 -43 -1151 -1370 -1882 -1436 -943 -715 -449 115 1346 601 1002 420 187 93 73 302 700 241 -58 -248 73 -114 -1156 -67 -1355 -749 -1048 -792 -228 296 377 534 -89 855 328 197 170 79 -151 -110 -332 333 119 -419 575 384 798 520 -352 33 -310 -16 -483 223 -13 -449 463 73 -158 -669 65 560 80 -245 -204 -21 -34 -625 -267 -554 3 -21 60 -608 -438 -38 -775 -276 -222 -221 -143 -373 -282 -50 -202 -186 -679 -452 -212 -283 -328 -666 -209 -110 -240 239 -300 -547 -213 -76 -440 -484 -254 -386 -517 -24 -350 144 135 -76 35 -52 -68 191 315 439 317 67 351 294 -30 149 -241 173 535 562 1067 490 393 231 37 368 847 611 315 -195 42 -151 48 -22 -264 -83 -22 -683 -949 -1380 -1000 -711 -569 -373 96 1115 470 779 313 133 71 58 279 739 299 -75 -309 84 -116 -1079 -66 -1506 -843 -1270 -1031 -321 434 607 890 -145 1317 514 298 266 119 -245 -185 -535 513 180 -604 858 562 1080 785 -568 58 -607 -31 -952 462 -30 -1061 1072 179 -378 -1498 138 1105 154 SS 20241101T074929.3Z 9071.326034 83 1 54.08 2 78.00 119.01 78.00 122.46 0.00 1 0.00 1 0 25 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