File name: Pandora238s1_Granada_20241214_L2Fit_fout2c14d20240721p1-8.txt File generation date: 20250305T233235.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20240721.txt Level 1 file used: Pandora238s1_Granada_20241214_L1_smca1c14d20240721p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20241214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on 11 to update SO2 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.1097 305.2506 305.3914 305.5322 305.6730 305.8138 305.9546 306.0954 306.2362 306.3769 306.5177 306.6584 306.7991 306.9398 307.0805 307.2212 307.3619 307.5025 307.6432 307.7838 307.9244 308.0651 308.2057 308.3463 308.4868 308.6274 308.7680 308.9085 309.0490 309.1896 309.3301 309.4706 309.6111 309.7516 309.8920 310.0325 310.1729 310.3134 310.4538 310.5942 310.7346 310.8750 311.0154 311.1557 311.2961 311.4364 311.5767 311.7171 311.8574 311.9977 312.1379 312.2782 312.4185 312.5587 312.6990 312.8392 312.9794 313.1196 313.2598 313.4000 313.5402 313.6803 313.8205 313.9606 314.1007 314.2408 314.3809 314.5210 314.6611 314.8012 314.9412 315.0813 315.2213 315.3613 315.5013 315.6413 315.7813 315.9213 316.0612 316.2012 316.3411 316.4811 316.6210 316.7609 316.9008 317.0407 317.1805 317.3204 317.4602 317.6001 317.7399 317.8797 318.0195 318.1593 318.2991 318.4388 318.5786 318.7183 318.8581 318.9978 319.1375 319.2772 319.4169 319.5566 319.6962 319.8359 319.9755 320.1151 320.2547 320.3944 320.5339 320.6735 320.8131 320.9527 321.0922 321.2317 321.3713 321.5108 321.6503 321.7898 321.9292 322.0687 322.2081 322.3476 322.4870 322.6264 322.7658 322.9052 323.0446 323.1840 323.3234 323.4627 323.6020 323.7414 323.8807 324.0200 324.1593 324.2985 324.4378 324.5771 324.7163 324.8555 324.9948 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241214T080936.5Z 9114.340006 321 1 14.38 2 82.61 126.71 105.10 319.87 0.00 1 0.00 1 0 17 5.798e-01 3.237e-02 4.488e-01 2.387e-02 7.635740e-01 1.262739e-02 9.012961e-03 -6.000000e+00 3.144897e-01 223.19 -2.00 3.42 -2.00 321.62 0.00e+00 -7.497447e-03 6.335320e-03 1.033333e-02 -6.000000e+00 1.586105e-02 276.38 -2.00 20.00 -2.00 321.14 0.00e+00 7.201 0.006 302.00 328.00 3 2.0368e+00 4.3812e-02 9.7666e-02 -6.0000e+00 7.7820e-01 5.4578e-01 6.1721e-02 9.6152e-02 -6.0000e+00 8.5882e-01 -8.3772e-01 5.9564e-02 3.7170e-02 -6.0000e+00 5.0644e-01 3.5324e-01 2.7885e-02 7.1468e-03 -6.0000e+00 2.2069e-01 4.6141e-05 -6.1330e-04 5.7314e-04 9.4396e-05 -6.0000e+00 1.3732e-02 3.1413e-03 0.0000e+00 12 9 9 12 1 1 -35.63 20.07 1.46 0.00314 -0.00147 7 3 1 5 0 1796.665 24.25 15.00 20.07 10.52 5.1 838.42 900000 13732 900000 900000 900000 900000 107290 -177707 -105501 2483 -139612 -210202 11377 -68660 900000 -24 -109629 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3335 3408 3116 665 4752 4828 2042 4226 1819 3012 3691 6515 328 5630 3021 2052 3923 3014 1505 1607 -1112 -7 -407 1423 2889 -1611 1407 -940 -1550 -956 2563 -2459 -2164 1162 1040 2332 655 -2012 -1624 -379 -66 506 -5849 -927 -6160 -858 -2838 -3372 -248 -4459 1730 -3593 -3217 -5915 -3753 990 1340 3117 -6402 485 -45 122 1330 572 2928 2868 2443 -428 1911 5631 6608 4555 -30 2197 -217 -2836 -420 4386 -2430 -1049 1483 -297 2836 -1459 2667 -1484 -3260 111 -2359 -2633 SS 20241214T081906.3Z 9114.346600 324 1 41.34 2 81.11 128.31 106.23 321.63 0.00 1 0.00 1 0 17 4.817e-01 1.079e-02 3.222e-01 7.755e-03 6.930268e-01 4.036530e-03 7.461339e-03 -6.000000e+00 2.575733e-01 223.19 -2.00 3.42 -2.00 321.39 0.00e+00 4.809993e-03 1.954980e-03 8.490637e-04 -6.000000e+00 1.245056e-02 276.38 -2.00 20.00 -2.00 320.90 0.00e+00 6.129 0.004 302.00 328.00 3 1.7533e+00 1.3506e-02 6.6155e-02 -6.0000e+00 6.3988e-01 1.4628e-01 1.9915e-02 3.5987e-02 -6.0000e+00 7.0364e-01 -1.6001e-01 2.2730e-02 2.0241e-02 -6.0000e+00 4.1163e-01 5.5963e-02 1.0754e-02 9.0015e-03 -6.0000e+00 1.7873e-01 1.6399e-04 -4.9004e-04 1.8358e-04 6.7970e-05 -6.0000e+00 1.0434e-02 4.0256e-03 0.0000e+00 12 9 9 12 1 1 98.88 20.07 0.92 0.00403 0.00034 53 8 1 5 0 765.086 24.25 15.00 20.07 10.89 5.1 841.70 -266679 900000 900000 73737 -242791 900000 -162894 900000 900000 900000 -219951 -99195 -136296 50124 105624 -49190 -89526 -37218 -14041 -30717 -34615 17096 -44739 91053 19817 20542 -84086 -73230 -2169 14632 26239 2049 39859 -8460 -28762 3935 -32807 40597 49802 12833 10698 16837 6003 4014 27953 3201 11012 21973 -10809 -1671 -1266 5220 4484 11209 5541 -533 5894 2361 -4904 -977 -784 3758 803 6554 1677 -4589 1770 2113 3714 1268 4256 126 -1681 -174 -425 215 1295 -945 2532 766 -2193 196 -653 -2315 -806 1377 427 -293 2605 687 -248 490 -1379 -1794 -784 -811 -798 88 -186 716 -548 -314 -2186 -385 -1530 -910 -732 -1875 -107 249 600 1298 -268 266 210 184 525 -993 535 -1179 261 1070 536 518 -130 351 1296 284 232 89 40 -439 -724 1184 48 14 8 -614 132 -339 -44 90 -33 -4184 900000 900000 557 -2963 900000 -1231 900000 900000 900000 -3739 -749 -1716 379 798 -526 -1578 -445 -141 -387 -458 141 -768 688 204 226 -2656 -1961 -28 191 396 45 739 -261 -948 100 -1374 976 1368 617 573 902 383 262 1478 247 807 1527 -1102 -168 -148 631 596 1550 841 -89 957 383 -826 -157 -133 696 177 1585 429 -1172 447 538 1080 446 1553 50 -640 -61 -133 59 345 -265 830 309 -1050 107 -381 -1443 -538 952 312 -219 1889 477 -158 297 -823 -1155 -588 -709 -732 94 -212 769 -555 -304 -1949 -364 -1461 -968 -761 -2138 -131 353 939 2105 -432 409 303 256 757 -1525 868 -2008 415 1625 799 735 -179 472 1610 400 383 163 74 -860 -1500 2553 114 35 20 -1585 330 -791 -97 185 -66 SS 20241214T083214.0Z 9114.355718 330 1 44.81 2 79.09 130.58 107.71 324.12 0.00 1 0.00 1 0 17 2.686e-01 6.403e-03 2.098e-01 3.745e-03 5.990384e-01 1.852680e-03 6.475690e-03 -6.000000e+00 1.417948e-01 223.19 -2.00 3.42 -2.00 320.87 0.00e+00 2.877375e-03 7.845542e-04 4.472524e-04 -6.000000e+00 6.455072e-03 276.38 -2.00 20.00 -2.00 320.35 0.00e+00 5.094 0.002 302.00 328.00 3 1.5772e+00 5.7596e-03 5.5399e-02 -6.0000e+00 3.4955e-01 5.1144e-02 7.8855e-03 3.0491e-02 -6.0000e+00 3.8323e-01 -3.2938e-02 8.6260e-03 1.6006e-02 -6.0000e+00 2.2775e-01 -2.2838e-03 4.2563e-03 6.2627e-03 -6.0000e+00 9.8730e-02 5.3800e-04 -4.1318e-04 8.8068e-05 4.1946e-05 -6.0000e+00 5.6706e-03 3.7313e-03 0.0000e+00 12 9 1 12 1 1 99.93 20.05 1.08 0.00373 0.00063 140 19 1 5 0 317.405 24.25 15.00 20.05 11.75 5.2 847.93 -92851 900000 -7945 -138551 900000 -70742 -139008 -101938 -50000 -65691 31428 -99017 42409 -80983 -32121 13541 -15793 -27220 -9114 34659 -24487 20018 -33913 6888 -10145 -14174 -15704 -22308 -16102 -9608 -10811 -18714 15075 -1072 78 3834 571 3626 -6189 -4893 -1199 3886 988 -1056 4300 -4086 377 -32 249 -2047 6950 -169 3598 4520 835 2325 1202 -1045 -1364 -1696 1426 3578 814 1659 112 1008 1800 100 1685 1610 813 117 -958 1295 -666 -814 -219 -977 -620 -1061 -1293 -1405 -1446 -1340 -869 -890 -122 -67 74 916 1073 54 557 23 764 651 776 921 -43 -215 444 -486 -660 -140 -1428 -795 -836 -908 -347 -75 447 415 161 753 103 151 -30 -16 -308 -454 -491 200 709 -360 746 581 1083 702 -313 -260 -27 -567 -124 444 -150 -374 464 -214 -42 -498 -61 511 -23 -495 900000 -29 -1284 900000 -344 -1480 -868 -289 -480 115 -1205 168 -1380 -430 136 -231 -505 -163 426 -553 279 -912 135 -249 -390 -443 -629 -417 -268 -384 -807 565 -48 3 154 27 200 -472 -445 -114 410 114 -125 493 -524 47 -4 34 -303 1088 -31 692 954 189 537 292 -251 -319 -394 341 944 252 583 40 329 604 34 654 738 401 60 -477 596 -278 -300 -78 -354 -266 -547 -763 -964 -1044 -1014 -649 -704 -100 -56 62 711 830 40 392 18 658 588 802 1112 -55 -262 502 -485 -603 -138 -1567 -883 -997 -1166 -481 -118 703 674 255 1231 157 221 -46 -25 -487 -748 -775 303 1139 -555 1088 831 1433 1035 -491 -446 -51 -1120 -255 961 -326 -854 1041 -508 -97 -1083 -127 1069 -46 SS 20241214T083726.7Z 9114.359336 333 1 54.11 2 78.30 131.50 108.28 325.13 0.00 1 0.00 1 0 25 2.139e-01 5.733e-03 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